公开(公告)号：US08058362B2

公开(公告)日：2011-11-15

申请号：US12388996

申请日：2009-02-19

Applicant: Ching-Hsuan Lin ,  Yu Ming Hu ,  Hong Tze Lin

Inventor： Ching-Hsuan Lin ,  Yu Ming Hu ,  Hong Tze Lin

IPC: C07D498/00 ,  C08G59/14 ,  C08L63/00 ,  C08L63/02 ,  C08L63/04

CPC classification number: C07F9/657172 ,  C08G59/304 ,  C08L63/00 ,  H05K1/0326

Abstract: An active-hydrogen-containing (carboxyl or hydroxyl) phosphorus compound is provided. An epoxy resin semi-thermoset formed by bonding the phosphorus compound to an epoxy group is also provided. A flame-retardant epoxy resin thermoset is formed after reacting the epoxy resin semi-thermoset with a curing agent. The epoxy resin thermoset possesses excellent flame retardancy, heat stability, and high glass transition temperature (Tg), does not produce toxic and corrosive fumes during combustion, and thus is an environmentally friendly flame-retardant material.

Abstract translation: 提供含活性氢（羧基或羟基）的磷化合物。 还提供了通过将磷化合物键合到环氧基团而形成的半热固性环氧树脂。 在环氧树脂半热固化剂与固化剂反应之后形成阻燃环氧树脂热固性材料。 环氧树脂热固性材料具有优异的阻燃性，热稳定性和高玻璃化转变温度（Tg），在燃烧过程中不产生有毒和腐蚀性烟雾，因此是环保型阻燃材料。

公开(公告)号：US20090215967A1

公开(公告)日：2009-08-27

申请号：US12388996

申请日：2009-02-19

Applicant: Ching-Hsuan Lin ,  Yu Ming Hu ,  Hong Tze Lin

Inventor： Ching-Hsuan Lin ,  Yu Ming Hu ,  Hong Tze Lin

IPC: C08G65/48 ,  C07D265/14 ,  C08G65/335

CPC classification number: C07F9/657172 ,  C08G59/304 ,  C08L63/00 ,  H05K1/0326

Abstract: An active-hydrogen-containing (carboxyl or hydroxyl) phosphorus compound is provided. An epoxy resin semi-thermoset formed by bonding the phosphorus compound to an epoxy group is also provided. A flame-retardant epoxy resin thermoset is formed after reacting the epoxy resin semi-thermoset with a curing agent. The epoxy resin thermoset possesses excellent flame retardancy, heat stability, and high glass transition temperature (Tg), does not produce toxic and corrosive fumes during combustion, and thus is an environmentally friendly flame-retardant material.

Abstract translation: 提供含活性氢（羧基或羟基）的磷化合物。 还提供了通过将磷化合物键合到环氧基团而形成的半热固性环氧树脂。 在环氧树脂半热固化剂与固化剂反应之后形成阻燃环氧树脂热固性材料。 环氧树脂热固性材料具有优异的阻燃性，热稳定性和高玻璃化转变温度（Tg），在燃烧过程中不产生有毒和腐蚀性烟雾，因此是环保型阻燃材料。

公开(公告)号：US08703882B2

公开(公告)日：2014-04-22

申请号：US12979394

申请日：2010-12-28

Applicant: Ching-Hsuan Lin ,  Hung-Tse Lin ,  Sheng Lung Chang ,  Yu-Ming Hu

Inventor： Ching-Hsuan Lin ,  Hung-Tse Lin ,  Sheng Lung Chang ,  Yu-Ming Hu

IPC: C07D327/04 ,  C07F9/655 ,  C08G59/30 ,  C08L63/00 ,  C08L63/02

CPC classification number: C07F9/657172 ,  C08G59/28 ,  C08G59/304

Abstract: Phosphorus-containing benzoxazine-based bisphenols and derivatives thereof are disclosed. The phosphorus-containing benzoxazine-based bisphenols are prepared by reacting DOPO with benzoxazine to form the phosphorus-containing benzoxazine-based bisphenols. The phosphorus-containing benzoxazine-based bisphenols can further to form advanced epoxy resins. The advanced epoxy resins can further be cured to form flame retardant epoxy thermosets.

