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公开(公告)号：US4980453A
公开(公告)日：1990-12-25
申请号：US146154
申请日：1988-01-20
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
CPC分类号： C08G75/23 , C08G64/06 , C08G65/4081
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
摘要翻译： 大环低聚物，包括聚碳酸酯，聚酯，聚酰胺，聚酰亚胺，聚醚酮和聚醚砜，可以方便地由各种螺（双）二氢化茚化合物，特别是6,6'-二官能3,3'，3'-四甲基螺（双）二氢化茚制备。 大环低聚物可以方便地转化为线性聚合物。
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公开(公告)号：USRE34431E
公开(公告)日：1993-11-02
申请号：US915381
申请日：1992-05-08
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23 , C08G63/00 , C07D231/00 , C07F7/04 , C08G69/42
CPC分类号： C08G63/193 , C08G64/06 , C08G64/183 , C08G65/4081 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
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公开(公告)号：US4696998A
公开(公告)日：1987-09-29
申请号：US890053
申请日：1986-07-28
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , Eugene P. Boden , Thomas G. Shannon , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , Eugene P. Boden , Thomas G. Shannon , Joseph W. Guiles
IPC分类号： C07D273/00 , C07D273/08 , C07D323/00 , C08G63/64 , C08G64/04 , C08G64/20 , C08G71/04 , C08G73/16 , C08G63/62
摘要： Cyclic heterocarbonates containing linkages such as ester, urethane, imide, ether sulfone, ether ketone or amide may be prepared from the corresponding bishaloformates. They may be converted to linear copolycarbonates.
摘要翻译： 含有键的环状杂碳酸酯如酯，氨基甲酸酯，酰亚胺，醚砜，醚酮或酰胺可以由相应的二卤代甲酸酯制备。 它们可以转化为线性共聚碳酸酯。
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公开(公告)号：US4727134A
公开(公告)日：1988-02-23
申请号：US871641
申请日：1986-06-06
IPC分类号： C08G63/42 , C08G64/00 , C08G64/02 , C08G64/06 , C08G64/16 , C08G64/26 , C08G64/30 , C08G75/28 , C08J5/04 , C08G63/62
CPC分类号： C08J5/04 , C08G64/0208 , C08G64/06 , C08G64/1608 , C08G64/26 , C08G64/30 , C08G75/28 , C08J5/24 , C08J2369/00
摘要： Cyclic polycarbonate (or thiol analog) oligomer mixtures are prepared by the reaction of bishaloformates or their thio analogs, or mixtures thereof with dihydroxy or dimercapto compounds, with alkali metal hydroxides and various amines. The oligomer mixtures may be converted to polycarbonates or their thiol analogs by a method which is particularly adaptable to integration with polycarbonate processing operations. Polymerization may be conducted simultaneously with molding, extrusion and the like. The oligomer mixtures are adaptable to the preparation of filled prepregs.
摘要翻译： 通过双卤代甲酸酯或其硫代类似物或其与二羟基或二巯基化合物的混合物与碱金属氢氧化物和各种胺的反应制备环状聚碳酸酯（或硫醇类似物）低聚物混合物。 低聚物混合物可以通过特别适用于与聚碳酸酯加工操作整合的方法转化为聚碳酸酯或其硫醇类似物。 聚合可以与成型，挤出等同时进行。 低聚物混合物适用于填充的预浸料的制备。
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5.发明授权
公开(公告)号：US4983706A
公开(公告)日：1991-01-08
申请号：US476066
申请日：1990-01-30
CPC分类号： C08G63/64
摘要： A process which comprises reacting interfacially a dihydric phenol, a carbonate precursor and a prior prepared salt of an aliphatic alpha omega dicarboxylic acid having from 8 to about 20 carbon atoms thereby producing a copolyestercarbonate.
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公开(公告)号：US5100804A
公开(公告)日：1992-03-31
申请号：US669161
申请日：1991-03-14
CPC分类号： C08G64/26 , G01N31/164 , Y10T436/19 , Y10T436/196666
摘要： The molar concentration of chloroformate in an organic chloroformate solution is determined by adding an excess of a monohydroxyaromatic compound, water and a catalytic amount of a 4-dialkylaminopyridine such as 4-dimethylaminopyridine, titrating with aqueous base and taking as the end point the volume of base which achieves complete conversation of chloroformate groups to monoaromatic carbonate groups, as shown by a rapid rise in the pH of the aqueous phase of more than two points to a value in the range of 7-9. This method is particularly applicable to the determination of bischloroformate molar concentration in systems to be converted to cyclic polycarbonate oligomers. Conversion may be effected by condensation in the presence of a trialkylamine and aqueous base in the amount of about 3 moles per mole of bischloroformate.
