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公开(公告)号：US20100326273A1
公开(公告)日：2010-12-30
申请号：US12875878
申请日：2010-09-03
IPC分类号： B01D53/22
CPC分类号： B01D67/0079 , B01D53/228 , B01D69/148 , B01D71/027 , B01D71/16 , B01D71/52 , B01D71/60 , B01D71/64 , B01D2323/30
摘要： This invention discloses a composition of, a method of making, and an application of high plasticization-resistant chemically cross-linked organic-inorganic hybrid membranes such as cross-linked cellulose acetate-cellulose triacetate-polyurethanepropylsilsesquioxane membranes. These cross-linked membranes with covalently interpolymer-chain-connected hybrid networks were prepared via a sol-gel condensation polymerization of cross-linkable organic polymer-organosilicon alkoxide precursor membrane materials. CO2 plasticization tests on these cross-linked membranes demonstrate extremely high CO2 plasticization resistance under CO2 pressure up to 5516 kPa (800 psig). These new cross-linked membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as desalination.
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公开(公告)号：US20100270234A1
公开(公告)日：2010-10-28
申请号：US12833193
申请日：2010-07-09
CPC分类号： B01D71/16 , B01D53/228 , B01D67/0006 , B01D67/0079 , B01D71/54 , B01D2323/30 , C08J5/2275 , C08J2375/04 , Y02P20/152
摘要： This invention discloses a composition of, a method of making, and an application of high plasticization-resistant chemically cross-linked organic-inorganic hybrid membranes such as cross-linked cellulose acetate-cellulose triacetate-polyurethanepropylsilsesquioxane membranes. These cross-linked membranes with covalently interpolymer-chain-connected hybrid networks were prepared via a sol-gel condensation polymerization of cross-linkable organic polymer-organosilicon alkoxide precursor membrane materials. CO2 plasticization tests on these cross-linked membranes demonstrate extremely high CO2 plasticization resistance under CO2 pressure up to 5516 kPa (800 psig). These new cross-linked membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as desalination.
摘要翻译： 本发明公开了一种组合物，制备和应用高增塑性化学交联的有机 - 无机杂化膜的组合物，例如交联的乙酸纤维素 - 三乙酸纤维素 - 聚氨酯丙基倍半硅氧烷膜。 通过可交联的有机聚合物 - 有机硅醇盐前体膜材料的溶胶 - 凝胶缩聚制备了具有共价互聚物链连接的杂化网络的这些交联膜。 这些交联膜上的二氧化碳增塑试验在二氧化碳压力高达5516 kPa（800 psig）下表现出极高的二氧化碳增塑性。 这些新的交联膜不仅可用于气体分离，如CO2 / CH4和CO2 / N2分离，O2 / N2分离，烯烃/石蜡分离（如丙烯/丙烷分离），异/正链烷烃分离， 用于液体分离，如脱盐。
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3.发明授权Crosslinked organic-inorganic hybrid membranes and their use in gas separation 有权交联的有机 - 无机杂化膜及其在气体分离中的应用公开(公告)号：US08030399B2
公开(公告)日：2011-10-04
申请号：US12847067
申请日：2010-07-30
IPC分类号： C08B37/00
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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4.发明申请CROSSLINKED ORGANIC-INORGANIC HYBRID MEMBRANES AND THEIR USE IN GAS SEPARATION 有权交联有机无机混合膜及其在气体分离中的应用公开(公告)号：US20100288122A1
公开(公告)日：2010-11-18
申请号：US12847067
申请日：2010-07-30
IPC分类号： B01D53/22
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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5.发明授权Crosslinked organic-inorganic hybrid membranes and their use in gas separation 有权交联的有机 - 无机杂化膜及其在气体分离中的应用公开(公告)号：US07790803B2
公开(公告)日：2010-09-07
申请号：US12131392
申请日：2008-06-02
IPC分类号： C07B37/00
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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6.发明授权Ionic liquid-solid-polymer mixed matrix membranes for gas separations 有权用于气体分离的离子液体 - 固体 - 聚合物混合基质膜公开(公告)号：US07943543B1
公开(公告)日：2011-05-17
申请号：US11537294
申请日：2006-09-29
CPC分类号： B01D53/228 , B01D67/0009 , B01D67/0011 , B01D67/0079 , B01D69/148 , B01D71/64 , B01D71/82 , B01D2323/08 , B01D2323/21 , B01D2323/46 , B01D2325/02 , Y02C10/10
摘要： New ionic liquid-solid-polymer mixed matrix membranes were proposed for gas separations such as CO2 removal from natural gas or N2. For the new mixed matrix membranes, the solids such as carbon molecular sieves, microporous molecular sieves, MCM-41 type of mesoporous molecular sieves, or polymer of intrinsic microporosity (PIM) are coated (or impregnated) with ionic liquids such as 1-butyl-3-methyl imidazolium bis[trifluoromethylsulfonyl]amide. The ionic liquids coated or impregnated solids are then dispersed in the continuous polymer matrix to form mixed matrix membranes. These hybrid mixed matrix membranes will combine the properties of the continuous polymer phase, the ionic liquids, and the dispersed ionic liquids coated or impregnated solids phase, which will possibly open up new opportunities for gas separation processes such as CO2 separation from natural gas or flue gas.
