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公开(公告)号：US4990564A
公开(公告)日：1991-02-05
申请号：US284552
申请日：1988-12-15
CPC分类号： C08L77/00
摘要： Thermoplastic molding materials containing, as essential components,(A) 5-95% by weight of a partially aromatic copolyamide essentially composed of(A.sub.1) 20-90% by weight of units derived from terephthalic acid and hexamethylenediamine(A.sub.2) 0-50% by weight of units derived from .epsilon.-caprolactam and(A.sub.3) 0-80% by weight of units derived from adipic acid and hexamethylenediamine,(B) 5-95% by weight of a polyphenylene ether,(C) 0-45% by weight of a vinylaromatic polymer and(D) 0-40% by weight of a rubber impact-modifier, are prepared.
摘要翻译： 含有（A）5-95重量％的部分芳族共聚酰胺的热塑性成型材料，其基本上由（A1）20-90重量％的衍生自对苯二甲酸和六亚甲基二胺（A2）的单元为0-50重量％ （A3）0-80重量％衍生自己二酸和六亚甲基二胺的单元，（B）5-95重量％的聚苯醚，（C）0-45重量％的由ε-己内酰胺衍生的单元 制备乙烯基芳族聚合物的重量和（D）0-40％重量的橡胶冲击改性剂。
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2.发明授权
公开(公告)号：US5019626A
公开(公告)日：1991-05-28
申请号：US161135
申请日：1988-02-26
CPC分类号： C08L71/12 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials contain, as essential components,A) 5-92% by weight of a polyphenylene ether which can contain up to 50% by weight of a styrene polymer which differs from C),B) 5-92% by weight of a nylon,C) 3-50% by weight of a copolymer composed of C.sub.1) 97-99.9% by weight of styrene and/or substituted styrenes of the general formula I ##STR1## where R is hydrogen, alkyl of 1 to 8 carbon atoms or halogen, R.sup.1 is alkyl of 1 to 8 carbon atoms or halogen and n is 0, 1, 2 or 3,C.sub.2) 0.1-3% by weight of an .alpha.,.beta.-unsaturated dicarbonyl compound andC.sub.3) 0-10% by weight of further, nonionic comonomers, andD) 0-35% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料作为必要组分含有A）5-92重量％的聚苯醚，其可以含有至多50重量％的与C）不同的苯乙烯聚合物，B）5-92重量％的 尼龙，C）3-50重量％的由C1）97-99.9重量％的苯乙烯和/或通式I（I）的取代苯乙烯组成的共聚物，其中R是氢，1至 8个碳原子或卤素，R1是1至8个碳原子的烷基或卤素，n是0,1,2或3，C2）0.1-3重量％的α，β-不饱和二羰基化合物和C3）0- 10重量％的另外的非离子共聚单体，和D）0-35重量％的橡胶抗冲改性剂。
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3.发明授权
公开(公告)号：US4943399A
公开(公告)日：1990-07-24
申请号：US349968
申请日：1989-05-08
IPC分类号： C08J3/20 , C08F283/08 , C08G65/48 , C08L71/12 , C08L77/00
CPC分类号： C08L71/126 , C08F283/08 , C08G65/485 , C08L77/00 , Y10S525/905
摘要： Thermoplastic molding materials based on polyphenylene ethers and nylons are prepared in an extruder by a continuous process in which a modified polyphenylene ether is prepared in a first zone of the extruder and is then mixed with nylons and, if required, further additives in one or more further zones.
摘要翻译： 在挤出机中通过连续方法制备基于聚苯醚和尼龙的热塑性成型材料，其中在挤出机的第一区域中制备改性聚苯醚，然后与尼龙混合，如果需要，在一个或多个 进一步的区域。
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4.发明授权
公开(公告)号：US4866114A
公开(公告)日：1989-09-12
申请号：US250170
申请日：1988-09-28
CPC分类号： C08L51/08 , C08G65/485 , C08L71/126 , C08L77/00
摘要： Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components,(A) from 10 to 90% by weight of component (A), which consists of(A.sub.1) from 70 to 99% by weight of a modified polyphenylene ether,(A.sub.2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and(B) from 90 to 10% by weight of component (B), which consists of(B.sub.1) from 80 to 99% by weight of one or more polyamides and(B.sub.2) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.
