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公开(公告)号：US06433101B1
公开(公告)日：2002-08-13
申请号：US09453020
申请日：1999-12-02
IPC分类号： C08F818
摘要： The present invention relates to the post-polymerization fluorination methods of polymers produced via ring-opening metathesis polymerization. Unlike prior art methods that result in low product yields and generally involve chemically aggressive reagents, the inventive methods produce fluorinated polymers in quantitative yields and under mild conditions. In preferred embodiments, a source of difluorocarbene is reacted with the desired polydiene to form a fluorinated polymer product. In preferred embodiments, the source of difluorocarbene is hexafluoropropylene oxide and the polydiene is poly-dicyclopentadiene (“poly-DCPD”). Fluorination and the concomitant removal of unsaturated bonds result in polymers having improved physical properties such as improved strength characteristics, enhanced oxidative and chemical stability, and low surface energies.
摘要翻译： 本发明涉及通过开环易位聚合制备的聚合物的后聚合氟化方法。 不同于导致低产物产率并且通常涉及化学腐蚀性试剂的现有技术方法，本发明方法以定量产率和温和条件下产生氟化聚合物。 在优选的实施方案中，将二氟卡宾源与所需的聚二烯反应以形成氟化聚合物产物。 在优选的实施方案中，二氟卡宾的来源是六氟环氧丙烷，聚二烯是聚二环戊二烯（“poly-DCPD”）。 氟化和伴随去除不饱和键导致具有改进的物理性质的聚合物，例如改进的强度特性，增强的氧化和化学稳定性和低表面能。
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2.发明授权Polymerization of low grade DCPD monomers using an olefin metathesis catalyst 失效使用烯烃复分解催化剂聚合低级DCPD单体
公开(公告)号：US6020443A
公开(公告)日：2000-02-01
申请号：US796865
申请日：1997-02-06
CPC分类号： C08G61/08
摘要： Methods for synthesizing polyDCPD via ROMP of low grade DCPD starting materials using Ruthenium or Osmium carbene complex catalyst. Transparent or translucent polyDCPD materials. The Ruthenium or Osmium carbene complex catalysts having the formula ##STR1## where M may be Os or Ru; R and R.sup.1 may be the same or different and may be hydrogen or a substituent group including C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.1 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl and C.sub.1 -C.sub.20 alkylsulfinyl; X and X.sup.1 may be the same or different and may be any anionic ligand; and L and L.sup.1 may be the same or different and may be neutral electron donor. The low grade DCPD starting materials containing less than about 97% by weight of DCPD monomers.
摘要翻译： 使用钌或锇卡宾复合催化剂，通过低品位DCPD原料的ROMP合成聚DDP的方法。 透明或半透明的聚DDP材料。 具有下式的钌或锇卡宾络合物催化剂其中M可以是Os或Ru; R和R 1可以相同或不同，并且可以是氢或包括C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基，C 2 -C 20链烯氧基， C 2 -C 20炔氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基和C 1 -C 20烷基亚磺酰基; X和X 1可以相同或不同，并且可以是任何阴离子配体; L和L 1可以相同或不同，并且可以是中性的电子给体。 含有低于约97重量％的DCPD单体的低品位DCPD原料。
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公开(公告)号：US06383319B1
公开(公告)日：2002-05-07
申请号：US09369051
申请日：1999-08-04
IPC分类号： C06B2700
摘要： Preferred embodiments of the present invention relate to rocket fuels comprising metal hydrides and poly-dicyclopentadiene (“poly-DCPD”). Although poly-DCPD also has physical and chemical properties that are compatible with being used as a rocket fuel in its own right, its primary function is as a binder for the metal hydride. Illustrative examples of metal hydrides include but are not limited to as aluminum hydrides, lithium hydrides, and lithium aluminum hydrides.
