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公开(公告)号:US10414975B2
公开(公告)日:2019-09-17
申请号:US15329390
申请日:2015-11-16
发明人: Chengyu Li , Wenzhi Sun , Ran Pang , Lihong Jiang , Su Zhang
摘要: This invention provides an orange-yellow-emitting phosphor, the preparation method and the use thereof. This orange-yellow-emitting phosphor has a general formula represented by formula I: Sr9−a−b−xMaMg1.5+b(PO4)7:xEu2+ formula I wherein in formula I, said M is one or two of Ca and Ba; and 0.001≤x≤0.9, 0≤a≤1.0, 0≤b≤2.3. This orange-yellow-emitting phosphor uses a phosphate as the host material and Eu2+ ions as activation ions. The chemical properties of the phosphor are stable. The phosphor has relatively wide excitation band and emission band. And the red component in its emission spectrum is abundant, therefore, coupling the blue InGaN chip with the orange-yellow-emitting phosphor provided by this invention can obtain warm white light. The phosphor is radiation free, therefore, it will not be harmful to the environment. It is indicated by experimental results that this orange-yellow-emitting phosphor can be effectively excited by light at a wavelength of 250-500 nm and emits a wide peak at 470-850 nm, wherein the main emission peaks lie at about 523 nm and 620 nm. This preparation method is simple, and the cost is relatively low, so it is amenable to industrial production.
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公开(公告)号:US20180194998A1
公开(公告)日:2018-07-12
申请号:US15329390
申请日:2015-11-16
发明人: Chengyu Li , Wenzhi Sun , Ran Pang , Lihong Jiang , Su Zhang
CPC分类号: C09K11/71 , C09K11/7738 , H01L33/502 , Y02B20/181
摘要: This invention provides an orange-yellow-emitting phosphor, the preparation method and the use thereof. This orange-yellow-emitting phosphor has a general formula represented by formula I: Sr9−a−b−xMaMg1.5+b(PO4)7:xEu2+ formula I; wherein in formula I, said M is one or two of Ca and Ba; and 0.001≤x≤0.9, 0≤a≤1.0, 0≤b≤2.3. This orange-yellow-emitting phosphor uses a phosphate as the host material and Eu2+ ions as activation ions. The chemical properties of the phosphor are stable. The phosphor has relatively wide excitation band and emission band. And the red component in its emission spectrum is abundant, therefore, coupling the blue InGaN chip with the orange-yellow-emitting phosphor provided by this invention can obtain warm white light. The phosphor is radiation free, therefore, it will not be harmful to the environment. It is indicated by experimental results that this orange-yellow-emitting phosphor can be effectively excited by light at a wavelength of 250-500 nm and emits a wide peak at 470-850 nm, wherein the main emission peaks lie at about 523 nm and 620 nm. This preparation method is simple, and the cost is relatively low, so it is amenable to industrial production.
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公开(公告)号:US09695359B2
公开(公告)日:2017-07-04
申请号:US14700723
申请日:2015-04-30
申请人: SICHUAN SUN FOR LIGHT CO., LTD. , CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES
发明人: Hongjie Zhang , Ming Zhang , Chengyu Li , Kun Zhao , Hao Zhang
IPC分类号: C09K11/77 , H01L25/075 , H01L33/50
CPC分类号: C09K11/7774 , H01L25/0753 , H01L33/502
摘要: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
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公开(公告)号:US20150267111A1
公开(公告)日:2015-09-24
申请号:US14700880
申请日:2015-04-30
申请人: SICHUAN SUNFOR LIGHT CO., LTD. , CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES
发明人: HONGJIE ZHANG , Ming Zhang , Chengyu Li , Kun Zhao , Hao Zhang
IPC分类号: C09K11/77
CPC分类号: C09K11/7774 , H01L25/0753 , H01L33/502
摘要: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
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公开(公告)号:US09695360B2
公开(公告)日:2017-07-04
申请号:US14700788
申请日:2015-04-30
申请人: SICHUAN SUN FOR LIGHT CO., LTD. , CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES
发明人: Chengyu Li , Kun Zhao , Hao Zhang , Hongjie Zhang , Ming Zhang
IPC分类号: C09K11/77 , H01L25/075 , H01L33/50
CPC分类号: C09K11/7774 , H01L25/0753 , H01L33/502
摘要: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
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公开(公告)号:US09611427B2
公开(公告)日:2017-04-04
申请号:US14700880
申请日:2015-04-30
申请人: SICHUAN SUNFOR LIGHT CO., LTD. , CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY, CHINESE ACADEMY OF SCIENCES
发明人: Hongjie Zhang , Ming Zhang , Chengyu Li , Kun Zhao , Hao Zhang
CPC分类号: C09K11/7774 , H01L25/0753 , H01L33/502
摘要: The invention relates to a yellow light afterglow material and a preparation method thereof as well as an LED illuminating device using the same. The yellow light afterglow material comprises the chemical formula of aY2O3.bAl2O3.cSiO2:mCe.nB.xNa.yP, where a, b, c, m, n, x and y are coefficients, and a is not less than 1 but not more than 2, b is not less than 2 but not more than 3, c is not less than 0.001 but not more than 1, m is not less than 0.0001 but not more than 0.6, n is not less than 0.0001 but not more than 0.5, x is not less than 0.0001 but not more than 0.2, and y is not less than 0.0001 but not more than 0.5; wherein Y, Al and Si are substrate elements, and Ce, B, Na and P are activators. The yellow light afterglow material is prepared by the following steps: weighing oxides of elements or materials which can generate oxides at high temperature by molar ratio as raw materials, evenly mixing and then sintering the raw materials at 1200-1700° in a reducing atmosphere.
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