公开(公告)号：US5821322A

公开(公告)日：1998-10-13

申请号：US851260

申请日：1997-05-05

申请人： Daniel Joseph Brunelle ,  Peter David Phelps ,  Eugene Pauling Boden ,  Mark Erik Nelson ,  Larry Ivis Flowers ,  Paul Dean Sybert ,  Erik Hendrick Adriaan Capelle

发明人： Daniel Joseph Brunelle ,  Peter David Phelps ,  Eugene Pauling Boden ,  Mark Erik Nelson ,  Larry Ivis Flowers ,  Paul Dean Sybert ,  Erik Hendrick Adriaan Capelle

IPC分类号： C07D295/02 ,  B01J31/02 ,  C07B61/00 ,  C07C68/02 ,  C07C69/96 ,  C07C209/12 ,  C07C211/63 ,  C07D295/13 ,  C08G64/22 ,  C08G64/24 ,  C08G64/00

CPC分类号： C07D295/13 ,  C07C211/63 ,  C08G64/24

摘要： Diaminoalkyl quaternary ammonium salts are prepared by the reaction of alkyl halides with tertiary diamines having C.sub.2-20 primary alkyl radicals attached to nitrogen and an alkyl radical between the two nitrogen atoms in which at least three carbon atoms separate said nitrogen atoms. Said salts are preferably substantially free from corresponding diamines. They are useful as catalysts for interfacial polycarbonate preparation by the reaction of phosgene with at least one dihydroxyaromatic compound. Polycarbonate preparation using such catalysts is economical in phosgene consumption, is accompanied by a rapid conversion of chloroformate groups to desirable species and affords a product with a very low proportion of unreacted dihydroxyaromatic compound.

摘要翻译： 二氨基烷基季铵盐通过烷基卤与与氮连接的具有C2-20伯烷基的叔二胺和两个氮原子之间的烷基与其中至少三个碳原子分开所述氮原子的烷基反应来制备。 所述盐优选基本上不含相应的二胺。 它们可用作通过光气与至少一种二羟基芳族化合物反应的界面聚碳酸酯制备的催化剂。 使用这种催化剂的聚碳酸酯制备在光气消耗中是经济的，伴随着氯甲酸酯基团快速转化为所需物质并提供具有非常低比例的未反应的二羟基芳族化合物的产物。

公开(公告)号：US5759406A

公开(公告)日：1998-06-02

申请号：US911754

申请日：1997-08-15

申请人： Peter David Phelps ,  Joseph John Caringi ,  Larry Ivis Flowers ,  Eugene Pauling Boden ,  David Lee Ramsey

发明人： Peter David Phelps ,  Joseph John Caringi ,  Larry Ivis Flowers ,  Eugene Pauling Boden ,  David Lee Ramsey

IPC分类号： B01D15/00 ,  C07C209/86 ,  C07C211/08 ,  C07C277/08

CPC分类号： C07C277/08 ,  B01D15/00 ,  C07C209/86

摘要： An adsorption process uses a non-ion-exchangeable adsorbent polymeric resin of a monoethylenically unsaturated monomer such as styrene and a polyvinylidene monomer such as divinylbenzene for the adsorption of organic bases, such amines, amine salts and guanidinium salts, from high ionic strength aqueous solutions. Desorption may be employed for the recovery of said organic bases, and said adsorbent resin may be regenerated.

摘要翻译： 吸附方法使用单烯属不饱和单体如苯乙烯的非离子交换吸附剂聚合物树脂和诸如二乙烯基苯的聚偏二乙烯单体从高离子强度水溶液中吸附有机碱，例如胺，胺盐和胍盐 。 解吸可用于回收所述有机碱，并且所述吸附树脂可以再生。

公开(公告)号：US5872294A

公开(公告)日：1999-02-16

申请号：US583921

申请日：1996-01-11

申请人： Joseph John Caringi ,  Gary Ray Faler ,  Peter David Phelps ,  Thomas Link Guggenheim ,  Larry Ivis Flowers ,  Daniel Joseph Brunelle ,  Roy Ray Odle

发明人： Joseph John Caringi ,  Gary Ray Faler ,  Peter David Phelps ,  Thomas Link Guggenheim ,  Larry Ivis Flowers ,  Daniel Joseph Brunelle ,  Roy Ray Odle

IPC分类号： C07D211/98 ,  B01J31/02 ,  B01J35/12 ,  C07B61/00 ,  C07C277/00 ,  C07C279/04 ,  C08G73/10 ,  C07C277/08

CPC分类号： C08G73/1021 ,  C07C277/00

摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts and the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.

摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作用作相转移催化剂的六取代胍盐的来源，二羟基芳族化合物的碱金属盐与取代的酰亚胺反应形成聚醚酰亚胺或其中间体。

公开(公告)号：US06235934B1

公开(公告)日：2001-05-22

申请号：US09216252

申请日：1998-12-17

申请人： Joseph John Caringi ,  Gary Ray Faler ,  Peter David Phelps ,  Thomas Link Guggenheim ,  Larry Ivis Flowers ,  Daniel Joseph Brunelle ,  Roy Ray Odle

发明人： Joseph John Caringi ,  Gary Ray Faler ,  Peter David Phelps ,  Thomas Link Guggenheim ,  Larry Ivis Flowers ,  Daniel Joseph Brunelle ,  Roy Ray Odle

IPC分类号： C07C27902

CPC分类号： C08G73/1021 ,  C07C277/00

摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts for the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.

摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作六取代胍盐的源，其可用作用于使二羟基芳族化合物与取代酰亚胺的碱金属盐反应形成聚醚酰亚胺或其中间体的相转移催化剂。

公开(公告)号：US6103855A

公开(公告)日：2000-08-15

申请号：US281497

申请日：1999-03-30

申请人： James Manio Silva ,  David Michel Dardaris ,  Larry Ivis Flowers ,  James Franklin Hoover ,  Allen Wai-Yee Ko

发明人： James Manio Silva ,  David Michel Dardaris ,  Larry Ivis Flowers ,  James Franklin Hoover ,  Allen Wai-Yee Ko

IPC分类号： C08G64/22 ,  C08G64/14 ,  C08G64/24 ,  C08G63/02

CPC分类号： C08G64/24 ,  C08G64/14

摘要： A method of preparing a polycarbonate comprising the steps of:a) charging at least one dihydroxy compound, an inert solvent, water, caustic, carbonyl halide, and catalyst to a vessel, and maintaining the pH of the reaction mixture between about 4 and about 12 during charging; andb) within an interval of between 0 and about 90% of the total carbonyl halide addition to the vessel, activating a reaction system that produces monofunctional aromatic chloroformates (MAC) and introducing the MAC to the vessel within the interval of 0 to about 90% of the total carbonyl halide addition to the vessel; where the MAC reaction system is coupled with the vessel, and where means are provided for delivery of the MAC from the reaction system to the vessel.

摘要翻译： 一种制备聚碳酸酯的方法，包括以下步骤：a）将至少一种二羟基化合物，惰性溶剂，水，苛性碱，羰基卤化物和催化剂装入容器中，并将反应混合物的pH保持在约4和约 充电时12 和b）在添加到容器中的总羰基卤的0至约90％的间隔内，激活产生单官能芳族氯甲酸酯（MAC）并在0至约90的间隔内将MAC引入容器的反应体系 添加到容器中的总羰基卤的百分比; 其中MAC反应系统与容器结合，并且其中提供用于将MAC从反应系统输送到容器的装置。