Abstract:
The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, such as spreadability on the skin, moist feeling, and softness, and having high stability such that such tactile impression is kept over a long period of time, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability. The present invention also provides various types of products, such as a cosmetic, using the resin beads. The resin beads are obtained by surface-treating, with a solid surface treatment agent, core beads formed with a resin containing cellulose as a main component, and have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, and a degree of crystallinity of 60% or less. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.
Abstract:
The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.
Abstract:
The present invention provides resin beads that are capable of imparting stable water repellency and oil absorbency at a high level to products, and realizing good spreadability and excellent persistence of makeup without giving sticky feeling when added to, for example, cosmetic materials, the process for producing the resin beads, and various kinds of products using the resin beads and having excellent properties. Resin beads being resin particles obtained by subjecting a monomer mixture containing a plurality of monomers each having a copolymerizable functional group to suspension polymerization in a state where at least a non-polymerizable silicone compound is present, the resin particles each having a roughened surface, and a process for producing the resin beads, and various kinds of products each using the resin beads and each having excellent properties.
Abstract:
The present invention provides resin beads that are capable of realizing a water repellent and oil repellent effect, and further, that are also capable of providing cosmetic materials excellent in persistence of makeup when added and used in cosmetic materials etc. because the resin beads themselves contain silicone in a fixed state, and the present invention also provides a process for producing the resin beads. Resin beads being resin particles (a copolymer) obtained by subjecting a monomer mixture containing a plurality of monomers each having a copolymerizable functional group to suspension polymerization in a state where at least a non-polymerizable silicone is present, the resin particles containing the silicon in a fixed state, and a process for producing the resin beads.
Abstract:
The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.
Abstract:
The present invention provides resin beads that can provide various types of products such as cosmetics which are unlikely to generate an odor and have superior tactile impression and spreadability on the skin and that can be substituted for resin particles composed of a synthetic material derived from petroleum, and the present invention also provides various types of products such as cosmetics using the resin beads. The resin beads are formed with a resin containing a cellulose derivative as a main component. In the resin beads, the cellulose derivative is at least one selected from the group consisting of cellulose acetate, cellulose acetate propionate, ethyl cellulose, and hydroxypropyl methyl cellulose, the volume average particle diameter is 50 μm or smaller, the degree of sphericity is 0.7 to 1.0, the degree of surface smoothness is 80 to 100%, the acetyl group content ratio is 15% by mass or less, and the propionyl group content ratio is 10% by mass or more. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition, which contain the resin beads.
Abstract:
The present invention provides a method for producing resin beads which can provide various types of products, such as cosmetics, imparted with superior tactile impression, spreadability on the skin, transparency, and product stability, and which can be substituted for resin particles composed of a synthetic material derived from petroleum. The method is a method for producing resin beads containing a cellulose derivative as a main component. The production method includes: a suspension preparation step of mixing an oil phase containing the cellulose derivative and an organic solvent that dissolves the cellulose derivative, the organic solvent having a water-solubility of 0.1 to 50.0 g, and an aqueous phase containing a dispersion stabilizer, thereby preparing a suspension containing oil droplets containing the cellulose derivative and the organic solvent; and an oil droplet contraction step of adding water to the suspension, thereby contracting the oil droplets, wherein the water is added to the suspension in such a way as to satisfy the following expression (A) until a content of the organic solvent in the suspension becomes equal to or less than the water-solubility of the organic solvent. (W/S)/T≤1.00 (A), wherein W: an addition amount of water (parts by mass), S: an amount of the suspension (parts by mass), and T: a time (minutes) required for addition.