Alkaline earth metal sulphurised hydrocarbyl phenate-containing additive
concentrate, process for its production and use thereof
    1.
    发明授权
    Alkaline earth metal sulphurised hydrocarbyl phenate-containing additive concentrate, process for its production and use thereof 失效
    碱土金属硫化的含烃基酚盐的添加剂浓缩物,其生产和使用的方法

    公开(公告)号:US5397484A

    公开(公告)日:1995-03-14

    申请号:US76384

    申请日:1993-06-14

    CPC分类号: C10M159/22

    摘要: An additive concentrate composition having a TBN greater than 300 suitable for incorporation into a finished lubricating oil composition comprising:(I') a first alkaline earth metal sulphurised hydrocarbyl phenate, and(II') a lubricating oil,the first alkaline earth metal sulphurised hydrocarbyl phenate (I') being obtained by overbasing a second alkaline earth metal sulphurised hydrocarbyl phenate containing at least 4% by weight sulphur, or its precursors, in the presence of the lubricating oil (II'), the amount of the lubricating oil (II') being such that the ratio of the weight of the additive concentrate to the weight of the second alkaline earth metal sulphurised hydrocarbyl phenate, or its precursors, is at least 3.0.

    摘要翻译: 一种TBN大于300的添加剂浓缩物组合物,其适用于掺入成品润滑油组合物中,该组合物包含:(I')第一碱土金属硫化烃基酚盐和(II')润滑油,第一碱土金属硫化烃基 酚酸盐(I')是通过在润滑油(II')存在下使含有至少4重量%硫或其前体的第二碱土金属硫化烃基酚盐过碱化得到的,润滑油(II ')使得添加剂浓缩物的重量与第二碱土金属硫化烃基酚盐或其前体的重量之比至少为3.0。

    Process for the production of a lubricating oil additive concentrate
    2.
    发明授权
    Process for the production of a lubricating oil additive concentrate 失效
    用于生产润滑油添加剂浓缩物的方法

    公开(公告)号:US5433871A

    公开(公告)日:1995-07-18

    申请号:US157336

    申请日:1993-11-23

    摘要: A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 which process comprises reacting at elevated temperaturecomponent (A) a defined mixture selected from defined sulphurized or non-sulphurized acids or calcium salts thereof,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri-(C.sub.2 -C.sub.4) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative,component (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri- or tetra-alkyl ammonium formate or alkanoate provided that when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

    摘要翻译: 一种生产TBN大于300的润滑油添加剂浓缩物的方法,该方法包括在升高的温度下将组分(A)与选自定义的硫化或非硫化酸或其钙盐的限定混合物反应,组分(B) (C)至少一种化合物,其为(i)水,(ii)具有2至4个碳原子的多元醇 ,(iii)二(C3或C4)二醇,(iv)三(C2-C4)二醇,(v)式(I)R(OR1)的单 - 或聚 - 亚烷基二醇烷基醚, xOR 2(I)其中R为C1至C6烷基,R1为亚烷基,R2为氢或C1至C6烷基,x为1至6的整数,(vi)C1至C20一元醇, (vii)C1至C20酮,(viii)C1至C10羧酸酯,或(ix)C1至C20醚,组分(D)润滑油,组分(E)碳二 组分(B),组分(F),所定义的羧酸或衍生物,组分(G),至少一种化合物(i)无机卤化物或(ii)链烷酸铵 或(C)是(ⅱ)组分(F)不是酰基氯,所有组分的重量比例如 产生TBN大于300的浓缩物。

    Process for the production of a lubricating oil additive concentrate
    3.
    发明授权
    Process for the production of a lubricating oil additive concentrate 失效
    用于生产润滑油添加剂浓缩物的方法

    公开(公告)号:US5441652A

    公开(公告)日:1995-08-15

    申请号:US158143

    申请日:1993-11-24

    CPC分类号: C07G17/002 C10M159/22

    摘要: A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 which process comprises reactingcomponent (A) a defined derivative of phenolcomponent (B) an alkaline earth metal base added either in a single addition of in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a C.sub.1 to C.sub.10 monohydric alcohol, (iii) a C.sub.1 to C.sub.20 ketone, (iv) a C.sub.1 to C.sub.10 carboxylic acid ester or (v) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivativecomponent (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri, or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

