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1.发明授权Thermoplastic molding materials based on polyphenylene ethers, nylons and styrene copolymers 失效基于聚苯醚，尼龙和苯乙烯共聚物的热塑性成型材料
公开(公告)号：US4959415A
公开(公告)日：1990-09-25
申请号：US179991
申请日：1988-04-11
CPC分类号： C08L53/02 , C08L71/123 , C08L77/00 , C08L67/00 , Y10S525/905
摘要： Thermoplastic molding materials containing(A) not less than 5% by weight of a polyphenylene ether and(B) not less than 5% by weight of a nylon furthermore contain(C) not less than 0.1% by weight of a copolymer composed of(C.sub.1) not less than 30% by weight of a styrene of the general formula I ##STR1## where R and R.sup.1 are alkyl of 1 to 8 carbon atoms, hydrogen and/or halogen and n is 0, 1, 2 or 3,(C.sub.2) not less than 0.5% by weight of an epoxide-containing polymerizable monomer and/or(C.sub.3) not less than 0.05% by weight of a halobenzyl-containing polymerizable monomer possessing a structural unit (II) ##STR2## where X is halogen, R.sup.2 and R.sup.3 are each alkyl of 1 to 8 carbon atoms or hydrogen and n is 1, 2 or 3, and/or(C.sub.4) not less than 0.05% by weight of a polymerizable monomer containing oxazoline groups and(C.sub.5) from 0 to 20% by weight of acrylonitrile, methacrylonitrile and/or other nonionic comonomers, and(D) from 0 to 35% by weight of a toughened rubber, and possess particularly good impact strength.
摘要翻译： 含有（A）不小于5重量％的聚苯醚的热塑性成型材料和（B）不小于5重量％的尼龙，还含有（C）不小于0.1重量％的由（ C1）不小于30重量％的通式I（I）的苯乙烯，其中R和R 1是1至8个碳原子的烷基，氢和/或卤素，n是0,1,2或 3，（C2）不小于0.5重量％的含环氧化物的可聚合单体和/或（C3）不少于0.05重量％的具有结构单元（II）的卤代苄基的可聚合单体（IMAGE） II）其中X是卤素，R2和R3各自为1-8个碳原子的烷基或氢，n为1,2或3，和/或（C4）不小于0.05重量％的含有恶唑啉基团的可聚合单体 和（C5）0至20重量％的丙烯腈，甲基丙烯腈和/或其它非离子共聚单体，和（D）0至35重量％的增韧橡胶，并且具有特定的 良好的冲击强度。
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2.发明授权
公开(公告)号：US4965318A
公开(公告)日：1990-10-23
申请号：US218977
申请日：1988-07-14
摘要： Thermoplastic molding materials contain(A) from 5 to 95% by weight of a nylon and(B) from 5 to 95% by weight of a copolymer composed of(B.sub.1) from 50 to 99.9% by weight of a styrene of the general formula I ##STR1## where R.sup.1 is alkyl or 1 to 4 carbon atoms or hydrogen, R.sup.2 is alkyl of 1 to 6 carbon atoms or halogen and m is 0, 1, 2 or 3,(B.sub.2) from 0.1 to 30% by weight of a monomer containing epoxide groups (II) ##STR2## or of a monomer containing lactam groups (III) ##STR3## or of a monomer containing halobenzyl groups (IV) ##STR4## where R.sup.3 is a divalent, branched or straight-chain alkyl group of 2 to 15 carbon atoms, R.sup.4 is alkyl of not more than 6 carbon atoms, X is halogen, n is 1, 2 or 3 and r is 0, 1, 2 or 3, and(B.sub.3) from 0 to 48% by weight of further comonomers.
