Metallized plastic article
    6.
    发明授权
    Metallized plastic article 失效
    金属化塑料制品

    公开(公告)号:US5503934A

    公开(公告)日:1996-04-02

    申请号:US333709

    申请日:1994-11-03

    摘要: It is possible to manufacture articles out of thermoplastic materials and to metallize the articles at their surface. In this way one can manufacture reflectors and similar articles. Most thermoplastic materials require extra processing steps prior to the metallization like application of primers, chemical etching and the like.The invention is based on the discovery that a certain type of materials can be metallized without any extra processing steps. The materials involved are polyestercarbonates or blends of polyestercarbonates and polycarbonate. This is quite surprising since polycarbonates can not be metallized in good quality without extra processing steps prior to the metallization step.

    摘要翻译: 可以从热塑性材料制造制品并在其表面上金属化制品。 这样就可以制造反射镜和类似物品。 大多数热塑性材料在金属化之前需要额外的加工步骤,如施加底漆,化学蚀刻等。 本发明基于以下发现:某种类型的材料可以金属化而没有任何额外的加工步骤。 所涉及的材料是聚酯碳酸酯或聚酯碳酸酯和聚碳酸酯的共混物。 这是非常令人惊奇的,因为在金属化步骤之前没有额外的加工步骤,聚碳酸酯不能以良好的质量进行金属化。

    Method for the preparation of crosslinked polycarbonates
    7.
    发明授权
    Method for the preparation of crosslinked polycarbonates 失效
    交联聚碳酸酯的制备方法

    公开(公告)号:US5115024A

    公开(公告)日:1992-05-19

    申请号:US654708

    申请日:1991-02-13

    IPC分类号: C08G64/30 C08J5/24 C08L69/00

    摘要: An improved method for the preparation of crosslinked polycarbonates comprises the reaction at elevated temperature of a composition containing cyclic polycarbonate oligomers with at least one polyglycidyl acrylate copolymer formed by the reaction of at least one olefinic compound with a glycidyl acrylate monomer. Further disclosed are network polycarbonates wherein the carbonate chains are linked to each other via polyglycidyl acrylate copolymer groups, and prepreg compositions which comprise a filler and a mixture of cyclic polycarbonate oligomers with a polyglycidyl acrylate copolymer.

    摘要翻译: 用于制备交联聚碳酸酯的改进方法包括在含有环状聚碳酸酯低聚物和至少一种通过至少一种烯属化合物与丙烯酸缩水甘油酯单体的反应形成的丙烯酸缩水甘油酯共聚物的组合物的高温下进行反应。 还公开了网络聚碳酸酯,其中碳酸酯链通过聚丙烯酸缩水甘油酯共聚物基团彼此连接,以及预浸料组合物,其包含填料和环状聚碳酸酯低聚物与聚缩水甘油丙烯酸酯共聚物的混合物。

    Preparation of polyestercarbonate from aliphatic dicarboxylic acid
    9.
    发明授权
    Preparation of polyestercarbonate from aliphatic dicarboxylic acid 失效
    从脂肪族二羧酸制备聚酯碳酸酯

    公开(公告)号:US5025081A

    公开(公告)日:1991-06-18

    申请号:US476067

    申请日:1990-01-30

    IPC分类号: C08G63/79 C08G63/64

    CPC分类号: C08G63/64

    摘要: A process for preparing a copolyestercarbonate which comprises reacting interfacially a dihydric phenol, a carbonate precursor, and a saturated aliphatic alpha omega dicarboxylic acid having from 9 to about 40 carbon atoms wherein the said diacid is from about 2 to about 20 mole percent based on the dihydric phenol reactant content and wherein the initial pH is from about 8 to about 9 for about 70 to about 95% of the carbonate precursor addition time period time period and is then raised to a final pH of from about 10 to 12 for the remainder of the carbonate precursor addition time period.

    Preparation of by the bischloroformate process of soft segment
polycarbonate
    10.
    发明授权
    Preparation of by the bischloroformate process of soft segment polycarbonate 失效
    软分段聚碳酸酯双氯甲酸酯工艺的制备

    公开(公告)号:US5494997A

    公开(公告)日:1996-02-27

    申请号:US283691

    申请日:1994-08-01

    CPC分类号: C08G63/64

    摘要: A process for preparing a polyestercarbonate copolymer which is nearly devoid of diaryl-carbonates and that exhibits a glass transition temperature lower than bisphenol-A carbonate homopolymer, and that shows improved processability is herein described. The desired lower Tg and improved flow can be achieved by the polycondensation of a dihydric phenol and aliphatic dicarboxylic acid. The condensate is polymerized with a carbonate forming reagent.

    摘要翻译: 这里描述了几乎不含二芳基碳酸酯并且显示玻璃化转变温度低于双酚A碳酸酯均聚物并且显示出改善的加工性能的聚酯碳酸酯共聚物的方法。 所需的较低Tg和改善的流动可以通过二元酚和脂族二羧酸的缩聚来实现。 冷凝物与碳酸酯形成试剂聚合。