摘要翻译： 自熄性热塑性聚苯醚/聚酰胺成型材料含有作为必要成分的（A）10〜90重量％的成分（A），（A1）70〜99重量％的改性聚亚苯基 乙醚，（A2）1〜30重量％的含有结合磷的化合物，其重量百分比以组分（A）的总重量计，和（B）90至10重量％的组分（B ），其由（B1）80至99重量％的一种或多种聚酰胺和（B2）1至20重量％的一种或多种含有结合的三嗪基的化合物和由以下组成的组：（a）氰尿酸和 其衍生物。
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5.发明授权
公开(公告)号：US5180778A
公开(公告)日：1993-01-19
申请号：US574073
申请日：1990-08-29
CPC分类号： C08L67/02 , C08L71/123 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containA) not less than 5% by weight of a polymer component consisting of from 50 to 100% by weight of polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component C),B) not less than 5% by weight of a polyester,C) not less than 0.1% by weight of a copolymer consisting ofC.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups, and/orC.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/orC.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups, andC.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, andD) from 0 to 40% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料包含A）不小于5重量％的由50至100重量％的聚苯醚和0至50重量％的不同于组分C）的苯乙烯聚合物组成的聚合物组分，B）不 小于5重量％的聚酯，C）不小于0.1重量％的由C1组成的共聚物，不少于20重量％的碳原子数2〜8的α-烯烃，苯乙烯或苯乙烯的取代苯乙烯 通式I其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1或2，或这些单体的混合物，C2）不小于0.5％ 重量的含有环氧基的可聚合单体和/或C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（II），其中X是卤素，R 2和R 3 各自为1至8个碳原子的烷基或氢，n为1,2或3，和/或C 4）不小于0.05重量％的可聚合单体 r为0〜65重量％的丙烯腈，甲基丙烯腈和其它非离子共聚单体，和D）0〜40重量％的橡胶抗冲改性剂。
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6.发明授权Thermoplastic molding materials based on polyphenylene ethers, nylons and styrene copolymers 失效基于聚苯醚，尼龙和苯乙烯共聚物的热塑性成型材料
公开(公告)号：US4959415A
公开(公告)日：1990-09-25
申请号：US179991
申请日：1988-04-11
CPC分类号： C08L53/02 , C08L71/123 , C08L77/00 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containing(A) not less than 5% by weight of a polyphenylene ether and(B) not less than 5% by weight of a nylon furthermore contain(C) not less than 0.1% by weight of a copolymer composed of(C.sub.1) not less than 30% by weight of a styrene of the general formula I ##STR1## where R and R.sup.1 are alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1, 2 or 3,(C.sub.2) not less than 0.5% by weight of an epoxide-containing polymerizable monomer and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer possessing a structural unit (II) ##STR2## where X is halogen, R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups and(C.sub.5) from 0 to 20% by weight of acrylonitrile, methacrylonitrile and/or other nonionic comonomers, and(D) from 0 to 35% by weight of a toughened rubber, and possess particularly good impact strength.
摘要翻译： 含有（A）不小于5重量％的聚苯醚的热塑性成型材料和（B）不小于5重量％的尼龙，还含有（C）不小于0.1重量％的由（ C1）不小于30重量％的通式I（I）的苯乙烯，其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1,2或 3，（C2）不小于0.5重量％的含环氧化物的可聚合单体和/或（C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（IMAGE） II）其中X是卤素，R2和R3各自为1-8个碳原子的烷基或氢，n为1,2或3，和/或（C4）不小于0.05重量％的含有恶唑啉基团的可聚合单体 和（C5）0至20重量％的丙烯腈，甲基丙烯腈和/或其它非离子共聚单体，和（D）0至35重量％的增韧橡胶，并且具有特定的 良好的冲击强度。
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公开(公告)号：US4957965A
公开(公告)日：1990-09-18
申请号：US228720
申请日：1988-08-05
CPC分类号： C08L77/00 , C08L71/126 , Y10S525/905
摘要： Thermoplastic molding materials contain, as essential components,(A) 5-95% by weight of a polyamide;(B) 5-95% by weight of a modified polyphenylene ether, prepared from(b.sub.1) 4.95-99.9% by weight of a polyphenylene ether,(b.sub.2) 0-90% by weight of a vinylaromatic polymer,(b.sub.3) 0.05-10% by weight of one or more compounds from the group consisting of(b.sub.31) an .alpha.,.beta.-unsaturated dicarbonyl compound,(b.sub.32) a monomer containing amide groups and a polymerizable double bond and(b.sub.33) a monomer containing lactam groups and a polymerizable double bond,(b.sub.4) 0-80% by weight of further graft-active monomers and(b.sub.5) 0.01-0.09% by weight of a free radical initiator,(C) 0-90% by weight of an unmodified polyphenylene ether,(D) 0-45% by weight of a vinylaromatic polymer and(E) 0-40% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料作为必要成分含有（A）5-95重量％的聚酰胺; （B）5-95重量％的由（b1）4.95-99.9重量％的聚苯醚制备的改性聚苯醚，（b2）0-90重量％的乙烯基芳族聚合物，（b3）0.05- 10重量％的一种或多种选自（b31）α，β-不饱和二羰基化合物，（b32）含酰胺基和可聚合双键的单体的化合物和（b33）含有内酰胺基团的单体和 （b4）0-80重量％的另外的接枝活性单体和（b5）0.01-0.09重量％的自由基引发剂，（C）0-90重量％的未改性聚苯醚， （D）0-45重量％的乙烯基芳族聚合物和（E）0-40重量％的橡胶抗冲改性剂。
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公开(公告)号：US5053458A
公开(公告)日：1991-10-01
申请号：US507086
申请日：1990-04-05
CPC分类号： C08L77/00 , C08L71/12 , Y10S525/905
摘要： Thermoplastic molding materials contain, as essential components,A) from 5 to 94% by weight of a polyamide,B) from 5 to 94% by weight of a polyphenylene ether,C) from 1 to 20% by weight of a partially hydrogenated PQP' block copolymer, where.alpha.) the blocks P and P' consist of vinylaromatic monomers and the total amount of these blocks in the block copolymer is from 25 to 40% by weight,.beta.) the number average molecular weight of block P is not more than 8,000 and is smaller than the number average molecular weight of block P',.gamma.) block Q consists of conjugated diene monomers and accounts in total for from 60 to 75% by weight of the block copolymer and.delta.) from 5 to 30% by weight of the double bonds in block Q are not hydrogenated, andD) from 0 to 50% by weight of a vinylaromatic polymer.