摘要翻译： 热塑性成型材料含有（A）5至95重量％的尼龙和（B）5至95重量％的由（B1）50-99.9重量％的通式 （I）其中R1是烷基或1-4个碳原子或氢，R2是1至6个碳原子的烷基或卤素，m是0,1,2或3，（B2）0.1-30％ （II）或含有内酰胺基团（III）的单体（III）或含有卤代苄基（IV）的单体的单体（Ⅳ）其中 R3是2至15个碳原子的二价，支链或直链烷基，R4是不大于6个碳原子的烷基，X是卤素，n是1,2或3，r是0,1,2或 3和（B3）0至48重量％的另外的共聚单体。
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3.发明授权Thermoplastic molding compositions containing polycarbonate and a graft copolymer of resin-forming monomers on a rubber 失效含有聚碳酸酯和树脂形成单体在橡胶上的接枝共聚物的热塑性成型组合物
公开(公告)号：US4603169A
公开(公告)日：1986-07-29
申请号：US722363
申请日：1985-04-12
申请人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel
发明人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel
CPC分类号： C08L51/04 , C08L69/00 , Y10S525/902
摘要： A thermoplastic molding material consists of a polycarbonate A and a graft copolymer B, the latter consisting of an elastomer (rubber) (b.sub.1) and a shell (b.sub.2) grafted onto the elastomer.The elastomer (b.sub.1) contains, as copolymerized units, from 35 to 100% by weight of a diene from the group consisting of the conjugated dienes of 4 to 5 carbon atoms, and can contain, as copolymerized units, from 0 to 65% by weight of a monomer from the group consisting of the alkyl acrylates or alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms.The shell (b.sub.2) is obtained in a conventional manner by successive polymerization of the monomers constituting the shell, in two process steps, in the presence of the elastomer (b.sub.1); in a first process step, from 10 to 90% by weight of a mixture of a vinylaromatic hydrocarbon and one or more ethylenically unsaturated monomers which differ from the said hydrocarbon, in a weight ratio of from 90:10 to 60:40, are first incorporated as copolymerized units, followed by the polymerization of from 90 to 10% by weight of a monomer from the group consisting of the alkyl acrylates or of the alkyl methacrylates, where alkyl is of 1 to 8 carbon atoms.The molding material is used for the production of shaped articles.
摘要翻译： 热塑性成型材料由聚碳酸酯A和接枝共聚物B组成，后者由接枝到弹性体上的弹性体（橡胶）（b1）和壳（b2）组成。 作为共聚单元，弹性体（b1）含有35〜100重量％的由4〜5个碳原子的共轭二烯组成的组的二烯，可以以共聚单位含有0〜65重量％ 由丙烯酸烷基酯或甲基丙烯酸烷基酯组成的组中的单体重量，其中烷基具有1至8个碳原子。 壳（b2）以常规方式通过在两个工艺步骤中在弹性体（b1）的存在下连续聚合构成壳的单体获得; 在第一工艺步骤中，以90:10至60:40的重量比为10至90重量％的乙烯基芳烃和一个或多个与所述烃不同的烯键式不饱和单体的混合物是第一 作为共聚单元引入，然后聚合90至10重量％的由丙烯酸烷基酯或甲基丙烯酸烷基酯组成的组的单体，其中烷基具有1至8个碳原子。 成型材料用于成型制品的生产。
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公开(公告)号：US4743661A
公开(公告)日：1988-05-10
申请号：US892473
申请日：1986-08-05
IPC分类号： C08G65/48 , C08F283/08
CPC分类号： C08G65/485
摘要： High molecular weight polyphenylene ethers are prepared from monohydric phenols by a conventional polycondensation, by a method in which the resulting polymers are reacted with an epoxide of the general formula (I) ##STR1## where R.sup.1 and R.sup.2 can be identical or different and are each alkyl, cycloalkyl, aryl, aryloxy, alkoxy or carboxyalkyl, each of which may contain a further epoxide group, or C.sub.3 -C.sub.20 -alkyl-substituted amino, or R.sup.1 is hydrogen and R.sup.2 is one of the above groups, or R.sup.1 and R.sup.2 form part of a cycloalkyl ring.
摘要翻译： 通过常规缩聚由一元酚制备高分子量聚苯醚，通过其中所得聚合物与通式（I）的环氧化物（I）反应的方法，其中R 1和R 2可以相同或不同 并且各自为烷基，环烷基，芳基，芳氧基，烷氧基或羧基烷基，其中每一个可以含有另外的环氧基团或C 3 -C 20烷基取代的氨基，或者R 1为氢，R 2为上述基团之一，或R 1 并且R 2形成环烷基环的一部分。
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公开(公告)号：US4618633A
公开(公告)日：1986-10-21
申请号：US772662
申请日：1985-09-05
摘要： A halogen-free self-extinguishing thermoplastic composition comprising as the flame retardant, one or more phosphorus-containing compounds or elemental phosphorous, a polyphenylene ether, a styrene-acrylonitrile copolymer, a phenol/aldehyde resin, a terpolymer of styrene, acrylonitrile and a hydroxy-containing ester of acrylic or methacrylic acid on which a polyphenylene ether is grafted, and optionally, a diene elastomer having grafted thereon styrene and acrylonitrile monomers.
