公开(公告)号：US20100291467A1

公开(公告)日：2010-11-18

申请号：US12718306

申请日：2010-03-05

申请人： Chunxin Ji ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Matthew Dioguardi

IPC分类号： B01J31/06 ,  H01M4/86

CPC分类号： H01M4/8807 ,  B82Y30/00 ,  H01M4/8605 ,  H01M4/8814 ,  H01M4/8817 ,  H01M4/8878 ,  H01M4/8892 ,  H01M2008/1095

摘要： A method of transferring nanostructured thin catalytic layers to a gas diffusion layer and thus making a catalyst coated diffusion media is described. The method includes treating the gas diffusion layer with a temporary adhesive to temporarily increase the adhesion strength within the microporous layer and to carbon fiber paper substrate, transferring the nanostructured thin catalytic layer to the microporous side of a gas diffusion media layer. The nanostructured thin catalytic layer can then be further processed, including adding additional components or layers to the nanostructured thin catalytic layer on the gas diffusion media layer. Preparation of catalyst coated diffusion media and a catalyst coated diffusion media based membrane electrode assembly (MEA) are also described.

摘要翻译： 描述了将纳米结构的薄催化层转移到气体扩散层并因此制备催化剂涂覆的扩散介质的方法。 该方法包括使用临时粘合剂处理气体扩散层，以暂时增加微孔层内的粘合强度和碳纤维纸基材，将纳米结构的薄催化层转移到气体扩散介质层的微孔侧。 然后可以进一步处理纳米结构的薄催化层，包括向气体扩散介质层上的纳米结构的薄催化剂层添加附加的组分或层。 还描述了制备催化剂涂覆的扩散介质和基于催化剂的扩散介质的膜电极组件（MEA）。

公开(公告)号：US08481231B2

公开(公告)日：2013-07-09

申请号：US12701095

申请日：2010-02-05

申请人： Chunxin Ji ,  Sumeet Bhargava ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Sumeet Bhargava ,  Matthew Dioguardi

IPC分类号： H01M4/02 ,  H01M4/36 ,  H01M8/00

CPC分类号： H01M4/9075 ,  H01M4/8807 ,  H01M4/881 ,  H01M4/8814 ,  H01M4/8828 ,  H01M4/90 ,  H01M8/1004 ,  H01M2008/1095 ,  Y02E60/50 ,  Y02E60/522

摘要： A method of making an electrode ink containing nanostructured catalyst elements is described. The method comprises providing an electrocatalyst decal comprising a carrying substrate having a nanostructured thin catalytic layer thereon, the nanostructure thin catalytic layer comprising nanostructured catalyst elements; providing a transfer substrate with an adhesive thereon; transferring the nanostructured thin catalytic layer from the carrying substrate to the transfer substrate; removing the nanostructured catalyst elements from the transfer substrate; providing an electrode ink solvent; and dispersing the nanostructured catalyst elements in the electrode ink solvent. Electrode inks, coated substrates, and membrane electrode assemblies made from the method are also described.

摘要翻译： 描述了制造含纳米结构催化剂元件的电极油墨的方法。 该方法包括提供一种电催化剂贴花，其包括在其上具有纳米结构的薄催化层的载体衬底，所述纳米结构薄催化层包含纳米结构的催化剂元素; 在其上提供具有粘合剂的转印衬底; 将纳米结构的薄催化层从载体衬底转移到转移衬底; 从转移基板去除纳米结构的催化剂元素; 提供电极油墨溶剂; 并将纳米结构的催化剂元素分散在电极油墨溶剂中。 还描述了由该方法制成的电极油墨，涂覆的基底和膜电极组件。

公开(公告)号：US20100291461A1

公开(公告)日：2010-11-18

申请号：US12701095

申请日：2010-02-05

申请人： Chunxin Ji ,  Sumeet Bhargava ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Sumeet Bhargava ,  Matthew Dioguardi

IPC分类号： H01M8/10 ,  H01M4/86 ,  H01M4/88

CPC分类号： H01M4/9075 ,  H01M4/8807 ,  H01M4/881 ,  H01M4/8814 ,  H01M4/8828 ,  H01M4/90 ,  H01M8/1004 ,  H01M2008/1095 ,  Y02E60/50 ,  Y02E60/522

摘要： A method of making an electrode ink containing nanostructured catalyst elements is described. The method comprises providing an electrocatalyst decal comprising a carrying substrate having a nanostructured thin catalytic layer thereon, the nanostructure thin catalytic layer comprising nanostructured catalyst elements; providing a transfer substrate with an adhesive thereon; transferring the nanostructured thin catalytic layer from the carrying substrate to the transfer substrate; removing the nanostructured catalyst elements from the transfer substrate; providing an electrode ink solvent; and dispersing the nanostructured catalyst elements in the electrode ink solvent. Electrode inks, coated substrates, and membrane electrode assemblies made from the method are also described.

