公开(公告)号：US08734945B2

公开(公告)日：2014-05-27

申请号：US13868017

申请日：2013-04-22

Applicant: DSM IP Assets B.V.

Inventor： Wendell Wayne Cattron ,  Steven Robert Schmid ,  Edward Joseph Murphy ,  John Monroe Zimmerman ,  Anthony Joseph Tortorello

IPC: B32B9/00 ,  D02G3/00 ,  C08F283/10 ,  C08F20/22

CPC classification number: G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

Abstract translation: 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US08731366B2

公开(公告)日：2014-05-20

申请号：US13797908

申请日：2013-03-12

Applicant: DSM IP Assets B.V.

Inventor： Xiaosong Wu ,  Steven Robert Schmid ,  Timothy Edward Bishop ,  John Monroe Zimmerman ,  Wendell Wayne Cattron ,  Edward Joseph Murphy ,  Pratik Shah

IPC: G02B6/00

CPC classification number: G02B1/10 ,  B05D1/42 ,  C03C25/1065 ,  C03C25/12 ,  C08G18/4866 ,  C08G18/672 ,  C09D175/16 ,  G02B1/046 ,  G02B6/02395 ,  Y10T428/2933 ,  C08G18/48

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract translation: 本发明的第一方面是一种配制可辐射固化的超涂层以应用于在电信网络中使用的光纤的方法。 还描述并要求保护用于配制可辐射固化的超涂层的方法中的多层薄膜缩小方法。 单模式也描述和要求保护涂覆有特定可辐射固化的超涂层的光纤。

公开(公告)号：US08724956B2

公开(公告)日：2014-05-13

申请号：US13797935

申请日：2013-03-12

Applicant: DSM IP Assets B.V.

Inventor： Xiaosong Wu ,  Steven Robert Schmid ,  Timothy Edward Bishop ,  John Monroe Zimmerman ,  Wendell Wayne Cattron ,  Edward Joseph Murphy ,  Pratik Shah

IPC: G02B6/00

CPC classification number: G02B1/10 ,  B05D1/42 ,  C03C25/1065 ,  C03C25/12 ,  C08G18/4866 ,  C08G18/672 ,  C09D175/16 ,  G02B1/046 ,  G02B6/02395 ,  Y10T428/2933 ,  C08G18/48

Abstract: The first aspect of the instant claimed invention is a method of formulating radiation curable Supercoatings for application to an optical fiber used in a telecommunications network. A Multi-layer Film Drawdown Method useful in the Method of formulating radiation curable Supercoatings is also described and claimed. Single mode Optical fibers coated with specific radiation curable Supercoatings are also described and claimed.

Abstract translation: 本发明的第一方面是一种配制可辐射固化的超涂层以应用于在电信网络中使用的光纤的方法。 还描述并要求保护用于配制可辐射固化的超涂层的方法中的多层薄膜缩小方法。 单模式也描述和要求保护涂覆有特定可辐射固化的超涂层的光纤。

公开(公告)号：US09062083B2

公开(公告)日：2015-06-23

申请号：US13802476

申请日：2013-03-13

Applicant: DSM IP Assets B.V.

Inventor： Timothy Edward Bishop ,  Edward Joseph Murphy ,  John Edmond Southwell ,  Satyendra Sarmah ,  TaiYeon Lee

IPC: C08F2/46 ,  C08B37/00 ,  C08F2/50 ,  B29C71/04 ,  A61L24/00 ,  A61L2/08 ,  C08G61/04 ,  C07F9/50 ,  C03C25/10 ,  C03C25/24 ,  C04B41/00 ,  C04B41/48 ,  C04B41/63 ,  C07F9/53 ,  C08F2/40 ,  C09D133/08 ,  C08K5/50 ,  C08F222/10

CPC classification number: C07F9/5036 ,  C03C25/1055 ,  C03C25/106 ,  C03C25/25 ,  C04B41/009 ,  C04B41/483 ,  C04B41/63 ,  C07F9/5337 ,  C08F2/40 ,  C08F2/50 ,  C08F222/1006 ,  C08K5/50 ,  C09D133/08 ,  C04B28/02 ,  C04B41/0045 ,  C08F2220/302 ,  C08F226/06 ,  C08F2220/281 ,  C08F220/06

Abstract: The invention relates to radiation curable compositions comprising a liquid 0/s(acyl)phosphine photo initiators of formula (I): wherein each of Ar1, Ar2 and Ar3 is independently a substituted or unsubstituted aryl group. The invention also relates to stabilized forms of liquid bis(acyl)phosphines of formula (I) and radiation curable composition comprising said stabilized photoinitiators. The radiation curable compositions are selected from the group consisting of an optical fiber coating composition and a coating composition capable of radiation cure on concrete and a coating composition capable of radiation cure on metal.

Abstract translation: 本发明涉及包含式（I）的液体0 / s（酰基）膦光引发剂的可辐射固化组合物：其中Ar1，Ar2和Ar3各自独立地为取代或未取代的芳基。 本发明还涉及式（I）的液体双（酰基）膦的稳定形式和包含所述稳定的光引发剂的可辐射固化组合物。 可辐射固化组合物选自光纤涂层组合物和能够在混凝土上辐射固化的涂料组合物和能够在金属上辐射固化的涂料组合物。

公开(公告)号：US20130237626A1

公开(公告)日：2013-09-12

申请号：US13802476

申请日：2013-03-13

Applicant: DSM IP ASSETS B.V.

Inventor： Timothy Edward BISHOP ,  Edward Joseph Murphy ,  John Edmond Southwell ,  Satyendra Sarmah ,  TaiYeon Lee

IPC: C07F9/50

CPC classification number: C07F9/5036 ,  C03C25/1055 ,  C03C25/106 ,  C03C25/25 ,  C04B41/009 ,  C04B41/483 ,  C04B41/63 ,  C07F9/5337 ,  C08F2/40 ,  C08F2/50 ,  C08F222/1006 ,  C08K5/50 ,  C09D133/08 ,  C04B28/02 ,  C04B41/0045 ,  C08F2220/302 ,  C08F226/06 ,  C08F2220/281 ,  C08F220/06

Abstract: The invention relates to radiation curable compositions comprising a liquid 0/s(acyl)phosphine photo initiators of formula (I): wherein each of Ar1, Ar2 and Ar3 is independently a substituted or unsubstituted aryl group. The invention also relates to stabilized forms of liquid bis(acyl)phosphines of formula (I) and radiation curable composition comprising said stabilized photoinitiators. The radiation curable compositions are selected from the group consisting of an optical fiber coating composition and a coating composition capable of radiation cure on concrete and a coating composition capable of radiation cure on metal.

Abstract translation: 本发明涉及包含式（I）的液体0 / s（酰基）膦光引发剂的可辐射固化组合物：其中Ar1，Ar2和Ar3各自独立地为取代或未取代的芳基。 本发明还涉及式（I）的液体双（酰基）膦的稳定形式和包含所述稳定的光引发剂的可辐射固化组合物。 可辐射固化组合物选自光纤涂层组合物和能够在混凝土上辐射固化的涂料组合物和能够在金属上辐射固化的涂料组合物。