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公开(公告)号:US20230056347A1
公开(公告)日:2023-02-23
申请号:US17797350
申请日:2021-01-12
申请人: Casale SA
IPC分类号: C07C273/16 , C07C273/04 , B01D61/02 , B01D3/06 , B01D5/00
摘要: A process for purifying a urea-containing aqueous stream, such as the aqueous stream from the recovery section of a urea plant, comprising a step of removing biuret from the urea-containing stream by reverse osmosis in one or more reverse osmosis stages.
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公开(公告)号:US20240344968A1
公开(公告)日:2024-10-17
申请号:US18701041
申请日:2022-10-11
申请人: Casale SA
摘要: Method for determining the corrosion rate of a piece of equipment of a urea synthesis plant, the method comprises the provision of electrodes including a working electrode immersed in an aqueous solution containing ammonium carbamate, the method further comprises the determination of polarization data of the working electrode and the determination of the corrosion rate of said piece of equipment based on said polarization data.
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公开(公告)号:US20240294469A1
公开(公告)日:2024-09-05
申请号:US18647214
申请日:2024-04-26
申请人: Casale SA
IPC分类号: C07C273/16 , B01D3/06 , B01D5/00 , B01D61/02 , C07C273/04
CPC分类号: C07C273/16 , B01D3/06 , B01D5/0072 , B01D5/0084 , B01D61/026 , C07C273/04 , B01D2311/06 , B01D2311/08 , B01D2313/50 , B01D2317/027
摘要: A process for purify ing a urea-containing aqueous stream, such as the aqueous stream from the recovery section of a urea plant. comprising a step of removing biuret from the urea-containing stream by reverse osmosis in one or more reverse osmosis stages.
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公开(公告)号:US20230322660A1
公开(公告)日:2023-10-12
申请号:US18037704
申请日:2021-08-31
申请人: Casale SA
IPC分类号: C07C275/62
CPC分类号: C07C275/62
摘要: A process for the production of biuret from urea wherein: a urea aqueous solution (24) withdrawn from the recovery section of a urea plant is processed to remove water and obtain a concentrated urea melt (25); said urea melt is processed under biuret-forming conditions to decompose urea into biuret and ammonia and obtain a high-biuret urea melt (26); said high-biuret urea melt (26) is diluted with water or with an aqueous stream obtaining a solution (28); the solution (28) is subject to crystallization and precipitation of a solid phase containing biuret which is separated from the aqueous phase.
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公开(公告)号:US20230211312A1
公开(公告)日:2023-07-06
申请号:US17995011
申请日:2021-04-07
申请人: CASALE SA
发明人: Filippo Iocchi , Leonardo Marrone
CPC分类号: B01J19/245 , C01B3/34 , C01B3/025 , C01C1/0417 , C01C1/0488 , C07C273/04 , B01D53/1475 , B01J2219/00024 , C01B2203/0233 , C01B2203/0475 , C01B2203/068 , B01D2252/2041 , B01D2257/504
摘要: A method for revamping an ammonia-urea plant wherein: the ammonia section is modernized to produce an extra amount of low pressure steam; condensation stage of the high-pressure urea synthesis loop is modified to use part of the condensation heat of the urea stripper vapours to produce medium-pressure steam, said medium-pressure steam is fed to one or more steam users of the urea section, particularly for carbamate decomposition, the input of low-pressure steam to the urea section is balanced by importing the extra low-pressure steam produced in the ammonia section.
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公开(公告)号:US11511248B2
公开(公告)日:2022-11-29
申请号:US17763400
申请日:2020-09-01
申请人: Casale SA
发明人: Leonardo Marrone
摘要: A method for controlling a prilling bucket in the prilling of a a urea melt (UM) including: feeding the urea melt to a prilling bucket (1) which vibrates under the action of a magnetostrictive device (2), wherein the vibration of the bucket is controlled, as a function of the amount of urea melt to be prilled, by the following steps: acquisition of a time-varying input signal (3) which represents the flow rate of urea melt fed to the prilling bucket; generation of a first signal (5) and of a second signal (6), independently from each other, as a function of said input signal (3); generation of a third signal (10) having a frequency which is modulated by said first signal and an magnitude which is modulated by said second signal, and use of said third signal to drive said magnetostrictive device (2).
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公开(公告)号:US20240002335A1
公开(公告)日:2024-01-04
申请号:US18035451
申请日:2021-09-10
申请人: Casale SA
发明人: Leonardo Marrone , Andrea Beretti
IPC分类号: C07C273/02 , C07C273/04 , C07C273/16 , B01J2/02
CPC分类号: C07C273/02 , C07C273/04 , C07C273/16 , B01J2/02
摘要: A process of prilling of a urea melt comprising the use of calcium lignosulfonate or carboxymethyl starch as additive to obtain a formaldehyde-free urea product.
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公开(公告)号:US20230303485A1
公开(公告)日:2023-09-28
申请号:US18035030
申请日:2021-09-10
申请人: Casale SA
发明人: Leonardo Marrone
IPC分类号: C07C273/16 , C05C9/00
CPC分类号: C07C273/16 , C05C9/005
摘要: A process for the production of feed grade urea starting from a liquid urea melt, the process comprising processing the urea melt (6) to promote the formation of biuret until a concentration of at least 3% biuret, and subjecting the so obtained biuret-containing urea melt (8) to a shaping process to obtain a granular urea product.
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公开(公告)号:US20230118984A1
公开(公告)日:2023-04-20
申请号:US17802101
申请日:2021-02-09
申请人: Casale SA
IPC分类号: C07C273/04 , B01J19/24
摘要: A process for synthesis of urea from ammonia and carbon dioxide wherein: the urea synthesis is performed with a stripping process in a synthesis loop including at least a reactor (1), a stripper (2) and a condenser (3); the reactor effluent is treated in the stripper to remove unreacted ammonia and carbon dioxide; the urea solution (14) from the stripper is sent to a low-pressure recovery section (4); the stripper vapours are split into a first portion (151) directed to the reactor and a second portion (152) sent to the condenser; the condenser (3) is a shell-and-tube kettle condenser where condensation of stripper vapours is performed in the tube side (30); a carbamate-containing effluent (20) from the condenser is returned to the reactor.
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公开(公告)号:US11535586B2
公开(公告)日:2022-12-27
申请号:US17287895
申请日:2019-11-07
申请人: Casale SA
发明人: Leonardo Marrone
IPC分类号: C07C273/16 , B01J19/24 , C07C273/04 , B01D1/22 , B01D9/00
摘要: A process for synthesis of urea from CO2 and NH3 wherein a steam flow (13) produced in the condenser (3) of a high-pressure synthesis loop is compressed to raise its pressure and temperature before using the steam as a heat source for a downstream step of the process.
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