摘要翻译： 一种无卤自熄型热塑性组合物，其包含阻燃剂，一种或多种含磷化合物或元素磷，聚苯醚，苯乙烯 - 丙烯腈共聚物，苯酚/醛树脂，苯乙烯，丙烯腈和 含有聚苯醚的丙烯酸或甲基丙烯酸的含羟基酯，以及任选地，其上接枝有苯乙烯和丙烯腈单体的二烯弹性体。
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6.发明授权Thermoplastic molding compositions containing polycarbonate and an acrylate graft copolymer 失效含有聚碳酸酯和丙烯酸酯接枝共聚物的热塑性成型组合物
公开(公告)号：US4605699A
公开(公告)日：1986-08-12
申请号：US722155
申请日：1985-04-11
申请人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel , Josef Schwaab , Herbert Frank
发明人： Konrad Mitulla , Juergen Hambrecht , Adolf Echte , Johann Swoboda , Peter Siebel , Josef Schwaab , Herbert Frank
CPC分类号： C08L51/003 , C08L69/00 , Y10S525/902
摘要： A thermoplastic molding material consists of from 10 to 90 parts by weight of a polycarbonate A and from 90 to 10 parts by weight of a graft copolymer B having a mean particle size of from 200 to 700 nm (d.sub.50 value of the integral mass distribution). The graft polymer B is formed from an elastomer (rubber) (b.sub.1), which accounts for from 10 to 80% by weight, and a grafted shell (b.sub.2), which accounts for from 90 to 20% by weight, the percentages in each case being based on (B).The elastomer (b.sub.1) is composed of from 50 to 99.9% by weight of an alkyl acrylate, where alkyl is of 1 to 8 carbon atoms, and from 0.1 to 5% by weight of a copolymerizable polyfunctional crosslinking monomer.The grafted shell (b.sub.2) is produced in three stages and contains, as graft monomers,(b.sub.2 a.sub.1) from 5 to 40% by weight of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms, in the first stage,(b.sub.2 a.sub.2) from 15 to 50% by weight of a mixture of a monoethylenically unsaturated aromatic hydrocarbon of not more than 12 carbon atoms and a copolymerizable ethylenically unsaturated monomer, in a weight ratio of from 90:10 to 60:40, in the second stage, and(b.sub.2 a.sub.3) from 10 to 85% by weight of an alkyl (meth)acrylate in the third stage, the percentages in each case being based on (b.sub.2).
摘要翻译： 热塑性成型材料由10〜90重量份的聚碳酸酯A和90〜10重量份的平均粒径为200〜700nm的接枝共聚物B（整体质量分布的d50）组成， 。 接枝聚合物B由占总重量的10〜80重量％的弹性体（橡胶）（b1）和接枝壳（b2）的90〜20重量％构成。 情况基于（B）。 弹性体（b1）由50〜99.9重量％的丙烯酸烷基酯（其中烷基为1〜8个碳原子）和0.1〜5重量％的可共聚的多官能交联单体组成。 接枝壳（b2）分三个阶段制成，在第一阶段，（b2a2）含有5-40重量％的不大于12个碳原子的单烯属不饱和芳族烃作为接枝单体，（b2a1） 15重量％至50重量％的不超过12个碳原子的单烯属不饱和芳族烃和可共聚烯属不饱和单体的混合物，其重量比为90:10至60:40，第二阶段为 （b2a3）在第三阶段为10〜85重量％的（甲基）丙烯酸烷基酯，其各自的百分比基于（b2）。
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公开(公告)号：US4672086A
公开(公告)日：1987-06-09
申请号：US803585
申请日：1985-12-02
申请人： Erhard Seiler , Juergen Hambrecht , Gerhard Heinz
发明人： Erhard Seiler , Juergen Hambrecht , Gerhard Heinz
摘要： Self-extinguishing thermoplastic polyester molding materials containing linear aromatic polyesters, polyphenylene ethers and additives containA. from 20 to 50% by weight of polyethylene terephthalate and/or polybutylene terephthalate, as much as 20 mol % of which may be modified with other dicarboxylic acids and/or diols,B. from 10 to 40% by weight of one or more polyphenylene ethers,C. from 5 to 15% by weight of one or more alkali metal or alkaline earth metal phosphates, high-boiling phosphoric acid esters, phosphorous acid esters, phosphinic acid esters or phosphonous acid esters or organic phosphine oxides,D. from 5 to 30% by weight of framework-forming fillers,E. from 0 to 30% by weight of one or more aromatic polycarbonates,F. from 0 to 30% by weight of glass fibers,G. from 0 to 20% by weight of one or more elastomeric polymers,H. from 0 to 20% by weight of one or more styrene polymers, the percentages of components A to H summing to 100, andI. if required, additives in effective amounts.