    摘要翻译: 一种生产TBN大于300的润滑油添加剂浓缩物的方法,该方法包括将组分(A)定义为苯酚组分(B)的衍生物,碱金属碱添加在多个 在反应中的中间点添加,组分(C)至少一种化合物,其为(i)水,(ii)C1至C10一元醇,(iii)C1至C20酮,(iv)C1至C10羧酸 酸性酯或(v)C1至C20醚,组分(D)润滑油,组分(E)二氧化碳,在组分(B),组分(F)中加入或每次加入所定义的羧酸或 衍生物组分(G)至少一种化合物,其为(i)无机卤化物或(ii)烷基铵或单 - ,二 - ,三 - 或四 - 烷基铵甲酸铵或链烷酸酯,条件是当组分(G) 是(ⅱ)中,组分(F)不是酰氯,所有组分的重量比都要生成 TBN大于300的浓缩物。

    Process for the preparation of a lubricating oil additive concentrate
with an organic halide catalyst
    4.
    发明授权
    Process for the preparation of a lubricating oil additive concentrate with an organic halide catalyst 失效
    用有机卤化物催化剂制备润滑油添加剂浓缩物的方法

    公开(公告)号:US5281345A

    公开(公告)日:1994-01-25

    申请号:US556823

    申请日:1990-07-23

    摘要: A process for the production of a lubricating oil additive concentrate comprises reacting at elevated temperature the following components:component (A) a defined acidcomponent (B)--a calcium base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C)--at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri-(C.sub.2 -C.sub.4) glycol, (v) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I) wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether, optionally,component (D)--a lubricating oil,component (E)--carbon dioxide added subsequent to the, or each, addition of component (B), andcomponent (F)--a compound of formula IIR.sup.3 X (II) wherein X is a halogen and R.sup.3 is an alkyl, alkenyl or alkaryl group or halo derivative thereof.

    摘要翻译: 用于生产润滑油添加剂浓缩物的方法包括在升高的温度下使以下组分反应:组分(A)所定义的酸组分(B) - 在中间点以单次添加或多次添加的钙碱 在反应期间,组分(C) - 至少一种化合物,其为(i)水,(ii)具有2至4个碳原子的多元醇,(iii)二(C3或C4)二醇,(iv) 三(C 2 -C 4)二醇,(v)式(I)R(OR 1)x OR 2(I)的单 - 或聚 - 亚烷基二醇烷基醚,其中R是C1至C6烷基,R1是亚烷基 基团,R 2是氢或C 1至C 6烷基,x是1至6的整数,(vi)C 1至C 20一元醇,(vii)C 1至C 20酮,(viii)C 1至C 10羧酸 酯,或(ix)C1至C20醚,任选的组分(D) - 在组分(B)添加或每次加入组分(B)和组分(F)后加入的润滑油,组分(E) - 二氧化碳, - 式I化合物 I R3X​​(II)其中X是卤素,R3是烷基,烯基或烷芳基或其卤代衍生物。

    Process for the production of a lubricating oil additive concentrate
    5.
    发明授权
    Process for the production of a lubricating oil additive concentrate 失效
    用于生产润滑油添加剂浓缩物的方法

    公开(公告)号:US5451331A

    公开(公告)日:1995-09-19

    申请号:US207222

    申请日:1994-03-04

    CPC分类号: C10M159/22

    摘要: A process for the production of a lubricating oil additive concentrate having a TBN greater than 300 comprises reacting at elevated temperaturecomponent (A) a defined salicylic acid derivative,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at internediate points during the reaction,component (C) at least one compound which is (i) water, (ii) a polyhydric alcohol having 2 to 4 carbon atoms, (iii) a di- (C.sub.3 or C.sub.4) glycol, (iv) a tri- (C.sub.2 -C.sub.4) glycol, (iv) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (vi) a C.sub.1 to C.sub.20 monohydric alcohol, (vii) a C.sub.1 to C.sub.20 ketone, (viii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (ix) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative, andcomponent (G) at least one compound which is (i) an inorganic halide of (ii) an ammonium alkanoate or mono-, di-, tri- or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (ii), component (F) is not an acid chloride,the weight ratios of all components being such as to produce a concentrate having a TBN greater than 300.

    摘要翻译: 生产TBN大于300的润滑油添加剂浓缩物的方法包括在升高的温度下使组分(A)与定义的水杨酸衍生物,组分(B)一起添加的碱土金属碱反应, (C)至少一种化合物,其为(i)水,(ii)具有2至4个碳原子的多元醇,(iii)二(C3或C4)二醇 ,(iv)三 - (C 2 -C 4)二醇,(iv)式(I)R(OR 1)x OR 2(I)的单 - 或多 - 亚烷基二醇烷基醚,其中R是C1至C6烷基 R1为亚烷基R2为氢或C1〜C6烷基,x为1〜6的整数,(vi)C1〜C20一元醇,(vii)C1〜C20酮,(viii)C1 至(C)的碳酸酯,或(ix)C1至C20醚,组分(D)润滑油,组分(E)中添加的组分(B),组分(F) )定义的羧酸或衍生物,和组分(G)至少一种化合物,其是(i)无机卤化物,(ii)烷基铵或烷基甲酸烷基酯或烷酸烷基酯的单,二,三或四烷基铵 当组分(G)为(ⅱ)时,组分(F)不是酰氯,所有组分的重量比都要产生TBN大于300的浓缩物。

