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公开(公告)号:US20210261854A1
公开(公告)日:2021-08-26
申请号:US17319414
申请日:2021-05-13
Applicant: ConocoPhilips Company , University of Kansas
Inventor: Huili Guan , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , David R. ZORNES , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , James P. JOHNSON , Faye L. SCULLY
IPC: C09K8/588 , C09K8/88 , C09K8/92 , E21B33/138
Abstract: The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g, in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.
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公开(公告)号:US20190256764A1
公开(公告)日:2019-08-22
申请号:US16398853
申请日:2019-04-30
Applicant: ConocoPhilips Company , University of Kansas
Inventor: Huili S. Guan , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , David R. ZORNES , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , James P. JOHNSON , Faye L. SCULLY
IPC: C09K8/588 , C09K8/92 , C09K8/88 , E21B33/138
Abstract: The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g, in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.
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公开(公告)号:US20140238702A1
公开(公告)日:2014-08-28
申请号:US14173901
申请日:2014-02-06
Applicant: University of Kansas , ConocoPhillips Comapny
Inventor: Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. Hedges , Min CHENG , Faye L. SCULLY
CPC classification number: C09K8/588 , C08F220/56 , C08F2800/10 , C08L33/26 , C09K8/594 , E21B33/138 , E21B43/164 , Y02P90/70
Abstract: The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.
Abstract translation: 本发明涉及在酸性pH下自交联或可在盐水中由酚类试剂进行交联的聚合物。 这样的聚合物具有较低的粘度并且可以深入泵入储层,在那里它们将原位交联,从而增加其粘度和/或形成凝胶并阻止小偷区。 还提供了制备和使用这些聚合物的方法。
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公开(公告)号:US20210388255A1
公开(公告)日:2021-12-16
申请号:US17412152
申请日:2021-08-25
Applicant: ConocoPhillips Company , University of Kansas
Inventor: Ying-Ying LIN , Cory BERKLAND , Jenn-Tai LIANG , Ahmad MORADI-ARAGHI , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY , David R. ZORNES
Abstract: The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.
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公开(公告)号:US20180002592A1
公开(公告)日:2018-01-04
申请号:US15708034
申请日:2017-09-18
Applicant: ConocoPhillips Company , University of Kansas
Inventor: Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , Min CHENG , Faye Lynn SCULLY , James H. HEDGES
Abstract: The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.
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公开(公告)号:US20160244658A1
公开(公告)日:2016-08-25
申请号:US15145842
申请日:2016-05-04
Applicant: CONOCOPHILLIPS COMPANY , University of Kansas
Inventor: Ahmad MORADI-ARAGHI , Min CHENG , Riley B. NEEDHAM , James H. HEDGES , Ramesh S. SARATHI , Faye L. SCULLY , Terry M. CHRISTIAN , Huili GUAN , Cory BERKLAND , Jenn-Tai LIANG
IPC: C09K8/588 , E21B43/16 , E21B33/138
CPC classification number: C09K8/588 , E21B33/138 , E21B43/16
Abstract: The invention is directed to stable and labile crosslinked water swellable polymeric microparticles that can be further gelled, methods for making same, and their various uses in the hygiene and medical arts, gel electrophoresis, packaging, agriculture, the cable industry, information technology, in the food industry, papermaking, use as flocculation aids, and the like. More particularly, the invention relates to a composition comprising expandable polymeric microparticles having labile crosslinkers and stable crosslinkers, said microparticle mixed with a fluid and an unreacted tertiary crosslinker comprising PEI or other polyamine based tertiary crosslinker that is capable of further crosslinking the microparticle on degradation of the labile crosslinker and swelling of the particle, so as to form a stable gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric microparticles are injected into a well and when the heat and/or pH of the well cause degradation of the labile crosslinker and when the microparticle expands, the tertiary crosslinker crosslinks the polymer to form a stable gel, thus diverting water to lower permeability regions and improving oil recovery.
