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    LIGAND EXCHANGE THERMOCHROMIC SYSTEMS AND HIGH E LIGANDS FOR SAME
    6.
    发明申请
    LIGAND EXCHANGE THERMOCHROMIC SYSTEMS AND HIGH E LIGANDS FOR SAME 有权
    配套交换式热电偶系统和高电压配置

    公开(公告)号：US20120292581A1

    公开(公告)日：2012-11-22

    申请号：US13477736

    申请日：2012-05-22

    申请人： Harlan J. Byker ,  Paul H. Ogburn, JR. ,  Douglas A. Vander Griend ,  Brad S. Veldkamp ,  Derick D. Winkle

    发明人： Harlan J. Byker ,  Paul H. Ogburn, JR. ,  Douglas A. Vander Griend ,  Brad S. Veldkamp ,  Derick D. Winkle

    IPC分类号： C09K9/02

    CPC分类号： C09K9/02 ,  B32B17/10036 ,  B32B17/10174 ,  B32B17/10477 ,  B32B17/10651 ,  B32B17/10678 ,  B32B17/10761 ,  C09K2211/187 ,  G02F1/0147 ,  B32B17/10 ,  B32B2367/00 ,  B32B2369/00

    摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.In accordance with certain aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.

    摘要翻译： 描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。 所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如 温度变化。 根据本发明的某些方面，公开了包含具有特别有用配体的过渡金属离子的热致变色体系，例如膦化合物，通过三个氮原子配位的三齿配体，二齿配体或邻位受体吡啶单齿配位体。

    Multi-layer ligand exchange thermochromic systems
    8.
    发明授权
    Multi-layer ligand exchange thermochromic systems 有权
    多层配体交换热变色系统

    公开(公告)号：US07525717B2

    公开(公告)日：2009-04-28

    申请号：US11849659

    申请日：2007-09-04

    申请人： Harlan J. Byker ,  Frederick A. Millett ,  Paul H. Ogburn, Jr. ,  Douglas A. Vander Griend ,  Brad S. Veldkamp ,  Derick D. Winkle

    发明人： Harlan J. Byker ,  Frederick A. Millett ,  Paul H. Ogburn, Jr. ,  Douglas A. Vander Griend ,  Brad S. Veldkamp ,  Derick D. Winkle

    IPC分类号： G02F1/01 ,  G02F1/00 ,  G09G3/34 ,  C07F15/04

    CPC分类号： C09K9/02 ,  B32B17/10036 ,  B32B17/10174 ,  B32B17/10477 ,  B32B17/10651 ,  B32B17/10678 ,  B32B17/10761 ,  C09K2211/187 ,  G02F1/0147 ,  B32B17/10 ,  B32B2367/00 ,  B32B2369/00

    摘要： Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.In accordance with one aspect of the present invention, a thermochromic device is disclosed comprising at least two thermochromic layers when each thermochromic layer includes a polymer, at least one transition metal ion, at least one HεL ligand capable of forming a HεMLC with the transition metal ion and at least one LεL ligand capable of forming an LεMLC with the transition metal ion. In accordance with yet another aspect of the present invention, the thermochromic device further includes a separator between the first and second thermochromic layers to prevent intermixing of the contents of the layers.

    摘要翻译： 描述了随着系统温度的可逆变化，热致变色LETC，电磁辐射吸收率呈现可逆变化的系统的配位交换。 所描述的LETC系统包括一个或多于一个的过渡金属离子，其经历过渡金属离子周围的络合或配位性质的热诱导变化，从而系统改变其吸收电磁辐射的能力，如 温度变化。 根据本发明的一个方面，公开了一种热致变色装置，其包含至少两个热致变色层，当每个热变色层包括聚合物，至少一种过渡金属离子，至少一种能够与过渡金属形成HepsilonMLC的HepsilonL配体 离子和能够与过渡金属离子形成LepsilonMLC的至少一种Lepsilon配体。 根据本发明的另一方面，热致变色装置还包括在第一和第二热变色层之间的隔板，以防止层的内容物的混合。

    Electrochromic media for producing a preselected color and devices comprising same
    9.
    发明授权
    Electrochromic media for producing a preselected color and devices comprising same 有权
    用于产生预选颜色的电致变色介质和包括其的装置

    公开(公告)号：US06288825B1

    公开(公告)日：2001-09-11

    申请号：US09666001

    申请日：2000-09-19

    申请人： Harlan J. Byker ,  Thomas F. Guarr ,  Derick D. Winkle

    发明人： Harlan J. Byker ,  Thomas F. Guarr ,  Derick D. Winkle

    IPC分类号： G02F115

    CPC分类号： C07D213/22 ,  C07D241/36 ,  C07D241/46 ,  C09K9/02 ,  G02F1/1521

    摘要： Electrochromic compositions suitable for use in electrochromic media in electrochromic devices contain minimally two electrochromic compounds of the same redox type, whose redox potentials are greater than 30 mV. The lower redox potential electrochromic compound makes a large contribution to the absorbancy of the electrochromic medium despite being present in only minor concentration.

    摘要翻译： 适用于电致变色装置中的电致变色介质的电致变色组合物含有最少的两种相同氧化还原型的电致变色化合物，其氧化还原电位大于30mV。 较低的氧化还原电位电致变色化合物对电致变色介质的吸收性有很大的贡献，尽管仅存在微量的浓度。

    Electrochromic media for producing a preselected color and devices comprising same
    10.
    发明授权
    Electrochromic media for producing a preselected color and devices comprising same 有权
    用于产生预选颜色的电致变色介质和包括其的装置

    公开(公告)号：US06661559B2

    公开(公告)日：2003-12-09

    申请号：US09920686

    申请日：2001-08-02

    申请人： Harlan J. Byker ,  Thomas F. Guarr ,  Derick D. Winkle

    发明人： Harlan J. Byker ,  Thomas F. Guarr ,  Derick D. Winkle

    IPC分类号： G02F115

    CPC分类号： C07D213/22 ,  C07D241/36 ,  C07D241/46 ,  C09K9/02 ,  G02F1/1521

    摘要： Electrochromic compositions suitable for use in electrochromic media in electrochromic devices contain minimally two electrochromic compounds of the same redox type, whose redox potentials are greater than 30 mV. The lower redox potential electrochromic compounds makes a large contribution to the absorbancy of the electrochromic medium despite being present in only minor concentration.

    摘要翻译： 适用于电致变色装置中的电致变色介质的电致变色组合物含有最少的两种相同氧化还原型的电致变色化合物，其氧化还原电位大于30mV。 较低的氧化还原电位电致变色化合物对电致变色介质的吸收性有很大贡献，尽管仅存在微量的浓度。