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    Organic electrolytic solution and lithium-sulfur battery comprising the same
    3.
    发明申请
    Organic electrolytic solution and lithium-sulfur battery comprising the same 有权
    有机电解液和含有它的锂硫电池

    公开(公告)号：US20050053842A1

    公开(公告)日：2005-03-10

    申请号：US10927188

    申请日：2004-08-27

    申请人： Young-Gyoon Ryu ,  Myung-Dong Cho ,  Sang-Mock Lee ,  Trofimov A.

    发明人： Young-Gyoon Ryu ,  Myung-Dong Cho ,  Sang-Mock Lee ,  Trofimov A.

    IPC分类号： H01M10/05 ,  H01M4/02 ,  H01M4/36 ,  H01M4/38 ,  H01M4/40 ,  H01M4/58 ,  H01M4/60 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

    CPC分类号： H01M10/0567 ,  H01M4/382 ,  H01M4/405 ,  H01M4/58 ,  H01M4/5815 ,  H01M4/60 ,  H01M4/602 ,  H01M10/052 ,  H01M2300/0025

    摘要： An organic electrolytic solution for a lithium-sulfur battery that can improve discharge capacity and cycle life of the battery, and a lithium-sulfur battery using the organic electrolytic solution are provided. The electrolytic solution includes a lithium salt, an organic solvent, and further a phosphine sulfide-based compound represented by formula (I) below: wherein R1, R2 and R3 are the same or different from each other, and each represents one selected from the group consisting of a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C1-C30 alkoxy group and a substituted or unsubstituted C8-C30 aralkenyl group. The electrolytic solution including the phosphine sulfide-based compound represented by Formula (I) can suppress production of lithium sulfides so that a reduction in battery capacity can be prevented.

    摘要翻译： 提供一种能够提高电池的放电容量和循环寿命的锂硫电池的有机电解液以及使用有机电解液的锂硫电池。 电解液包括锂盐，有机溶剂，以及下述式（I）表示的硫化
    膦系化合物：其中R1，R2和R3彼此相同或不同，并且各自表示选自 取代或未取代的C 1 -C 30烷基，取代或未取代的C 6 -C 30芳基，取代或未取代的C 1 -C 30烷氧基和取代或未取代的C 8 -C 30芳烯基。 包含由式（I）表示的硫化膦类化合物的电解液可以抑制硫化锂的生成，从而可以防止电池容量的降低。

    Organic electrolytic solution and lithium-sulfur battery comprising the same
    4.
    发明授权
    Organic electrolytic solution and lithium-sulfur battery comprising the same 有权
    有机电解液和含有它的锂硫电池

    公开(公告)号：US07338735B2

    公开(公告)日：2008-03-04

    申请号：US10927188

    申请日：2004-08-27

    申请人： Young-Gyoon Ryu ,  Myung-Dong Cho ,  Sang-Mock Lee ,  Boris A. Trofimov

    发明人： Young-Gyoon Ryu ,  Myung-Dong Cho ,  Sang-Mock Lee ,  Boris A. Trofimov

    IPC分类号： H01M4/74 ,  H01M4/36 ,  H01G9/02 ,  C07F9/02

    CPC分类号： H01M10/0567 ,  H01M4/382 ,  H01M4/405 ,  H01M4/58 ,  H01M4/5815 ,  H01M4/60 ,  H01M4/602 ,  H01M10/052 ,  H01M2300/0025

    摘要： An organic electrolytic solution for a lithium-sulfur battery that can improve discharge capacity and cycle life of the battery, and a lithium-sulfur battery using the organic electrolytic solution are provided. The electrolytic solution includes a lithium salt, an organic solvent, and further a phosphine sulfide-based compound represented by formula (I) below: wherein R1, R2 and R3 are the same or different from each other, and each represents one selected from the group consisting of a substituted or unsubstituted C1-C30 alkyl group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C1-C30 alkoxy group and a substituted or unsubstituted C8-C30 aralkenyl group. The electrolytic solution including the phosphine sulfide-based compound represented by Formula (I) can suppress production of lithium sulfides so that a reduction in battery capacity can be prevented.