摘要翻译： 描述了制造含纳米结构催化剂元件的电极油墨的方法。 该方法包括提供一种电催化剂贴花，其包括在其上具有纳米结构的薄催化层的载体衬底，所述纳米结构薄催化层包含纳米结构的催化剂元素; 在其上提供具有粘合剂的转印衬底; 将纳米结构的薄催化层从载体衬底转移到转移衬底; 从转移基板去除纳米结构的催化剂元素; 提供电极油墨溶剂; 并将纳米结构的催化剂元素分散在电极油墨溶剂中。 还描述了由该方法制成的电极油墨，涂覆的基底和膜电极组件。

公开(公告)号：US08802329B2

公开(公告)日：2014-08-12

申请号：US12465913

申请日：2009-05-14

申请人： Chunxin Ji ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Matthew Dioguardi

IPC分类号： H01M4/02 ,  H01M4/36 ,  H01M4/62 ,  H01M8/00

CPC分类号： H01M4/881 ,  H01M4/8807 ,  H01M4/8814 ,  H01M4/8828 ,  H01M8/1004 ,  H01M2008/1095 ,  Y02P70/56

摘要： A method of transferring a nanostructured thin catalytic layer from its carrying substrate to a porous transfer substrate and further processing and restructuring the nanostructured thin catalytic layer on the porous transfer substrate is provided. The method includes transferring the nanostructured catalytic layer from its carrying substrate to a transfer substrate. The nanostructured catalytic layer then is processed and reconstructed, including removing the residual materials and adding additional components or layers to the nanostructured catalytic layer, on the transfer substrate. Methods of fabricating catalyst coated membranes with the reconstructed electrode including the nanostructured thin catalytic layer, reconstructed electrode decals, and catalyst coated proton exchange membranes are also described.

摘要翻译： 提供将纳米结构的薄催化剂层从其承载基底转移到多孔转移基底并进一步处理和重组多孔转移基底上的纳米结构的薄催化层的方法。 该方法包括将纳米结构催化剂层从其承载基底转移到转移基底。 然后对纳米结构催化剂层进行处理和重建，包括在转移基板上除去残留的材料并向纳米结构的催化剂层添加额外的组分或层。 还描述了制备具有包括纳米结构薄催化层，重建电极贴花和催化剂涂覆的质子交换膜的重建电极的催化剂涂覆膜的方法。

公开(公告)号：US20110294037A1

公开(公告)日：2011-12-01

申请号：US12788915

申请日：2010-05-27

申请人： Chunxin Ji ,  Matthew Dioguardi ,  Sumeet Bhargava

发明人： Chunxin Ji ,  Matthew Dioguardi ,  Sumeet Bhargava

IPC分类号： H01M8/10 ,  H01M4/02

CPC分类号： H01M4/881 ,  H01M4/8814 ,  H01M4/92 ,  H01M8/1004 ,  Y02P70/56

摘要： A method of making an electrode is provided. The method includes providing an electrocatalyst decal comprising a carrying substrate having a nanostructured thin catalytic layer thereon; providing a transfer substrate with an adjacent adhesive layer; adhering the nanostructured thin catalytic layer adjacent to the adhesive layer to form a composite structure; removing the carrying substrate from the composite structure; and removing the transfer substrate from the composite structure to form the stand-alone nanostructured thin catalytic film comprising the adhesive layer with the nanostructured thin catalytic layer adhered thereto. A stand alone nanostructured thin catalytic film and methods of constructing electrodes with the stand alone nanostructured thin catalytic films are also described.

