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    METHOD AND REACTOR FOR THE PREPARATION OF METHANOL
    1.
    发明申请
    METHOD AND REACTOR FOR THE PREPARATION OF METHANOL 有权
    用于制备甲醇的方法和反应器

    公开(公告)号：US20100267848A1

    公开(公告)日：2010-10-21

    申请号：US12809016

    申请日：2009-02-12

    申请人： Christophe Duwig ,  Poul Erik Hojlund Nielsen ,  Max Thorhauge

    发明人： Christophe Duwig ,  Poul Erik Hojlund Nielsen ,  Max Thorhauge

    IPC分类号： C07C27/06 ,  B01J8/02

    CPC分类号： B01J8/0285 ,  B01J8/067 ,  B01J2208/00115 ,  B01J2208/00123 ,  B01J2208/00132 ,  B01J2208/00141 ,  B01J2208/0015 ,  C10G2/34 ,  C10G2/341 ,  C10G2300/4006 ,  C10G2300/4056

    摘要： Method and reactor for performing Fischer-Tropsch (FT) synthesis with controlled steam partial pressure by introducing cool points in the FT reactor, typically in form of cooled solid surfaces. At the surface, the low temperature will force condensation of the water into a liquid film. Thereby, the partial pressure of steam in the gas and reactor will not exceed significantly the vapour partial pressure at the liquid film and water from the gas stream will be removed as it is produced, i.e. steam induced deactivation is avoided. In addition, the decrease of hydrogen and carbon monoxide partial pressures due to dilution by steam will be kept low ensuring a constant high reaction rate.

    摘要翻译： 通过在FT反应器中引入冷点，通常以冷却的固体表面的形式，通过控制蒸汽分压进行费 - 托（FT）合成的方法和反应器。 表面上，低温会使水冷凝成液膜。 因此，气体和反应器中的蒸汽的分压不会显着地超过液体膜处的蒸气分压，并且来自气流的水将在产生时被去除，即避免蒸汽诱导的失活。 另外，由于蒸汽稀释而导致的氢气和一氧化碳分压的降低将保持较低，从而确保恒定的高反应速率。

    PROCESS FOR THE PREPARATION OF SYNTHESIS GAS FROM BLACK LIQUOR
    2.
    发明申请
    PROCESS FOR THE PREPARATION OF SYNTHESIS GAS FROM BLACK LIQUOR 有权
    从黑液中制备合成气的方法

    公开(公告)号：US20090282739A1

    公开(公告)日：2009-11-19

    申请号：US12431240

    申请日：2009-04-28

    申请人： Poul Erik Hojlund Nielsen ,  Bodil Voss

    发明人： Poul Erik Hojlund Nielsen ,  Bodil Voss

    IPC分类号： C10J3/46

    CPC分类号： C01B3/36 ,  C01B3/32 ,  C01B3/50 ,  C01B3/52 ,  C01B2203/0415 ,  C01B2203/047 ,  C01B2203/0475 ,  C07C41/01 ,  D21C11/125 ,  C07C43/043

    摘要： A process for the adjustment of the composition of a synthesis gas produced in a high temperature black liquor gasifier. The process includes the steps of (a) generating a gasifier effluent stream from black liquor in the gasifier by a blast and optionally an atomising stream; (b) optionally quenching the gasifier effluent stream with a gas stream to form a gas quenched effluent stream; (c) quenching the gasifier effluent of step (a) or the gas quenched effluent gas stream of step (b) with a water stream to form a raw synthesis gas; (d) further cooling and cleaning and separating the raw synthesis gas to form a purified unprocessed synthesis gas with an appropriate H2/CO ratio; (e) partly converting the purified synthesis gas to dimethyl ether in a synthesis section, producing at least a product stream of DME and a hydrogen rich purge stream of processed; (f) splitting and recycling individual or combinations of split streams of the processed or the unprocessed synthesis gas to step a and/or step (b); and recycling a by-product stream of CO2 being further generated in step (e) in part or completely to step (a) and/or step (b).

    摘要翻译： 用于调节在高温黑液气化器中生产的合成气的组成的方法。 该方法包括以下步骤：（a）通过鼓风和任选的雾化流从气化器中的黑液生成气化器流出物流; （b）任选地用气流骤冷气化器流出物流以形成气体骤冷流出物流; （c）用水流淬火步骤（a）的气化器流出物或步骤（b）的气体骤冷流出物气流，以形成原始合成气; （d）进一步冷却和清洗并分离原始合成气以形成具有合适H 2 / CO比的纯化未加工合成气; （e）在合成部分中部分地将纯化的合成气转化为二甲醚，至少产生DME的产物流和加氢的富氢吹扫流; （f）将经处理或未经处理的合成气的分流或分离流分离和回收到步骤a和/或步骤（b）; 并且在步骤（e）中再次产生副产物二氧化碳流，部分或完全是步骤（a）和/或步骤（b）。