摘要翻译： 氯甲酸酯在有机氯甲酸酯溶液中的摩尔浓度通过加入过量的单羟基芳族化合物，水和催化量的4-二烷基氨基吡啶如4-二甲基氨基吡啶来测定，用碱水溶液滴定，并以作为终点的体积 碱性化合物可使氯甲酸酯基团完全与单芳族碳酸酯基团进行通讯，如水相pH值的快速上升超过两点所示，为7-9。 该方法特别适用于待转化为环状聚碳酸酯低聚物的体系中双氯甲酸酯摩尔浓度的测定。 转化率可以通过在三烷基胺和碱水溶液的存在下以每摩尔二氯甲酸酯约3摩尔的量进行缩合来进行。
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公开(公告)号：US5300624A
公开(公告)日：1994-04-05
申请号：US66381
申请日：1993-05-24
申请人： Eugene P. Boden , Peter D. Phelps
发明人： Eugene P. Boden , Peter D. Phelps
摘要： A method is provided for making flame retardant polycarbonates by phosgenating a mixture of bisphenols having up to about 50 mole % of tetrahalobisphenols, such as tetrabromobisphenols. There is employed a mixture of a phase transfer catalyst and a tertiary organic amine to provide high molecular weight copolymer without excessive phosgene usage.
摘要翻译： 提供了一种制备阻燃聚碳酸酯的方法，该方法是通过使具有最多约50摩尔％的四卤代双酚（例如四溴双酚）的双酚的混合物进行光气化。 使用相转移催化剂和叔有机胺的混合物以提供高分子量共聚物而不过度使用光气。
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8.发明授权Preparation of branched polycarbonates and chloroformates, and intermediates therefor 失效支链聚碳酸酯和氯甲酸酯的制备及其中间体
公开(公告)号：US5142088A
公开(公告)日：1992-08-25
申请号：US646590
申请日：1991-01-28
摘要： Ester polyphenols such as the tris(bisphenol A) ester of trimellitic acid are prepared by the reaction of the corresponding aromatic poly(acyl halide) with a dihydroxyaromatic compound such as bisphenol A. They may be employed in the preparation of branched polycarbonates via chloroformate oligomer compositions.
摘要翻译： 酯类多酚如偏苯三酸的三（双酚A）酯通过相应的芳族聚酰卤与二羟基芳族化合物如双酚A的反应来制备。它们可用于通过氯甲酸酯低聚物制备支链聚碳酸酯 组合物。
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公开(公告)号：US5136018A
公开(公告)日：1992-08-04
申请号：US615942
申请日：1990-11-19
申请人： Eugene P. Boden , Peter D. Phelps
发明人： Eugene P. Boden , Peter D. Phelps
IPC分类号： C08G64/06 , C07C69/007 , C07C69/82 , C07C69/83 , C08G63/193 , C08G64/00
CPC分类号： C08G63/193 , C07C69/007 , C07C69/82
摘要： Macrocyclic polyarylate oligomers containing a mixture of isophthalate and terephthalate moieties are prepared by reaction of a mixture of isophthaloyl and terephthaloyl chloride with one or more bisphenols under specific reaction conditions. They are characterized by a reduced degree of crystallinity and therefore lower processing temperatures than the corresponding isophthalate oligomers.
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公开(公告)号：US5015720A
公开(公告)日：1991-05-14
申请号：US535258
申请日：1990-06-08
申请人： Eugene P. Boden , Peter D. Phelps
发明人： Eugene P. Boden , Peter D. Phelps
CPC分类号： C08G63/64
摘要： Polycarbonates containing aliphatic dicarboxylic ester groups, and having glass transition temperatures and processing temperatures lower than the corresponding homopolycarbonates are prepared via an intermediate which is in turn prepared from a dihydroxyaromatic compound and a C.sub.4-6 aliphatic dicarboxylic acid anhydride, preferably succinic anhydride. Phosgenation of said intermediate produces the desired soft segment polycarbonate.
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