    Production of a lubricating oil additive concentrate
    6.
    发明授权
    Production of a lubricating oil additive concentrate 失效
    生产润滑油添加剂浓缩物

    公开(公告)号:US5384053A

    公开(公告)日:1995-01-24

    申请号:US202665

    申请日:1994-02-25

    摘要: A process for the production of a lubricating oil additive concentrate comprises reacting at elevated temperaturecomponent (A) a calcium hydrocarbyl-substituted sulphonate,component (B) an alkaline earth metal base added either in a single addition or in a plurality of additions at intermediate points during the reaction,component (C) at least one compound which is (i) a polyhydric alcohol having 2 to 4 carbon atoms, (ii) a di- (C.sub.3 or C.sub.4) glycol, (iii) a tri- (C.sub.2 -C.sub.4) glycol, (iv) a mono- or poly-alkylene glycol alkyl ether of the formula (I)R(OR.sup.1).sub.x OR.sup.2 (I)wherein R is a C.sub.1 to C.sub.6 alkyl group, R.sup.1 is an alkylene group, R.sup.2 is hydrogen or a C.sub.1 to C.sub.6 alkyl group and x is an integer from 1 to 6, (v) a C.sub.1 to C.sub.20 monohydric alcohol, (vi) a C.sub.1 to C.sub.20 ketone, (vii) a C.sub.1 to C.sub.10 carboxylic acid ester, or (viii) a C.sub.1 to C.sub.20 ether,component (D) a lubricating oil,component (E) carbon dioxide added subsequent to the, or each, addition of component (B),component (F) a defined carboxylic acid or derivative, component (G) at least one compound which is (i) an inorganic halide or (ii) an ammonium alkanoate or a mono-, di-, tri-, or tetra-alkyl ammonium formate or alkanoate provided that, when component (G) is (it), component (F) is not an acid chloride.

    摘要翻译: 制备润滑油添加剂浓缩物的方法包括在升高的温度下使组分(A)烃基取代的烃磺酸钙,组分(B)在中间体中以单一添加剂或多种添加剂加入的碱土金属碱 (C)至少一种化合物,其为(i)具有2至4个碳原子的多元醇,(ii)二(C3或C4)二醇,(iii)三 - (C2- C4)二醇,(iv)式(I)R(OR1)xOR2(I)的单 - 或聚 - 亚烷基二醇烷基醚,其中R是C1-C6烷基,R1是亚烷基,R2是氢 或C1〜C6烷基,x为1〜6的整数,(v)C1〜C20一元醇,(vi)C1〜C20酮,(vii)C1〜C10羧酸酯或(viii) )组分(D),组分(D)润滑油,组分(E)二氧化碳,在组分(B),组分(F)中加入或分别加入一种所定义的羧酸或de (G)至少一种化合物,其为(i)无机卤化物或(ii)烷基铵或单 - ,二 - ,三 - 或四 - 烷基甲酸铵或链烷酸铵,条件是当组分( G)是(it),组分(F)不是酰氯。

    Highly overbased lubricating oil additive concentrates their preparation
and use
    8.
    发明授权
    Highly overbased lubricating oil additive concentrates their preparation and use 失效
    高度高碱性润滑油添加剂浓缩其制备和使用

    公开(公告)号:US6028039A

    公开(公告)日:2000-02-22

    申请号:US895692

    申请日:1997-07-17

    CPC分类号: C07G17/008 C10M159/22

    摘要: An additive concentrate having a TBN greater than 300 suitable for incorporation into a finished lubricating oil composition comprising:(I) a lubricating oil soluble sulphurised or non-sulphurised alkaline earth metal hydrocarbyl phenate derived either from a hydrocarbyl phenate or its precursors and modified by reaction to incorporate:(i) an aldehyde, and(ii) from greater than 2 to less than 40% by weight based on the weight of the concentrate of either (a) at least one carboxylic acid having the formula: ##STR1## wherein R is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.1 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride or ester thereof, or (b) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride or ester thereof, and (II) a lubricating oil,wherein the amount of lubricating oil (II) in the additive concentrate is such that the ratio of the weight of the additive concentrate to the weight of the hydrocarbyl phenate or its precursors from which the modified sulphurised or non-sulphurised phenate is derived is at least 3.0.