摘要翻译： 提供了制造电极的方法。 该方法包括提供一种电催化剂贴花，其中包括在其上具有纳米结构的薄催化剂层的承载基材; 提供具有相邻粘合剂层的转移基板; 将纳米结构的薄催化层附着在粘合剂层上以形成复合结构; 从复合结构中去除承载基底; 以及从复合结构中去除转印衬底以形成独立的纳米结构的薄催化膜，该薄膜包括粘附有纳米结构的薄催化层的粘合剂层。 还描述了独立的纳米结构的薄催化膜和用独立的纳米结构的薄催化膜构建电极的方法。

公开(公告)号：US08507152B2

公开(公告)日：2013-08-13

申请号：US12718330

申请日：2010-03-05

申请人： Chunxin Ji ,  Steven G. Goebel ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Steven G. Goebel ,  Matthew Dioguardi

IPC分类号： H01M4/02 ,  H01M8/00 ,  B44C1/165

CPC分类号： H01M4/8814 ,  H01M4/8807 ,  H01M4/881 ,  H01M4/8828 ,  H01M2008/1095

摘要： A method of making a reconstructed electrode having a plurality of nanostructured thin catalytic layers is provided. The method includes combining a donor decal comprising at least one nanostructured thin catalytic layer on a substrate with an acceptor decal comprising a porous substrate and at least one nanostructured thin catalytic layer. The donor decal and acceptor decal are bonded together using a temporary adhesive, and the donor substrate is removed. The temporary adhesive is then removed with appropriate solvents. Catalyst coated proton exchange membranes and catalyst coated diffusion media made from the reconstructed electrode decals having a plurality of nanostructured thin catalytic layers are also described.

摘要翻译： 提供了制造具有多个纳米结构的薄催化层的重建电极的方法。 该方法包括将包含至少一个纳米结构的薄催化剂层的施主贴图与包含多孔底物和至少一个纳米结构的薄催化层的受体贴片组合在一起。 供体贴花和接受体贴花使用临时粘合剂粘合在一起，并且移除供体底物。 然后用合适的溶剂除去临时粘合剂。 还描述了由具有多个纳米结构的薄催化层的重建电极贴片制成的催化剂涂覆的质子交换膜和由催化剂涂覆的扩散介质。

公开(公告)号：US08445164B2

公开(公告)日：2013-05-21

申请号：US12788915

申请日：2010-05-27

申请人： Chunxin Ji ,  Matthew Dioguardi ,  Sumeet Bhargava

发明人： Chunxin Ji ,  Matthew Dioguardi ,  Sumeet Bhargava

IPC分类号： H01M8/00 ,  H01M4/02 ,  H01M4/36 ,  H01M4/62 ,  H01M4/88

CPC分类号： H01M4/881 ,  H01M4/8814 ,  H01M4/92 ,  H01M8/1004 ,  Y02P70/56

摘要： A method of making an electrode is provided. The method includes providing an electrocatalyst decal comprising a carrying substrate having a nanostructured thin catalytic layer thereon; providing a transfer substrate with an adjacent adhesive layer; adhering the nanostructured thin catalytic layer adjacent to the adhesive layer to form a composite structure; removing the carrying substrate from the composite structure; and removing the transfer substrate from the composite structure to form the stand-alone nanostructured thin catalytic film comprising the adhesive layer with the nanostructured thin catalytic layer adhered thereto. A stand alone nanostructured thin catalytic film and methods of constructing electrodes with the stand alone nanostructured thin catalytic films are also described.

摘要翻译： 提供了制造电极的方法。 该方法包括提供一种电催化剂贴花，其中包括在其上具有纳米结构的薄催化剂层的承载基材; 提供具有相邻粘合剂层的转移基板; 将纳米结构的薄催化层附着在粘合剂层上以形成复合结构; 从复合结构中去除承载基底; 以及从复合结构中去除转印衬底以形成独立的纳米结构的薄催化膜，该薄膜包括粘附有纳米结构的薄催化层的粘合剂层。 还描述了独立的纳米结构的薄催化膜和用独立的纳米结构的薄催化膜构建电极的方法。

公开(公告)号：US20100291473A1

公开(公告)日：2010-11-18

申请号：US12718330

申请日：2010-03-05

申请人： Chunxin Ji ,  Steven G. Goebel ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Steven G. Goebel ,  Matthew Dioguardi

IPC分类号： H01M4/86 ,  B32B37/00

CPC分类号： H01M4/8814 ,  H01M4/8807 ,  H01M4/881 ,  H01M4/8828 ,  H01M2008/1095

摘要： A method of making a reconstructed electrode having a plurality of nanostructured thin catalytic layers is provided. The method includes combining a donor decal comprising at least one nanostructured thin catalytic layer on a substrate with an acceptor decal comprising a porous substrate and at least one nanostructured thin catalytic layer. The donor decal and acceptor decal are bonded together using a temporary adhesive, and the donor substrate is removed. The temporary adhesive is then removed with appropriate solvents. Catalyst coated proton exchange membranes and catalyst coated diffusion media made from the reconstructed electrode decals having a plurality of nanostructured thin catalytic layers are also described.

