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    High-solids binder combinations for scratch-resistant topcoats
    1.
    发明授权
    High-solids binder combinations for scratch-resistant topcoats 有权
    用于耐刮面漆的高固体粘合剂组合

    公开(公告)号：US07196134B2

    公开(公告)日：2007-03-27

    申请号：US10845685

    申请日：2004-05-14

    申请人： Christian Wamprecht ,  Markus Mechtel ,  Jörg Tillack ,  Thomas Klimmasch

    发明人： Christian Wamprecht ,  Markus Mechtel ,  Jörg Tillack ,  Thomas Klimmasch

    IPC分类号： C08L31/02

    CPC分类号： C08G18/4277 ,  C08G18/4063 ,  C08G18/6254 ,  C09D175/04

    摘要： High-solids binder combinations comprising polyisocyanates, special lactone-based polyols and polyacrylate-polyols, a process for preparing such binders, and their use for producing coatings.The lactone-based polyols include ε-caprolactone-based polyols having an average hydroxy functionality ≧2 and a number-average molecular weight of from 119 to 2000 g/mol. The polyacrylate resins are prepared by copolymerizing optionally functional polybutadienes, aromatic monomers, hydroxyalkyl esters of acrylic or methacrylic acid having primary hydroxyl groups, aliphatic esters of acrylic or methacrylic acid and C1 to C8 monoalcohols, α,β-unsaturated C3–C7 monocarboxylic or dicarboxylic acids or of one or more monoesters of maleic acid or fumaric acid and C1 to C14 monoalchols.

    摘要翻译： 包含多异氰酸酯，特殊内酯类多元醇和聚丙烯酸酯 - 多元醇的高固体粘合剂组合物，制备这种粘合剂的方法及其用于制备涂料的用途。

    Nanoparticle-modified polyisocyanates
    2.
    发明授权
    Nanoparticle-modified polyisocyanates 有权
    纳米粒子改性的多异氰酸酯

    公开(公告)号：US08088880B2

    公开(公告)日：2012-01-03

    申请号：US11985448

    申请日：2007-11-15

    申请人： Arno Nennemann ,  Michael Mager ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Gurtler ,  Christian Wamprecht

    发明人： Arno Nennemann ,  Michael Mager ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Gurtler ,  Christian Wamprecht

    IPC分类号： C08G18/06

    CPC分类号： C08G18/289 ,  C08K3/013 ,  C08K3/36 ,  C08K5/544 ,  C08L75/00 ,  C08L75/04

    摘要： The present invention relates to innovative, nanoparticle-modified polyisocyanates, a process for their preparation and to their use in coating compositions and adhesives. The process comprises the steps of 1) reacting A) polyisocyanates with B) alkoxysilanes, and subsequently 2) incorporating by dispersion inorganic particles, optionally surface modified, having an average particle size of less than 200 nm as determined by means of dynamic light scattering in dispersion, where the alkoxysilanes are according to formula (I) Q-Z—SiXaY3-a  (I) in which Q is an isocyanate-reactive group, X is a hydrolysable group, Y is identical or different alkyl groups, Z is a C1-C12 alkylene group and a is an integer from 1 to 3.

    摘要翻译： 本发明涉及创新的纳米颗粒改性的多异氰酸酯，其制备方法及其在涂料组合物和粘合剂中的用途。 该方法包括以下步骤：1）使A）多异氰酸酯与B）烷氧基硅烷反应，随后2）通过分散无机颗粒（任选表面改性的）并入，通过动态光散射测定其平均粒度小于200nm 分散体，其中烷氧基硅烷根据式（I）其中Q是异氰酸酯反应性基团的QZ-SiXaY3-a（I），X是可水解基团，Y是相同或不同的烷基，Z是C1-C12 亚烷基，a为1〜3的整数。

    Nanoparticle-modified polyisocyanates
    4.
    发明申请
    Nanoparticle-modified polyisocyanates 有权
    纳米粒子改性的多异氰酸酯