Abstract translation: 本发明涉及可以进一步凝胶化的稳定和不稳定的交联水溶胀性聚合物微粒,其制备方法及其在卫生和医学领域,凝胶电泳,包装,农业,电缆工业,信息技术, 食品工业,造纸,用作絮凝助剂等。 更具体地说,本发明涉及包含具有不稳定交联剂和稳定交联剂的可膨胀聚合物微粒的组合物,所述微粒与流体混合,以及包含PEI或其它聚胺基三级交联剂的未反应的叔交联剂,其能够在降解时进一步交联微粒 不稳定的交联剂和颗粒的溶胀,从而形成稳定的凝胶。 特别重要的用途是作为石油生产中的注入流体,其中将可发性聚合物微粒注入井中,并且当井的热和/或pH引起不稳定交联剂的降解时,并且当微粒膨胀时,三价交联剂交联 聚合物形成稳定的凝胶,从而将水转移到渗透率较低的区域,并提高油的回收率。
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公开(公告)号:US20140202693A1
公开(公告)日:2014-07-24
申请号:US14143169
申请日:2013-12-30
Applicant: The University of Kansas , CONOCOPHILLIPS COMPANY
Inventor: Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. Needham , Min CHENG , Faye Lynn SCULLY , James H. HEDGES
IPC: C09K8/588
Abstract: The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.
Abstract translation: 本申请涉及保持多价金属离子直到发生一定程度的纳米凝胶降解的纳米凝胶或组合物,然后用含羧酸酯的聚合物缓慢释放多价金属离子用于凝胶化。 包含这些纳米凝胶的组合物以及可与多价金属离子交联的聚合物允许在各种应用中部署这些混合物,并大大增加凝胶化时间。
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公开(公告)号:US20190382646A1
公开(公告)日:2019-12-19
申请号:US16527958
申请日:2019-07-31
Applicant: CONOCOPHILLIPS COMPANY , University of Kansas
Inventor: Huili GUAN , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY
IPC: C09K8/588 , C08F220/56 , C08L33/26 , E21B33/138 , E21B43/16 , C09K8/594
Abstract: The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.
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公开(公告)号:US20160115371A1
公开(公告)日:2016-04-28
申请号:US14989350
申请日:2016-01-06
Applicant: ConocoPhillips Company , University of Kansas
Inventor: Stephen J. JOHNSON , Cory BERKLAND , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , Min CHENG , Ying-Ying LIN , Andrew B. WOODSIDE
CPC classification number: C09K8/588 , C09K8/035 , C09K8/524 , C09K8/528 , C09K8/584 , C09K8/604 , C09K2208/10 , C09K2208/22 , C09K2208/32 , E21B43/16
Abstract: The disclosure is directed to low molecular weight polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.
Abstract translation: 本公开涉及可用于将试剂深入烃储层的低分子量聚电解质复合纳米颗粒。 还提供了制备和使用所述聚电解质复合纳米颗粒的方法。
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10.
公开(公告)号:US20140196894A1
公开(公告)日:2014-07-17
申请号:US14059580
申请日:2013-10-22
Applicant: University of Kansas , ConocoPhillips Company
Inventor: Cory BERKLAND , Huili GUAN , Ahmad MORADI-ARAGHI , Jenn-Tai LIANG , Terry M. CHRISTIAN , Riley B. NEEDHAM , James H. HEDGES , Min CHENG , Faye L. SCULLY
IPC: C09K8/588
Abstract: The invention is directed to stable crosslinked swellable fluorescently tagged polymeric microparticles, methods for making same, and their various uses. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the microparticles expand. The swelled polymer diverts water to lower permeability regions and improves oil recovery. The tags allow monitoring of the presence and concentration of the tagged microparticles and ultimately allow evaluation of the performance of such treatments. Detection of polymeric microparticles in producing wells can be instructive for teaching about the character and extent of thief zones in the subsurface. Better knowledge of the reservoir flow will enable improved application of the gel treatments, improved oil recovery, and allow improved forecasting using simulation modeling.
Abstract translation: 本发明涉及稳定的交联可溶胀荧光标记的聚合物微粒,其制备方法及其各种用途。 特别重要的用途是作为石油生产中的注射液,其中将可发性聚合物颗粒注入目标区域,并且当目标区域的热和/或合适的pH导致不稳定交联剂的降解和微粒膨胀时。 溶胀的聚合物将水转移到渗透性较低的区域,并改善油的回收率。 标签允许监测标记的微粒的存在和浓度,并且最终允许评价这些处理的性能。 在生产井中检测聚合物微粒可能有助于教授地下小偷区域的特征和程度。 更好地了解储层流动将有助于改进凝胶处理的应用,改善石油采收率,并允许使用模拟建模改进预测。
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