    摘要翻译: TBN大于300的添加剂浓缩物适于掺入成品润滑油组合物中,其包含:(I)衍生自烃基酚盐或其前体并通过反应改性的润滑油可溶性硫化或非硫化碱土金属烃基酚盐 以(i)醛,和(ii)大于2至小于40重量%,基于浓缩物的重量(a)至少一种具有下式的羧酸:其中R是C10 C 24烷基或烯基,R 1为氢,C 1〜C 4烷基或-CH 2 -COOH基,或其酸酐或酯,或(b)含有36〜100个碳原子的二元或多元羧酸 或其酸酐或酯,和(II)润滑油,其中添加剂浓缩物中的润滑油(II)的量使得添加剂浓缩物的重量与酚基酚盐或其前体的重量之比 经修饰的硫化或非硫化酚盐衍生自其中的至少3.0。

    Alkaline earth metal hydrocarbyl salicylate concentrates, their
preparation and use
    9.
    发明授权
    Alkaline earth metal hydrocarbyl salicylate concentrates, their preparation and use 失效
    碱土金属盐酸水杨酸盐浓缩液,其制备和使用

    公开(公告)号:US5458790A

    公开(公告)日:1995-10-17

    申请号:US355171

    申请日:1994-12-08

    CPC分类号: C10M159/22

    摘要: An additive concentrate having a TBN greater than 300 suitable for incorporation into a finished lubricating oil comprises: (I) a lubricating oil soluble overbased alkaline earth metal hydrocarbyl salicylate modified by reaction to incorporate (a) an aldehyde, and (b) from 2 to 40% by weight, based on the weight of the concentrate, of either (i) at least one carboxylic acid having the formula: ##STR1## wherein R.sup.3 is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.4 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a CH.sub.2 COOH group, or an anhydride or ester thereof, or (ii) a di- or poly-carboxylic acid containing from 36 to 100 carbon atoms or an acid anhydride, acid chloride or ester thereof, and (II) a lubricating oil.

    摘要翻译: 具有TBN大于300的添加剂浓缩物适于掺入成品润滑油中包括:(I)通过反应改性的润滑油溶性高碱性碱土金属水杨酸烃基酯,其通过反应引入(a)醛,和(b)从2至 基于浓缩物的重量,40重量%的(i)至少一种具有下式的羧酸:其中R 3是C 10至C 24烷基或烯基,R 4是氢, C 1〜C 4烷基或CH 2 COOH基,或其酸酐或酯,或(ii)含有36〜100个碳原子的二羧酸或多元羧酸或酸酐,酰氯或其酯,和 II)润滑油。

    Alkaline earth metal hydrocarbyl phenates, their sulphurized
derivatives, their production and use thereof
    10.
    发明授权
    Alkaline earth metal hydrocarbyl phenates, their sulphurized derivatives, their production and use thereof 失效
    碱土金属烃基酚盐,其硫化衍生物,其生产和用途

    公开(公告)号:US6090759A

    公开(公告)日:2000-07-18

    申请号:US991546

    申请日:1997-12-16

    IPC分类号: C10M159/22

    摘要: An additive concentrate suitable for incorporation into a finished lubricating oil composition is disclosed. The additive concentrate comprises:(a) a lubricating oil, and(b) a lubricating oil soluble sulphurized or non-sulphurized alkaline earth metal hydrocarbyl phenate modified by incorporation from 2 to less than 40% by weight based on the weight of said concentrate of either (i) at least one carboxylic acid having the formula: ##STR1## wherein R is a C.sub.10 to C.sub.24 alkyl or alkenyl group and R.sup.1 is either hydrogen, a C.sub.1 to C.sub.4 alkyl group or a --CH.sub.2 --COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, said concentrate having a TBN greater than 300, and a viscosity at 100.degree. C. of less than 1,000 cSt. A process for making the foregoing concentrate is disclosed. A finished lubricating oil composition containing the foregoing concentrate is also disclosed.

    摘要翻译: 公开了适于掺入成品润滑油组合物中的添加剂浓缩物。 添加剂浓缩物包括:(a)润滑油,和(b)润滑油可溶的硫化或非硫化碱土金属的烃基酚盐,其通过以所述浓缩物的重量计2至小于40重量% (i)至少一种具有下式的羧酸:其中R是C 10至C 24烷基或烯基,R 1是氢,C 1至C 4烷基或-CH 2 -COOH基,或者酸酐,酰氯 或其酯或(ii)含有36至100个碳原子的二羧酸或多羧酸或其酸酐,酰氯或其酯,所述浓缩物的TBN大于300,而在100℃下的粘度小于 1,000 cSt 公开了制备上述浓缩物的方法。 还公开了含有上述浓缩物的成品润滑油组合物。