摘要翻译： 提出了新的离子液固固体混合基质膜用于气体分离，例如从天然气或N2中除去二氧化碳。 对于新的混合基质膜，将诸如碳分子筛，微孔分子筛，MCM-41型介孔分子筛或本征微孔聚合物（PIM）的固体用离子液体例如1-丁基 -3-甲基咪唑双[三氟甲磺酰基]酰胺。 然后将离子液体涂覆或浸渍的固体分散在连续聚合物基质中以形成混合基质膜。 这些混合混合基质膜将结合连续聚合物相，离子液体和分散的离子液体涂覆或浸渍的固体相的性质，这可能为气体分离过程（例如从天然气或烟道中分离CO 2）开辟新的机会 加油站。
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7.发明申请Crosslinked Organic-Inorganic Hybrid Membranes and Their Use in Gas Separation 有权交联有机无机杂化膜及其在气体分离中的应用公开(公告)号：US20090299015A1
公开(公告)日：2009-12-03
申请号：US12131392
申请日：2008-06-02
IPC分类号： C08L1/12
CPC分类号： C08L1/20 , B01D53/228 , B01D67/0079 , B01D71/00 , B01D71/16 , B01D71/52 , B01D71/70 , B01D2257/102 , B01D2257/504 , C08B7/00 , C08G65/33306 , C08G65/33351 , C08G65/336 , C08G2650/58 , C08L71/02 , Y02C10/10 , Y02P20/152
摘要： The present invention is for crosslinked membranes and in particular for crosslinked poly(ethylene oxide)-cellulose acetate-silsesquioxane (PEO-CA-Si) organic-inorganic hybrid membranes and their use in gas separation. These crosslinked PEO-CA-Si membranes were prepared by in-situ sol-gel co-condensation of crosslinkable PEO-organotrialkoxysilane and CA-organotrialkoxysilane polymers in the presence of acetic acid catalyst during the formation of membranes. The crosslinkable PEO- and CA-organotrialkoxysilane polymers were synthesized via the reaction between the hydroxyl groups on PEO (or on CA) and the isocyanate on organotrialkoxysilane to form urethane linkages under mild conditions. The crosslinked PEO-CA-Si membranes exhibited both increased selectivity of CO2/N2 and CO2 permeability as compared to a CA membrane, suggesting that these membranes are very promising for gas separations such as CO2/N2 separation.
摘要翻译： 本发明涉及交联膜，特别是交联聚（环氧乙烷） - 醋酸纤维素 - 倍半硅氧烷（PEO-CA-Si）有机 - 无机混合膜及其在气体分离中的应用。 这些交联的PEO-CA-Si膜通过在形成膜期间在乙酸催化剂存在下通过可交联的PEO-有机三烷氧基硅烷和CA-有机三烷氧基硅烷聚合物的原位溶胶 - 凝胶共缩合制备。 通过PEO（或CA）上的羟基与有机三烷氧基硅烷上的异氰酸酯之间的反应合成可交联PEO-和CA-有机三烷氧基硅烷聚合物，以在温和条件下形成氨基甲酸酯键。 与CA膜相比，交联的PEO-CA-Si膜显示出增加的CO 2 / N 2选择性和CO 2渗透性，这表明这些膜对于气体分离如CO 2 / N 2分离是非常有希望的。
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公开(公告)号：US20070209505A1
公开(公告)日：2007-09-13
申请号：US11679142
申请日：2007-02-26
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0079 , B01D69/141 , B01D69/147 , B01D71/028 , B01D71/72
摘要： The present invention discloses a new class of high flux mixed matrix membranes that are made by incorporating porous inorganic fillers (e.g. microporous and mesoporous molecular sieves, carbon molecular sieves, porous metal-organic frameworks) into a high flux high surface area microporous organic polymer matrix. These microporous organic polymers are referred to as “polymers of intrinsic microporosity” or PIMs. The high flux membranes are promising for a wide range of separations including liquid separations such as pervaporation of phenol/water and also gas separations in the petrochemical, refinery, and natural gas industries such as methane/carbon dioxide, olefin/paraffin and iso/normal paraffins separations.