摘要翻译： 含有线性芳族聚酯，聚苯醚和添加剂的自熄性热塑性聚酯成型材料含有A.20至50重量％的聚对苯二甲酸乙二醇酯和/或聚对苯二甲酸丁二醇酯，多达20摩尔％可用其它二羧酸改性 和/或二醇，B。10至40重量％的一种或多种聚苯醚，C.5至15重量％的一种或多种碱金属或碱土金属磷酸盐，高沸点磷酸酯，磷 酸酯，次膦酸酯或膦酸酯或有机膦氧化物，D为5至30重量％的骨架形成填料，E为0至30重量％的一种或多种芳族聚碳酸酯，F为0 至30重量％的玻璃纤维，G.0.0至20重量％的一种或多种弹性体聚合物，H为0至20重量％的一种或多种苯乙烯聚合物，组分A至H的百分比相对于 100和I.如果需要，添加剂 有效量。
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公开(公告)号：US4654418A
公开(公告)日：1987-03-31
申请号：US627984
申请日：1984-07-05
申请人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
发明人： Rosemarie Berger , Hermann Dreher , Juergen Hambrecht , Eduard Heil , Rudi W. Reffert , Johann Swoboda , Adolf Echte , Peter Siebel
CPC分类号： C08G65/46
摘要： The catalyst is removed in the preparation of high molecular weight polyphenylene ethers from monohydric phenols, which are alkyl-substituted at the two ortho-positions but not at the para-position and may or may not be alkyl-substituted at the meta-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. in the presence of a catalyst complex obtained from a copper salt and an organic amine, in the presence of from 1 to 20 parts by weight of a solvent per part by weight of the monomeric phenol, and in the presence or absence of an activator, and removal of the metal component of the catalyst from the polyphenylene ether solution with a complex-forming or chelate-forming compound in aqueous solution, in the presence or absence of reducing and stabilizing substances and assistants for accelerating the interphase reactions and for phase separation, by a method in which the continuous removal of the copper catalyst is carried out in one or more mixer-settler stages at a phase volume ratio of the organic phase to the aqueous phase of from 1:0.1 to 1:1.0, preferably from 1:0.4 to 1:0.6.
摘要翻译： 在从一元酚制备高分子量聚苯醚时除去催化剂，该二元酚在两个邻位进行烷基取代，而不是在对位，在间位可以是或不是烷基取代的， 在由铜盐和有机胺获得的催化剂配合物的存在下，在15〜50℃下，与氧气进行氧化偶合反应，每份由1〜20份重量的溶剂 单体苯酚的重量，并且在存在或不存在活化剂的情况下，在存在或不存在复合物形成或螯合形成化合物的情况下，在聚苯醚溶液中除去催化剂的金属组分 减少和稳定物质和辅助剂，用于加速相间反应和相分离，方法是连续除去铜催化剂的方法是在一个或多个混合沉淀器 以有机相与水相的相体积比为1:0.1至1:1.0，优选1:0.4至1:0.6。
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公开(公告)号：US4536567A
公开(公告)日：1985-08-20
申请号：US631948
申请日：1984-07-18
CPC分类号： C08G65/46
摘要： High molecular weight polyphenylene ethers are prepared from a monohydric phenol by an oxidative coupling reaction with oxygen in the presence of a catalyst complex obtained from a copper salt and an organic amine, and in the presence of a solvent, by a process in which the metal component of the catalyst is removed after the polymerization by adding one or more organic ammonium salts of the general formula ##STR1## where A.sup..crclbar. is an anion or polyanion of an organic carboxylic, sulfonic or phosphonic acid, R.sup.1 is hydrogen, R.sup.2 and R.sup.3 are each hydrogen, alkyl of 1 to 18 carbon atoms or aryl and R.sup.4 is alkyl of 1 to 18 carbon atoms or aryl.
摘要翻译： 在由铜盐和有机胺得到的催化剂配合物存在下，通过与氧的氧化偶联反应，在溶剂存在下，通过一种方法制备高分子量聚苯醚，其中金属 通过加入一种或多种通式为“IMAGE”的有机铵盐，其中A（ - ）是有机羧酸，磺酸或膦酸的阴离子或聚阴离子，R1是氢，R2和R2，并且 R3各自为氢，1至18个碳原子的烷基或芳基，R4为1至18个碳原子的烷基或芳基。
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公开(公告)号：US4440906A
公开(公告)日：1984-04-03
申请号：US337404
申请日：1982-01-06
IPC分类号： C08L25/00 , C08L25/04 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L51/06 , C08L71/00 , C08L71/12 , C08L61/04
CPC分类号： C08L25/00 , C08L51/003 , C08L71/123 , C08L51/04 , C08L71/12 , Y10S525/905
摘要： The use of tricyclodecenyl alcohol in place of other crosslinking agents for crosslinking the soft component of impact-resistant polystyrene based on a polystyrene-grafted poly(alkyl acrylate) improves the flow of mixtures of the said polystyrene with polyphenylene ethers.
摘要翻译： 基于聚苯乙烯接枝的聚（丙烯酸烷基酯），使用三环癸烯醇代替用于交联耐冲击聚苯乙烯的软组分的其它交联剂改善了所述聚苯乙烯与聚苯醚的混合物的流动。
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