利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

7 条记录 (耗时 0.026 秒)

    Thiocarbonylthio compound and free radical polymerization employing the same
    3.
    发明授权
    Thiocarbonylthio compound and free radical polymerization employing the same 有权
    硫羰硫基化合物和使用其的自由基聚合

    公开(公告)号：US07968743B2

    公开(公告)日：2011-06-28

    申请号：US12612067

    申请日：2009-11-04

    申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    IPC分类号： C07C327/02 ,  C08F2/00

    CPC分类号： C08F2/38 ,  C07C327/36

    摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R3 can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent containing CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

    摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R 3还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷硫基芳基或含有CN，CO，COOH，COOCH 3或杂环部分的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。

    Thiocarbonylthio compound and free radical polymerization employing the same
    4.
    发明授权
    Thiocarbonylthio compound and free radical polymerization employing the same 有权
    硫羰硫基化合物和使用其的自由基聚合

    公开(公告)号：US07632959B2

    公开(公告)日：2009-12-15

    申请号：US11136005

    申请日：2005-05-24

    申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    IPC分类号： C07C327/02

    CPC分类号： C08F2/38 ,  C07C327/36

    摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent contaning CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

    摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷基硫代芳基或与CN，CO，COOH，COOCH 3或杂环部分相连的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。

    THIOCARBONYLTHIO COMPOUND AND FREE RADICAL POLYMERIZATION EMPLOYING THE SAME
    5.
    发明申请
    THIOCARBONYLTHIO COMPOUND AND FREE RADICAL POLYMERIZATION EMPLOYING THE SAME 有权
    甲硫醇化合物和使用它的自由基聚合

    公开(公告)号：US20100048844A1

    公开(公告)日：2010-02-25

    申请号：US12612067

    申请日：2009-11-04

    申请人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    发明人： Kuo Chen Shih ,  Po Wen Chung ,  Mei Hua Wang

    IPC分类号： C08F2/00

    CPC分类号： C08F2/38 ,  C07C327/36

    摘要： A thiocarbonylthio compound and free radical polymerization employing the same. The thiocarbonylthio compound is represented by formula (I) or (II): wherein Z can be independently perfluoroalkyl, alkyl, haloalkyl, aryl, alkylaryl, haloalkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, alkoxyaryl, alkylsulfonyl, alkylsulfonylaryl, dialkylphosphinyl, or dialkylphosphinothioyl; R1 and R2 can be each independently hydrogen, alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl; R3 is alkyl, aryl, aminoalkyl, alkylamino, alkoxy or alkoxyaryl. Furthermore, R can also be alkyl, aryl, alkylaryl, arylalkyl, aminoalkyl, alkylamino, alkoxy, haloalkylaryl, alkylsilyl, alkylthio, alkylthioaryl, or substituent contaning CN, CO, COOH, COOCH3 or heterocyclic moieties; and R4 is perfluoroalkyl. The thiocarbonylthio compound can be used as a reversible chain transfer agent in a free radical polymerization to obtain a polymer with a controlled molecular weight and narrow polydispersity.

    摘要翻译： 硫代羰基硫代化合物和使用其的自由基聚合。 硫代羰基硫代化合物由式（I）或（II）表示：其中Z可以独立地为全氟烷基，烷基，卤代烷基，芳基，烷基芳基，卤代烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，烷氧基芳基，烷基磺酰基，烷基磺酰基芳基，二烷基氧膦基或二烷基膦硫基 ; R 1和R 2可各自独立地为氢，烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基; R3是烷基，芳基，氨基烷基，烷基氨基，烷氧基或烷氧基芳基。 此外，R还可以是烷基，芳基，烷基芳基，芳基烷基，氨基烷基，烷基氨基，烷氧基，卤代烷基芳基，烷基甲硅烷基，烷硫基，烷基硫代芳基或与CN，CO，COOH，COOCH 3或杂环部分相连的取代基; R4是全氟烷基。 硫羰基硫代化合物可以在自由基聚合中用作可逆链转移剂，以获得具有受控分子量和窄分散性的聚合物。