摘要翻译： 本发明公开了一种新型高通量混合基质膜，其通过将多孔无机填料（例如微孔和介孔分子筛，碳分子筛，多孔金属 - 有机骨架）并入高通量高表面积微孔有机聚合物基体 。 这些微孔有机聚合物被称为“内在微孔聚合物”或PIM。 高通量膜对于广泛的分离是有希望的，包括液体分离，例如苯酚/水的渗透蒸发，以及在石化，炼油和天然气工业中的气体分离，例如甲烷/二氧化碳，烯烃/石蜡和异/正常 石蜡分离。
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9.发明授权Processes for olefin/paraffin separation utilizing porous, hydrophobic poly(ether ether ketone) membranes 有权使用多孔疏水性聚（醚醚酮）膜进行烯烃/石蜡分离的方法公开(公告)号：US08203028B2
公开(公告)日：2012-06-19
申请号：US12788595
申请日：2010-05-27
申请人： Santi Kulprathipanja , Chunqing Liu
发明人： Santi Kulprathipanja , Chunqing Liu
IPC分类号： C07C7/144
摘要： Processes for olefin/paraffin separation utilizing porous, hydrophobic poly(ether ether ketone) (PEEK) membranes are provided. In accordance with an exemplary embodiment, a process for olefin/paraffin separation comprises providing a porous membrane formed of PEEK polymer functionalized with hydrophobic groups, the porous membrane having a first surface and a second surface. The first surface of the porous membrane is contacted with a feed comprising an olefin and a paraffin and a permeate is caused to flow from the second surface of the porous membrane. The permeate has a concentration of the paraffin that is higher than a concentration of the paraffin of the feed.
摘要翻译： 提供利用多孔疏水性聚（醚醚酮）（PEEK）膜的烯烃/石蜡分离方法。 根据示例性实施方案，烯烃/石蜡分离方法包括提供由疏水基官能化的PEEK聚合物形成的多孔膜，所述多孔膜具有第一表面和第二表面。 多孔膜的第一表面与包含烯烃和石蜡的进料接触，使渗透物从多孔膜的第二表面流出。 渗透物的石蜡浓度高于饲料中石蜡的浓度。
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公开(公告)号：US07344585B1
公开(公告)日：2008-03-18
申请号：US11216823
申请日：2005-08-31
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D67/0079 , B01D69/10 , B01D69/141 , B01D69/148 , B01D71/028 , B01D71/16 , B01D71/70 , B01D2257/504 , B01D2257/7022 , B01D2323/20 , Y02C10/10
摘要： An improved mixed matrix membrane for the separation of gases comprises a nitrogen containing compound such as an amine, silicone rubber and activated carbon on a porous support. The membrane may also comprise a carbonate such as potassium carbonate and a plasticizer such as polyethylene glycol. Membranes of this design may be used in processing natural gas or other gases. The gases which may be separated by the membrane include mixtures of methane and carbon dioxide, mixtures of oxygen and nitrogen, and mixtures of carbon dioxide and nitrogen.
摘要翻译： 用于分离气体的改进的混合基质膜包括在多孔载体上的含氮化合物如胺，硅橡胶和活性炭。 膜还可以包含碳酸盐如碳酸钾和增塑剂如聚乙二醇。 该设计的膜可用于加工天然气或其他气体。 可以由膜分离的气体包括甲烷和二氧化碳的混合物，氧和氮的混合物，以及二氧化碳和氮气的混合物。
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