摘要翻译： 提供了制造具有多个纳米结构的薄催化层的重建电极的方法。 该方法包括将包含至少一个纳米结构的薄催化剂层的施主贴图与包含多孔底物和至少一个纳米结构的薄催化层的受体贴片组合在一起。 供体贴花和接受体贴花使用临时粘合剂粘合在一起，并且移除供体底物。 然后用合适的溶剂除去临时粘合剂。 还描述了由具有多个纳米结构的薄催化层的重建电极贴片制成的催化剂涂覆的质子交换膜和由催化剂涂覆的扩散介质。

公开(公告)号：US08512908B2

公开(公告)日：2013-08-20

申请号：US12718306

申请日：2010-03-05

申请人： Chunxin Ji ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Matthew Dioguardi

IPC分类号： H01M8/10 ,  H01M4/02 ,  H01M8/00 ,  B44C1/165 ,  B01J31/00

CPC分类号： H01M4/8807 ,  B82Y30/00 ,  H01M4/8605 ,  H01M4/8814 ,  H01M4/8817 ,  H01M4/8878 ,  H01M4/8892 ,  H01M2008/1095

摘要： A method of transferring nanostructured thin catalytic layers to a gas diffusion layer and thus making a catalyst coated diffusion media is described. The method includes treating the gas diffusion layer with a temporary adhesive to temporarily increase the adhesion strength within the microporous layer and to carbon fiber paper substrate, transferring the nanostructured thin catalytic layer to the microporous side of a gas diffusion media layer. The nanostructured thin catalytic layer can then be further processed, including adding additional components or layers to the nanostructured thin catalytic layer on the gas diffusion media layer. Preparation of catalyst coated diffusion media and a catalyst coated diffusion media based membrane electrode assembly (MEA) are also described.

摘要翻译： 描述了将纳米结构的薄催化层转移到气体扩散层并因此制备催化剂涂覆的扩散介质的方法。 该方法包括使用临时粘合剂处理气体扩散层，以暂时增加微孔层内的粘合强度和碳纤维纸基材，将纳米结构的薄催化层转移到气体扩散介质层的微孔侧。 然后可以进一步处理纳米结构的薄催化层，包括向气体扩散介质层上的纳米结构的薄催化剂层添加附加的组分或层。 还描述了制备催化剂涂覆的扩散介质和基于催化剂的扩散介质的膜电极组件（MEA）。

公开(公告)号：US20100291463A1

公开(公告)日：2010-11-18

申请号：US12465913

申请日：2009-05-14

申请人： Chunxin Ji ,  Matthew Dioguardi

发明人： Chunxin Ji ,  Matthew Dioguardi

IPC分类号： H01M8/10 ,  H01M4/86 ,  B32B37/02 ,  B44C1/165

CPC分类号： H01M4/881 ,  H01M4/8807 ,  H01M4/8814 ,  H01M4/8828 ,  H01M8/1004 ,  H01M2008/1095 ,  Y02P70/56

摘要： A method of transferring a nanostructured thin catalytic layer from its carrying substrate to a porous transfer substrate and further processing and restructuring the nanostructured thin catalytic layer on the porous transfer substrate is provided. The method includes transferring the nanostructured catalytic layer from its carrying substrate to a transfer substrate. The nanostructured catalytic layer then is processed and reconstructed, including removing the residual materials and adding additional components or layers to the nanostructured catalytic layer, on the transfer substrate. Methods of fabricating catalyst coated membranes with the reconstructed electrode including the nanostructured thin catalytic layer, reconstructed electrode decals, and catalyst coated proton exchange membranes are also described.

摘要翻译： 提供将纳米结构的薄催化剂层从其承载基底转移到多孔转移基底并进一步处理和重组多孔转移基底上的纳米结构的薄催化层的方法。 该方法包括将纳米结构催化剂层从其承载基底转移到转移基底。 然后对纳米结构催化剂层进行处理和重建，包括在转移基板上除去残留的材料并向纳米结构的催化剂层添加额外的组分或层。 还描述了制备具有包括纳米结构薄催化层，重建电极贴花和催化剂涂覆的质子交换膜的重建电极的催化剂涂覆膜的方法。