摘要翻译： 本发明的优选实施方案涉及包含金属氢化物和聚二环戊二烯（“poly-DCPD”）的火箭燃料。 虽然poly-DCPD也具有与其本身用作火箭燃料相容的物理和化学性质，但其主要功能是作为金属氢化物的粘合剂。 金属氢化物的说明性实例包括但不限于氢化铝，氢化锂和氢化锂铝。
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公开(公告)号：US5266370A
公开(公告)日：1993-11-30
申请号：US679862
申请日：1991-04-03
CPC分类号： F16L9/12 , B29C41/04 , Y10S138/07 , Y10T428/1362 , Y10T428/139 , Y10T428/1397 , Y10T428/31
摘要： A centrifugally cast plastic pipe comprised of a polymer derived from monomers polymerized in bulk is provided. A pressurized cylindrical mold provides smooth inner and outer surfaces. Pipes with a wall thickness of from 1/8 inch to 3 inches and an outer diameter of 1 inch to 12 feet are provided.
摘要翻译： 提供了由衍生自大量聚合的单体的聚合物组成的离心铸塑管。 加压圆柱形模具提供光滑的内表面和外表面。 提供壁厚为1/8英寸至3英寸，外径为1英寸至12英尺的管道。
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公开(公告)号：US06410110B1
公开(公告)日：2002-06-25
申请号：US09148834
申请日：1998-09-04
IPC分类号： B29C4104
CPC分类号： C08G61/08 , Y10T428/1369 , Y10T428/139 , Y10T428/1397
摘要： Thermosetting resin pipes and pipe fittings are provided which are prepared by polymerizing a cyclic olefin monomer in the presence of a ruthenium or osmium metathesis polymerization catalyst. These articles may be prepared by various methods, such as centrifugal casting. Reinforced articles may also be prepared by filament winding.
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公开(公告)号：USRE36340E
公开(公告)日：1999-10-12
申请号：US895396
申请日：1997-07-16
CPC分类号： F16L9/12 , B29C41/04 , Y10S138/07 , Y10T428/1362 , Y10T428/139 , Y10T428/1397 , Y10T428/31
摘要： A centrifugally cast plastic pipe comprised of a polymer derived from monomers polymerized in bulk is provided. A pressurized cylindrical mold provides smooth inner and outer surfaces. Pipes with a wall thickness of from 1/8 inch to 3 inches and an outer diameter of 1 inch to 12 feet are provided.
摘要翻译： 提供了由衍生自大量聚合的单体的聚合物组成的离心铸塑管。 加压圆柱形模具提供光滑的内表面和外表面。 提供壁厚为+ E，1/8 + EE英寸至3英寸，外径为1英寸至12英尺的管道。
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7.发明授权
公开(公告)号：US5087343A
公开(公告)日：1992-02-11
申请号：US534708
申请日：1990-06-08
CPC分类号： C25B9/00
摘要： A molded, one piece electrolytic cell head is provided which is obtained from a closed mold. The structure weighs more than 100 pounds and is comprised of bulk polymerized monomers having norbornene functionality. The structure provides improved performance over cell heads comprised of fiber glass reinforced polyester since fiber reinforcement is not required.
摘要翻译： 提供从闭合的模具获得的模制的一体式电解池头。 结构重量大于100磅，由具有降冰片烯功能的本体聚合单体组成。 由于不需要纤维增强，该结构提供了由玻璃纤维增强聚酯组成的电池头的改进的性能。
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公开(公告)号：US3988412A
公开(公告)日：1976-10-26
申请号：US577026
申请日：1975-05-13
申请人： Charles S. Woodson
发明人： Charles S. Woodson
CPC分类号： B29C70/326 , B29C41/042 , B29C41/22 , B29K2101/10 , B29K2101/12 , B29K2105/0854
摘要： Method of making a plastic pipe and method of making same, having an outer shell of reinforced thermo-setting resin and an inner shell of thermo-setting and thermo-plastic resins.
摘要翻译： 制造塑料管的方法及其制造方法，具有增强热固树脂的外壳和热固树脂和热塑性树脂的内壳。
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