摘要翻译： 热塑性成型材料含有A）5至94重量％的聚酰胺，B）5至94重量％的聚苯醚，C）1至20重量％的部分氢化的PQP '嵌段共聚物，其中α）嵌段P和P'由乙烯基芳族单体组成，并且嵌段共聚物中这些嵌段的总量为25至40重量％，β）块P的数均分子量不多 小于块P'的数均分子量，γ）嵌段Q由共轭二烯单体构成，总共占嵌段共聚物的60〜75重量％，δ占5〜30重量％ 嵌段Q中双键的重量不被氢化，D）为0至50重量％的乙烯基芳族聚合物。
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9.发明授权
公开(公告)号：US4962157A
公开(公告)日：1990-10-09
申请号：US209210
申请日：1988-06-20
CPC分类号： C08L67/02 , C08L71/123 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials contain(A) not less than 5% by weight of a polymer component consisting of from 50 to 10 % by weight by polyphenylene ethers and from 0 to 50% by weight of a styrene polymer differing from component (C),(B) not less than 5% by weight of a polyester,(C) not less than 0.1% by weight of a copolymer consisting of(C.sub.1) not less than 20% by weight of .alpha.-olefins of 2 to 8 carbon atoms, styrene or substituted styrenes of the general formula I ##STR1## where R and R.sup.1 is alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1 or 2, or a mixture of these monomers,(C.sub.2) not less than 0.5% by weight of a polymerizable monomer containing epoxide groups,and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer having the structural unit (II) ##STR2## where X is halogen and R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3,and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups,and(C.sub.5) from 0 to 65% by weight of acrylonitrile, methacrylonitrile and further nonionic comonomers, and(D) from 0 to 40% by weight of a rubber impact modifier.
摘要翻译： 热塑性成型材料含有（A）不少于5重量％的由聚苯醚组成的聚合物组分50至10重量％和0至50重量％不同于组分（C）的苯乙烯聚合物，（C） B）不小于5重量％的聚酯，（C）不小于0.1重量％的由（C1）不低于20重量％的2-8个碳原子的α-烯烃组成的共聚物，苯乙烯 或通式I的取代苯乙烯（I）其中R和R 1是1至8个碳原子的烷基，氢和/或卤素和n是0,1或2，或这些单体的混合物（C2 ）不小于0.5重量％的含有环氧基的可聚合单体，和/或（C3）不小于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（II）其中 X是卤素，R 2和R 3各自是1至8个碳原子的烷基或氢，n是1,2或3，和/或（C 4）不小于0.05重量％的聚合物 包含恶唑啉基的单体，和（C5）0至65重量％的丙烯腈，甲基丙烯腈和其它非离子共聚单体，和（D）0至40重量％的橡胶抗冲改性剂。
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公开(公告)号：US4386178A
公开(公告)日：1983-05-31
申请号：US316071
申请日：1981-10-28
申请人： Wilhelm Schuette , Albrecht Hilt , Manfred Walter , Klaus Boehlke
发明人： Wilhelm Schuette , Albrecht Hilt , Manfred Walter , Klaus Boehlke
IPC分类号： C08L59/00 , C08G12/42 , C08L59/02 , C08L61/00 , C08L61/04 , C08L61/20 , C08L61/28 , C08K5/34
摘要： Polyacetal molding materials which contain, as a stabilizer, from 0.1 to 10% by weight of a melamine resin, the latter being a melamine-formaldehyde condensate, having a mean degree of polymerization of from 1.2 to 6.0 and a melamine:formaldehyde ratio of from 1:2 to 1:5.5, which has been partially etherified with a C.sub.1 -C.sub.4 -alkanol so that the ratio melamine:ether radicals is from 1:1.5 to 1:5.0 and the ratio melamine:free methylol groups is from 1:0.5 to 1:3. The molding materials can be converted to moldings which can be used industrially at elevated ambient temperatures.
摘要翻译： 聚缩醛成型材料含有作为稳定剂0.1至10重量％的三聚氰胺树脂，后者为三聚氰胺 - 甲醛缩合物，其平均聚合度为1.2至6.0，三聚氰胺：甲醛比为 1：2至1：5.5，其用C1-C4链烷醇部分醚化，使得三聚氰胺：醚基的比例为1:1.5至1:5.0，三聚氰胺：游离羟甲基的比例为1:0.5 至1：3。 成型材料可以转化成可在工业上在高温环境下使用的模制品。
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