摘要:
The application provides articles, systems, and methods for adsorbing and desorbing nitrogen oxides (NOx) at desired temperatures. The catalytic article comprises a NOx adsorber composition comprising a platinum group metal (PGM) component disposed on or impregnated in a support material, and a substrate, wherein the catalytic article further comprises a magnetic material capable of inductive heating in response to an applied alternating electromagnetic field. The catalytic article further comprises a conductor associated therewith for receiving current and generating an alternating electromagnetic field in response thereto, wherein the conductor is positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material. This field can inductively heat the magnetic material to heat the NOx adsorber composition to desorb the NOx from the NOx adsorber composition.
摘要:
Provided is a catalyst article comprising a substrate and a catalyst composition disposed on the substrate, the catalyst composition comprising a support material having supported thereon: one or more platinum group metals (PGMs); and a Ta-polyoxometalate (POM).
摘要:
A four-way conversion catalyst for the treatment of an exhaust gas stream of a gasoline engine, the catalyst comprising a porous wall flow filter substrate comprising an inlet end, an outlet end, a substrate axial length extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate, wherein the plurality of passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end; wherein in the pores of the porous internal walls and on the surface of the porous internal walls, which surface defines the interface between the porous internal walls and the passages, the catalyst comprises a three-way conversion catalytic coating comprising an oxygen storage compound and a platinum group metal supported on a refractory metal oxide; wherein in the pores of the porous internal walls, the three-way conversion catalytic coating is present as in-wall-coating and on the surface of the porous internal walls, the three-way conversion catalytic coating is present as on-wall-coating; wherein in addition to said three-way conversion catalytic coating, the catalyst comprises no further coating in the pores of the porous internal walls and no further coating on the surface of the porous internal walls.
摘要:
The invention provides a catalyst composition, including a mixture of catalytically active particles and a magnetic material, such as superparamagnetic iron oxide nanoparticles, capable of inductive heating in response to an applied alternating electromagnetic field. The catalytically active particles will typically include a base metal, platinum group metal, oxide of base metal or platinum group metal, or combination thereof, and will be adapted for use in various catalytic systems, such as diesel oxidation catalysts, catalyzed soot filters, lean NOx traps, selective catalytic reduction catalysts, ammonia oxidation catalysts, or three-way catalysts. The invention also includes a system and method for heating a catalyst material, which includes a catalyst article that includes the catalyst composition and a conductor for receiving current and generating an alternating electromagnetic field in response thereto, the conductor positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material.
摘要:
A method for preparing a metal-organic framework (MOF) comprising contacting one or more of a rare earth metal ion component with one or more of a tetratopic ligand component, sufficient to form a rare earth-based MOF for controlling moisture in an environment. A method of moisture control in an environment comprising adsorbing and/or desorbing water vapor in an environment using a MOF, the MOF including one or more of a rare earth metal ion component and one or more of a tetratopic ligand component. A method of controlling moisture in an environment comprising sensing the relative humidity in the environment comprising a MOF; and adsorbing water vapor on the MOF if the relative humidity is above a first level, sufficient to control moisture in an environment. The examples relate to a MOF created from 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (BTEB) as tetratopic ligand, 2-fluorobenzoic acid and Y(NO3)3, Tb(NO3)3 and Yb(NO3)3 as rare earth metals.
摘要:
A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.
摘要:
Described are catalytic articles comprising a substrate having a washcoat on the substrate, the washcoat containing a catalytic component having a first average (D50) particle size and a functional binder component having a second average (D50) particle size in the range of about 10 nm to about 1000 nm, wherein the ratio of the first average (D50) particle size to the second average (D50) particle size is greater than about 10:1. The catalytic articles are useful in methods and systems to purify exhaust gas streams from an engine.
摘要:
[Summary][Problem]The problem addressed by the present invention lies in providing an exhaust gas purification filter which can efficiently treat particulate matter in exhaust gas.[Solution]The present invention provides an exhaust gas purification filter including a substrate comprising a plurality of porous partitions, wherein the partitions form an exhaust gas flow path, a porous catalytic layer is provided on the partitions and the catalytic layer having a thickness of 10 μm or greater is provided over at least 20% of the total length of the partitions in the lengthwise direction thereof, and the catalytic layer having a thickness of 10 μm or greater is not present on the partitions 15 mm from an outflow side.
摘要:
An oxidation catalyst composite, methods and systems for the treatment of exhaust gas emissions from an advanced combustion engine, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) from a diesel engine and an advanced combustion diesel engine are disclosed. More particularly, washcoat compositions are disclosed comprising at least two washcoat layers, a first washcoat comprising a palladium component and a first support containing cerium and a second washcoat containing platinum and one or more molecular sieves.
摘要:
An emission control catalyst for treating an engine exhaust includes non-precious metal group (“NPGM”) mixed phase oxide catalyst having a mullite phase containing optionally in close contact with other metal oxides. The mixed phase catalyst may be included in one or more layers or zones of a multi-layered or multi-zoned emission control catalyst and optionally in combination with precious metal catalysts such as Pt, Pd and Au.