Abstract translation: 公开了含磷苯并恶嗪的双酚及其衍生物。 通过使DOPO与苯并恶嗪反应形成含磷苯并恶嗪类双酚制备含磷苯并恶嗪类双酚。 含磷苯并恶嗪类双酚可进一步形成先进的环氧树脂。 先进的环氧树脂可进一步固化，形成阻燃环氧热固性材料。

公开(公告)号：US08242266B2

公开(公告)日：2012-08-14

申请号：US13353330

申请日：2012-01-19

Applicant: Ching-Hsuan Lin ,  Chia-Wei Chang ,  Tsung-Li Lin ,  Kuen-Yuan Hwang ,  An-Pang Tu ,  Fang-Hsien Su

Inventor： Ching-Hsuan Lin ,  Chia-Wei Chang ,  Tsung-Li Lin ,  Kuen-Yuan Hwang ,  An-Pang Tu ,  Fang-Hsien Su

IPC: C07D413/10

CPC classification number: C07F9/657172

Abstract: The Phosphorus-containing bisphenols and preparing method thereof are disclosed. A method for producing the phosphorus-containing bisphenol of the formula (1) includes reacting compounds respectively defined by a formula (a), (b), (c) and an acid catalyst to yield compounds of phosphorus-containing bisphenol.

Abstract translation: 公开了含磷双酚及其制备方法。 制备式（1）的含磷双酚的方法包括分别由式（a），（b），（c）和酸催化剂定义的化合物反应，得到含磷双酚的化合物。

公开(公告)号：US20100130698A1

公开(公告)日：2010-05-27

申请号：US12276654

申请日：2008-11-24

Applicant: WEN-CHIUNG SU ,  Chun-Ku Liu ,  Ru-Jong Jeng ,  Shenghong A. Dai ,  Ching-Hsuan Lin

Inventor： WEN-CHIUNG SU ,  Chun-Ku Liu ,  Ru-Jong Jeng ,  Shenghong A. Dai ,  Ching-Hsuan Lin

IPC: C08G59/14

CPC classification number: C08G59/1477 ,  C08G59/184 ,  C08G59/5033 ,  C08L63/00

Abstract: The invention discloses a novel cross-linked epoxy resin with flame-retardant properties and method for producing the same. The polymeric material of the invention includes an epoxy resin, a curing agent and a modification agent. Particularly, the modification agent is a derivative of 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide (DOPO). Moreover, the curing agent is 4,4′-diaminodiphenyl methane (DDM), or tris(4-aminephenyl)amine (NNH).

Abstract translation: 本发明公开了一种具有阻燃性能的新型交联环氧树脂及其制造方法。 本发明的聚合物材料包括环氧树脂，固化剂和改性剂。 特别地，改性剂是9,10-二氢-9-氧杂-10-磷杂菲10-氧化物（DOPO）的衍生物。 此外，固化剂是4,4'-二氨基二苯基甲烷（DDM）或三（4-氨基苯基）胺（NNH）。

公开(公告)号：US07566780B2

公开(公告)日：2009-07-28

申请号：US12017067

申请日：2008-01-21

Applicant: Ching-Hsuan Lin ,  Ya-Ru Taso ,  Chau-Wei Hsieh ,  Hao-Hsin Lee ,  Fang-Hsien Su ,  An-Pang Tu ,  Kuen-Yuan Hwang

Inventor： Ching-Hsuan Lin ,  Ya-Ru Taso ,  Chau-Wei Hsieh ,  Hao-Hsin Lee ,  Fang-Hsien Su ,  An-Pang Tu ,  Kuen-Yuan Hwang

IPC: C07D413/02 ,  C07D413/14

CPC classification number: C07F9/657172

Abstract: The present invention provides phosphorus-based oxazine compounds and the preparation method thereof. The phosphorus-based oxazine compounds of the present invention can provide better fire-resistant characteristics, while the preparation method for the phosphorus-based oxazine compound of the present invention can offer high yields and/or high purity phosphorus-based oxazine compounds.

Abstract translation: 本发明提供磷基恶嗪化合物及其制备方法。 本发明的磷基恶嗪化合物可以提供更好的耐火特性，而本发明的磷系恶嗪化合物的制备方法可以提供高产率和/或高纯度的磷基恶嗪化合物。

公开(公告)号：US08822723B2

公开(公告)日：2014-09-02

申请号：US13103046

申请日：2011-05-07

Applicant: Wen-Chiung Su ,  Ching-Hsuan Lin ,  Hung-Tse Lin

Inventor： Wen-Chiung Su ,  Ching-Hsuan Lin ,  Hung-Tse Lin

IPC: C07F9/28 ,  C07F9/02 ,  C07F9/6571

CPC classification number: C07F9/657172 ,  C07F9/65719

Abstract: A series of curing agents are provided. The curing agents are multi-functional and phosphorus-containing. The curing agents have excellent processability to be used as an epoxy resin curing agent. The curing agents can be cured to obtain a phosphorus-containing epoxy thermoset with flame retardancy characteristic. The epoxy thermosets are very fit for circuit board substrate having high glass transition temperature; semiconductor packaging material; and related materials.