    摘要翻译： 提供一种能够提高电池的放电容量和循环寿命的锂硫电池的有机电解液以及使用有机电解液的锂硫电池。 所述电解液包含锂盐，有机溶剂和下述式（I）表示的硫化
    合物化合物：其中R 1，R 2和R 2 3个彼此相同或不同，并且各自表示选自取代或未取代的C 1 -C 30烷基，取代或未取代的C 6 -C 30芳基，取代或未取代的C 1 -C 30芳基， 未取代的C 1 -C 30烷氧基和取代或未取代的C 8 -C 30芳烯基。 包含由式（I）表示的硫化膦类化合物的电解液可以抑制硫化锂的生成，从而可以防止电池容量的降低。

    Organic electrolytic solution and lithium battery employing the same
    7.
    发明授权
    Organic electrolytic solution and lithium battery employing the same 有权
    有机电解液和采用其的锂电池

    公开(公告)号：US08445142B2

    公开(公告)日：2013-05-21

    申请号：US12775997

    申请日：2010-05-07

    申请人： Dong-Joon Lee ,  Young-Gyoon Ryu ,  Dong-Min Im ,  Sook-Soo Lee

    发明人： Dong-Joon Lee ,  Young-Gyoon Ryu ,  Dong-Min Im ,  Sook-Soo Lee

    IPC分类号： H01M8/00

    CPC分类号： H01M10/0525 ,  H01M4/13 ,  H01M10/0567

    摘要： An organic electrolytic solution including a lithium salt, an organic solvent, and a compound represented by the formula and a lithium battery employing the organic electrolytic solution. Groups Z1 and Z2 are each, independently, a cyano group, an isocyano group, a substituted or unsubstituted dicyanoethylphosphino group, or a substituted or unsubstituted dialkoxyphosphoryloxy group. Groups R1 through R4 are described fully in the Description. The organic electrolyte solution inhibits decomposition of an electrolytic solution and elution or precipitation of metal ions, and thus the lithium battery including the organic electrolytic solution has excellent cycle characteristics and lifetime characteristics.

    摘要翻译： 包含锂盐，有机溶剂和下式表示的化合物的有机电解液和使用有机电解液的锂电池。 基团Z 1和Z 2各自独立地为氰基，异氰基，取代或未取代的二氰基乙基膦基或取代或未取代的二烷氧基磷酰氧基。 说明中完整描述了R1至R4组。 有机电解质溶液抑制电解液的分解和金属离子的析出或沉淀，因此包含有机电解液的锂电池具有优异的循环特性和寿命特性。

    Lithium-sulfur battery
    8.
    发明申请
    Lithium-sulfur battery 审中-公开
    锂硫电池

    公开(公告)号：US20050042503A1

    公开(公告)日：2005-02-24

    申请号：US10921850

    申请日：2004-08-20

    申请人： Ju-Yup Kim ,  Young-Gyoon Ryu

    发明人： Ju-Yup Kim ,  Young-Gyoon Ryu

    IPC分类号： H01M10/05 ,  H01M2/16 ,  H01M4/134 ,  H01M4/36 ,  H01M4/38 ,  H01M4/60 ,  H01M10/052 ,  H01M4/40 ,  H01M4/58

    CPC分类号： H01M10/052 ,  H01M2/166 ,  H01M2/1673 ,  H01M4/134 ,  H01M4/366 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/60

    摘要： A lithium-sulfur battery includes a cathode, a lithium metal anode, and a separator interposed between the cathode and the anode. The separator contains less than two fluorine atoms per carbon atom to enable a protective layer to form on a surface of the lithium metal anode. The lithium-sulfur battery forms a uniform and dense LiF protective layer on the surface of the lithium metal and stabilizes the lithium metal during its operation. The lithium-sulfur battery prevents the formation of lithium dendrites and inhibits the decomposition of an electrolytic solution to provide improved cycle characteristics and excellent charging/discharging efficiency. In addition, the lithium-sulfur battery blocks the reaction of polysulfide with the surface of lithium metal to prevent a reduction of the lifetime of the battery.

    摘要翻译： 锂硫电池包括阴极，锂金属阳极和介于阴极和阳极之间的隔膜。 隔膜每个碳原子含有少于两个氟原子，以便在锂金属阳极的表面上形成保护层。 锂硫电池在锂金属表面上形成均匀且致密的LiF保护层，并在其操作期间稳定锂金属。 锂硫电池防止锂枝晶的形成，并抑制电解液的分解，提供改善的循环特性和优异的充放电效率。 此外，锂 - 硫电池阻止多硫化物与锂金属表面的反应，以防止电池寿命的降低。

    Positive electrode having polymer film and lithium-sulfur battery employing the positive electrode
    9.
    发明授权
    Positive electrode having polymer film and lithium-sulfur battery employing the positive electrode 有权
    具有聚合物膜的正极和使用该正极的锂 - 硫电池

