摘要:
A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which(i) an oxidic material comprising copper oxide, aluminum oxide and aluminum oxide is made available(ii) pulverulent metallic copper, copper flakes, pulverulent cement, graphite or a mixture thereof is added to the oxidic material, and(iii) the mixture resulting from (ii) is shaped to form a shaped body.
摘要:
The invention relates to a method for hydrogenation of an organic compound comprising at least one carbonyl group, whereby the organic compound is brought into contact with a moulded body in the presence of hydrogen. Said body may be produced by a method in which (i) an oxidic material is prepared, comprising copper oxide, aluminium oxide, and at least one oxide of lanthanum, tungsten, molybdenum, titanium, or zirconium, followed by (ii) addition of powdered metallic copper, copper platelets, powdered cement, graphite, mixtures or a mixture thereof with graphite to the oxidic material and (iii) moulding the mixture from (ii) to give a moulded body, characterised in that the moulded body is in the form of catalyst tablets or catalyst extrudates with a diameter d and/or height h
摘要:
The invention relates to a method for hydrogenation of an organic compound comprising at least one carbonyl group, whereby the organic compound is brought into contact with a moulded body in the presence of hydrogen. Said body may be produced by a method in which (i) an oxidic material is prepared, comprising copper oxide, aluminum oxide, and at least one oxide of lanthanum, tungsten, molybdenum, titanium, or zirconium, followed by (ii) addition of powdered metallic copper, copper platelets, powdered cement, graphite, mixtures or a mixture thereof with graphite to the oxidic material and (iii) moulding the mixture from (ii) to give a moulded body, characterised in that the moulded body is in the form of catalyst tablets or catalyst extrudates with a diameter d and/or height h
摘要:
Process for hydrogenating an organic compound having at least one carbonyl group, in which the organic compound is contacted, in the presence of hydrogen, with a shaped body which is producible in a process in which (i) an oxidic material comprising copper oxide and aluminum oxide and at least one of the oxides of iron, lanthanum, tungsten, molybdenum, titanium, zirconium, tin or manganese, and if appropriate additionally tin oxide and/or manganese oxide, is provided, (ii) pulverulent metallic copper, copper flakes, pulverulent cement, graphite or a mixture thereof are added to the oxidic material, (iii) the mixture resulting from (ii) is shaped to a shaped body and (iv) the shaped body is treated with water or steam.
摘要:
Catalysts comprising: a ground, spent (de)hydrogenation catalyst material present in an amount of 10 to 70% by weight based on the catalyst, the ground, spent catalyst material comprising iron oxide; and a fresh catalyst material present in an amount of 30 to 90% by weight based on the catalyst, the fresh catalyst material comprising iron oxide, wherein at least a portion of the iron oxide in the fresh catalyst material comprises a phase selected from the group consisting of hematite, potassium ferrite, and mixtures thereof are described along with processes for preparing and using the same.
摘要:
Catalysts comprising: a ground, spent (de)hydrogenation catalyst material present in an amount of 10 to 70% by weight based on the catalyst, the ground, spent catalyst material comprising iron oxide; and a fresh catalyst material present in an amount of 30 to 90% by weight based on the catalyst, the fresh catalyst material comprising iron oxide, wherein at least a portion of the iron oxide in the fresh catalyst material comprises a phase selected from the group consisting of hematite, potassium ferrite, and mixtures thereof are described along with processes for preparing and using the same.