Abstract translation: 提供一系列固化剂。 固化剂是多功能和含磷的。 固化剂具有优异的加工性能，可用作环氧树脂固化剂。 固化剂可以固化，得到具有阻燃特性的含磷环氧热固性材料。 环氧热固性材料非常适合具有高玻璃化转变温度的电路板基材; 半导体封装材料; 和相关材料。

公开(公告)号：US08293865B2

公开(公告)日：2012-10-23

申请号：US12458186

申请日：2009-07-02

Applicant: Ching-Hsuan Lin ,  Tsung Li Lin ,  Yu-Ting Fang ,  Kuen-Yuan Hwang ,  An-Pang Tu

Inventor： Ching-Hsuan Lin ,  Tsung Li Lin ,  Yu-Ting Fang ,  Kuen-Yuan Hwang ,  An-Pang Tu

IPC: C08G79/02 ,  C08G79/00 ,  C07C9/02

CPC classification number: C08G69/42 ,  C07F9/657172 ,  C08G59/10 ,  C08G59/3254 ,  C08G69/26 ,  C08G73/10 ,  H05K1/0346 ,  H05K1/0393

Abstract: A series of novel phosphorus-containing compounds having the following formula is provided: in which: R1-R4, A, Q and m are as defined in the specification. A process for the preparation of the compound of formula (I) is also provided. A polymer of formula (PA), and preparation process and use thereof are further provided. A polymer of formula (PI), and preparation process and use thereof are also provided.

Abstract translation: 提供了一系列具有下式的新型含磷化合物：其中：R1-R4，A，Q和m如说明书中所定义。 还提供了制备式（I）化合物的方法。 进一步提供式（PA）的聚合物及其制备方法和用途。 还提供了式（PI）的聚合物及其制备方法和用途。

公开(公告)号：US08134021B2

公开(公告)日：2012-03-13

申请号：US12502241

申请日：2009-07-14

Applicant: Ching-Hsuan Lin ,  Chia-Wei Chang ,  Tsung-Li Lin ,  Kuen-Yuan Hwang ,  An-Pang Tu ,  Fang-Hsien Su

Inventor： Ching-Hsuan Lin ,  Chia-Wei Chang ,  Tsung-Li Lin ,  Kuen-Yuan Hwang ,  An-Pang Tu ,  Fang-Hsien Su

IPC: C07D413/10 ,  C07F9/28

CPC classification number: C07F9/657172

Abstract: The Phosphorus-containing bisphenols and preparing method thereof are disclosed. A method for producing the phosphorus-containing bisphenol of the formula (1) includes reacting compounds respectively defined by a formula (a), (b), (c) and an acid catalyst to yield compounds of phosphorus-containing bisphenol.

Abstract translation: 公开了含磷双酚及其制备方法。 制备式（1）的含磷双酚的方法包括分别由式（a），（b），（c）和酸催化剂定义的化合物反应，得到含磷双酚的化合物。

公开(公告)号：US20130123457A1

公开(公告)日：2013-05-16

申请号：US13396891

申请日：2012-02-15

Applicant: Wen-Chiung Su ,  Ching-Hsuan Lin ,  Hung-Tse Lin ,  Feng-Jen Wang

Inventor： Wen-Chiung Su ,  Ching-Hsuan Lin ,  Hung-Tse Lin ,  Feng-Jen Wang

IPC: C08G59/02 ,  C07F9/6571

CPC classification number: C07D413/10 ,  C07F9/657172 ,  C08G14/06 ,  C08G59/4071 ,  C08G59/5046

Abstract: Disclosed is a method for making a low-k, flame-retardant, bi-functional benzoxazine. The method includes the steps of dissolving phosphoric diamine with various functional groups, phenolic adamantane and paraformaldehyde in a solvent at 72° C. to 88° C. for 7 to 9 hours, and cooling and introducing the solution in n-hexane to separate the low-k, flame-retardant, phosphoric, bi-functional benzoxazine.

Abstract translation: 公开了制备低k阻燃双功能苯并恶嗪的方法。 该方法包括以下步骤：将各种官能团的磷二胺，酚金刚烷和多聚甲醛溶解在溶剂中，在72〜88℃下反应7〜9小时，冷却并将溶液引入正己烷中， 低k，阻燃，磷酸，双功能苯并恶嗪。