    公开(公告)号：US20080119601A1

    公开(公告)日：2008-05-22

    申请号：US11985448

    申请日：2007-11-15

    申请人： Arno Nennemann ,  Michael Mager ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Gurtler ,  Christian Wamprecht

    发明人： Arno Nennemann ,  Michael Mager ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Gurtler ,  Christian Wamprecht

    IPC分类号： C08K3/10 ,  C08K3/12 ,  C08K3/14 ,  C08L83/00

    CPC分类号： C08G18/289 ,  C08K3/013 ,  C08K3/36 ,  C08K5/544 ,  C08L75/00 ,  C08L75/04

    摘要： The present invention relates to innovative, nanoparticle-modified polyisocyanates, a process for their preparation and to their use in coating compositions and adhesives. The process comprises the steps of 1) reacting A) polyisocyanates with B) alkoxysilanes, and subsequently 2) incorporating by dispersion inorganic particles, optionally surface modified, having an average particle size of less than 200 nm as determined by means of dynamic light scattering in dispersion, where the alkoxysilanes are according to formula (I) Q-Z-SiXaY3-a  (I) in which Q is an isocyanate-reactive group, X is a hydrolysable group, Y is identical or different alkyl groups, Z is a C1-C12 alkylene group and a is an integer from 1 to 3.

    摘要翻译： 本发明涉及创新的纳米颗粒改性的多异氰酸酯，其制备方法及其在涂料组合物和粘合剂中的用途。 该方法包括以下步骤：1）使A）多异氰酸酯与B）烷氧基硅烷反应，随后2）通过分散无机颗粒（任选表面改性的）并入，通过动态光散射测定其平均粒度小于200nm 分散体，其中烷氧基硅烷根据式（I）<？in-line-formula description =“In-line Formulas”end =“lead”→> QZ-SiX 其中Q是异氰酸酯反应性基团，X是可水解基团，Y是相同的。 或不同的烷基，Z是C 1 -C 12亚烷基，a是1至3的整数。

    Polysiloxane-modified polyisocyanates, processes for preparing the same, and polyurethanes containing the same
    8.
    发明授权
    Polysiloxane-modified polyisocyanates, processes for preparing the same, and polyurethanes containing the same 有权
    聚硅氧烷改性的多异氰酸酯，其制备方法和含有它们的聚氨酯

    公开(公告)号：US08278399B2

    公开(公告)日：2012-10-02

    申请号：US12267634

    申请日：2008-11-10

    申请人： Arno Nennemann ,  Markus Mechtel ,  Thomas Klimmasch ,  Meike Niesten

    发明人： Arno Nennemann ,  Markus Mechtel ,  Thomas Klimmasch ,  Meike Niesten

    IPC分类号： C08L83/06

    CPC分类号： C08G77/458 ,  C08G18/10 ,  C08G18/61 ,  C08G18/792 ,  C08G18/285

    摘要： Processes for preparing siloxane-modified polyisocyanates, the processes comprising: providing a polyisocyanate reactant; and reacting the polyisocyanate reactant with a hydroxyl-containing siloxane having a number-average molecular weight of 200 to 3000 g/mol and an average OH functionality of greater than or equal to 1.8, and corresponding to the general formula (I): wherein X represents an aliphatic, unbranched or branched C1 to C20 radical optionally containing ether groups; R represents a hydroxyl-functional radical; R1 represents a hydrogen or an optionally heteroatom-containing C1 to C20 hydrocarbon radical; and n is 1 to 40; siloxane-modified polyisocyanates prepared thereby, and uses therefor.

    摘要翻译： 制备硅氧烷改性的多异氰酸酯的方法，该方法包括：提供多异氰酸酯反应物; 并使多异氰酸酯反应物与数均分子量为200-3000g / mol，平均OH官能度大于或等于1.8的羟基含硅氧烷反应，并对应于通式（I）：其中X 代表任选地含有醚基团的脂族，非支链或支链C1至C20基团; R表示羟基官能团; R 1表示氢或任选含杂原子的C 1至C 20烃基; n为1〜40; 由此制备的硅氧烷改性的多异氰酸酯，并用于此。