    公开(公告)号：US07078124B2

    公开(公告)日：2006-07-18

    申请号：US10924912

    申请日：2004-08-25

    申请人： Ju-Yup Kim ,  Myung-Dong Cho ,  Young-Gyoon Ryu

    发明人： Ju-Yup Kim ,  Myung-Dong Cho ,  Young-Gyoon Ryu

    IPC分类号： H01M2/18

    CPC分类号： H01M10/052 ,  H01M4/02 ,  H01M4/136 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/622 ,  H01M2004/028

    摘要： A positive electrode which has a positive active material layer formed on a conductive substrate and a polymer film coated on the positive active material layer, wherein the positive active material layer includes a positive active material, pores of which are filled with a polymeric material containing a nonaqueous electrolyte, and the polymer film, and the polymer film formed of the polymeric material containing the nonaqueous electrolyte. The polymeric material is formed by polymerization of a composition comprising a monomer and the nonaqueous electrolyte. The monomer includes 1 to 6 functional groups per molecule, and the functional groups are selected from the group consisting of vinyl, allyl, acryl, methacryl and epoxy group. Since the lithium-sulfur battery using the positive electrode increases degree of the positive active material utilization, the cycle life characteristics and capacity of the battery can be improved, and swelling of the positive electrode of the lithium-sulfur battery can be reduced.

    摘要翻译： 具有在导电性基材上形成的正极活性物质层和涂布在正极活性物质层上的聚合物膜的正极，其中所述正极活性物质层包含正极活性物质，其孔被填充有含有 非水电解质和聚合物膜，以及由含有非水电解质的聚合物材料形成的聚合物膜。 聚合物材料通过包含单体和非水电解质的组合物的聚合而形成。 单体每分子含有1〜6个官能团，官能团选自乙烯基，烯丙基，丙烯酰基，甲基丙烯酰基和环氧基。 由于使用正极的锂硫电池增加了正极活性物质利用的程度，因此可以提高电池的循环寿命特性和容量，并且可以降低锂硫电池的正极的膨胀。

    Positive electrode having polymer film and lithium-sulfur battery employing the positive electrode
    10.
    发明申请
    Positive electrode having polymer film and lithium-sulfur battery employing the positive electrode 有权
    具有聚合物膜的正极和使用该正极的锂 - 硫电池

    公开(公告)号：US20050175903A1

    公开(公告)日：2005-08-11

    申请号：US10924912

    申请日：2004-08-25

    申请人： Ju-Yup Kim ,  Myung-Dong Cho ,  Young-Gyoon Ryu

    发明人： Ju-Yup Kim ,  Myung-Dong Cho ,  Young-Gyoon Ryu

    IPC分类号： H01M2/16 ,  H01M4/134 ,  H01M4/136 ,  H01M4/38 ,  H01M4/58 ,  H01M4/60 ,  H01M4/62 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/40

    CPC分类号： H01M10/052 ,  H01M4/02 ,  H01M4/136 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/622 ,  H01M2004/028

    摘要： A positive electrode which has a positive active material layer formed on a conductive substrate and a polymer film coated on the positive active material layer, wherein the positive active material layer includes a positive active material, pores of which are filled with a polymeric material containing a nonaqueous electrolyte, and the polymer film, and the polymer film formed of the polymeric material containing the nonaqueous electrolyte. The polymeric material is formed by polymerization of a composition comprising a monomer and the nonaqueous electrolyte. The monomer includes 1 to 6 functional groups per molecule, and the functional groups are selected from the group consisting of vinyl, allyl, acryl, methacryl and epoxy group. Since the lithium-sulfur battery using the positive electrode increases degree of the positive active material utilization, the cycle life characteristics and capacity of the battery can be improved, and swelling of the positive electrode of the lithium-sulfur battery can be reduced.

    摘要翻译： 具有在导电性基材上形成的正极活性物质层和涂布在正极活性物质层上的聚合物膜的正极，其中所述正极活性物质层包含正极活性物质，其孔被填充有含有 非水电解质和聚合物膜，以及由含有非水电解质的聚合物材料形成的聚合物膜。 聚合物材料通过包含单体和非水电解质的组合物的聚合而形成。 单体每分子含有1〜6个官能团，官能团选自乙烯基，烯丙基，丙烯酰基，甲基丙烯酰基和环氧基。 由于使用正极的锂硫电池增加了正极活性物质利用的程度，因此可以提高电池的循环寿命特性和容量，并且可以降低锂硫电池的正极的膨胀。