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1.发明授权Diaminoalkyl quaternary ammonium salts and method for their preparation and use 失效二氨基烷基季铵盐及其制备和使用方法
公开(公告)号：US5821322A
公开(公告)日：1998-10-13
申请号：US851260
申请日：1997-05-05
申请人： Daniel Joseph Brunelle , Peter David Phelps , Eugene Pauling Boden , Mark Erik Nelson , Larry Ivis Flowers , Paul Dean Sybert , Erik Hendrick Adriaan Capelle
发明人： Daniel Joseph Brunelle , Peter David Phelps , Eugene Pauling Boden , Mark Erik Nelson , Larry Ivis Flowers , Paul Dean Sybert , Erik Hendrick Adriaan Capelle
IPC分类号： C07D295/02 , B01J31/02 , C07B61/00 , C07C68/02 , C07C69/96 , C07C209/12 , C07C211/63 , C07D295/13 , C08G64/22 , C08G64/24 , C08G64/00
CPC分类号： C07D295/13 , C07C211/63 , C08G64/24
摘要： Diaminoalkyl quaternary ammonium salts are prepared by the reaction of alkyl halides with tertiary diamines having C.sub.2-20 primary alkyl radicals attached to nitrogen and an alkyl radical between the two nitrogen atoms in which at least three carbon atoms separate said nitrogen atoms. Said salts are preferably substantially free from corresponding diamines. They are useful as catalysts for interfacial polycarbonate preparation by the reaction of phosgene with at least one dihydroxyaromatic compound. Polycarbonate preparation using such catalysts is economical in phosgene consumption, is accompanied by a rapid conversion of chloroformate groups to desirable species and affords a product with a very low proportion of unreacted dihydroxyaromatic compound.
摘要翻译： 二氨基烷基季铵盐通过烷基卤与与氮连接的具有C2-20伯烷基的叔二胺和两个氮原子之间的烷基与其中至少三个碳原子分开所述氮原子的烷基反应来制备。 所述盐优选基本上不含相应的二胺。 它们可用作通过光气与至少一种二羟基芳族化合物反应的界面聚碳酸酯制备的催化剂。 使用这种催化剂的聚碳酸酯制备在光气消耗中是经济的，伴随着氯甲酸酯基团快速转化为所需物质并提供具有非常低比例的未反应的二羟基芳族化合物的产物。
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2.发明授权
公开(公告)号：US5759406A
公开(公告)日：1998-06-02
申请号：US911754
申请日：1997-08-15
申请人： Peter David Phelps , Joseph John Caringi , Larry Ivis Flowers , Eugene Pauling Boden , David Lee Ramsey
发明人： Peter David Phelps , Joseph John Caringi , Larry Ivis Flowers , Eugene Pauling Boden , David Lee Ramsey
IPC分类号： B01D15/00 , C07C209/86 , C07C211/08 , C07C277/08
CPC分类号： C07C277/08 , B01D15/00 , C07C209/86
摘要： An adsorption process uses a non-ion-exchangeable adsorbent polymeric resin of a monoethylenically unsaturated monomer such as styrene and a polyvinylidene monomer such as divinylbenzene for the adsorption of organic bases, such amines, amine salts and guanidinium salts, from high ionic strength aqueous solutions. Desorption may be employed for the recovery of said organic bases, and said adsorbent resin may be regenerated.
摘要翻译： 吸附方法使用单烯属不饱和单体如苯乙烯的非离子交换吸附剂聚合物树脂和诸如二乙烯基苯的聚偏二乙烯单体从高离子强度水溶液中吸附有机碱，例如胺，胺盐和胍盐 。 解吸可用于回收所述有机碱，并且所述吸附树脂可以再生。
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3.发明授权Aqueous hexasubstituted guanidinium chlorides and methods for their preparation and use 失效六取代氯化胍水溶液及其制备和使用方法
公开(公告)号：US5872294A
公开(公告)日：1999-02-16
申请号：US583921
申请日：1996-01-11
申请人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
发明人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
IPC分类号： C07D211/98 , B01J31/02 , B01J35/12 , C07B61/00 , C07C277/00 , C07C279/04 , C08G73/10 , C07C277/08
CPC分类号： C08G73/1021 , C07C277/00
摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts and the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.
摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作用作相转移催化剂的六取代胍盐的来源，二羟基芳族化合物的碱金属盐与取代的酰亚胺反应形成聚醚酰亚胺或其中间体。
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4.发明授权Aqueous hexasubstituted guanidinium chlorides and methods for their preparation and use 失效六取代氯化胍水溶液及其制备和使用方法公开(公告)号：US06235934B1
公开(公告)日：2001-05-22
申请号：US09216252
申请日：1998-12-17
申请人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
发明人： Joseph John Caringi , Gary Ray Faler , Peter David Phelps , Thomas Link Guggenheim , Larry Ivis Flowers , Daniel Joseph Brunelle , Roy Ray Odle
IPC分类号： C07C27902
CPC分类号： C08G73/1021 , C07C277/00
摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts for the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.
摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作六取代胍盐的源，其可用作用于使二羟基芳族化合物与取代酰亚胺的碱金属盐反应形成聚醚酰亚胺或其中间体的相转移催化剂。
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公开(公告)号：US5652312A
公开(公告)日：1997-07-29
申请号：US373805
申请日：1995-01-17
申请人： Peter David Phelps , Eugene Pauling Boden , Patrick Joseph McCloskey , David Michel Dardaris , Adelbert Hermannus Leonardus Groothuis
发明人： Peter David Phelps , Eugene Pauling Boden , Patrick Joseph McCloskey , David Michel Dardaris , Adelbert Hermannus Leonardus Groothuis
IPC分类号： C08G63/64 , C08G63/91 , C08F283/02 , C08G64/00
CPC分类号： C08G63/916 , C08G63/64
摘要： Polyestercarbonates, particularly those containing aliphatic dicarboxylic acid-derived structural units, are redistributed by heating in the presence of a carbonate redistribution catalyst, and, optionally, a diaryl carbonate. The redistribution products have weight average molecular weights different from, and typically lower than, the initial molecular weight.
摘要翻译： 聚碳酸酯，特别是含有脂族二羧酸衍生的结构单元的碳酸酯，通过在碳酸盐再分布催化剂和任选的碳酸二芳基酯的存在下加热而重新分布。 再分配产物的重均分子量不同于，通常低于初始分子量。
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公开(公告)号：US06790934B2
公开(公告)日：2004-09-14
申请号：US10034866
申请日：2001-12-21
申请人： Norman Enoch Johnson , Raul Eduardo Ayala , Thomas Joseph Fyvie , Amy Rene Freshour , David Winfield Woodruff , Peter David Phelps , Ganesh Kailasam , Paul Edward Howson , Elliott West Shanklin , Lioba Maria Kloppenburg , David Bruce Hall , Pradeep Jeevaji Nadkarni , Daniel Joseph Brunelle
发明人： Norman Enoch Johnson , Raul Eduardo Ayala , Thomas Joseph Fyvie , Amy Rene Freshour , David Winfield Woodruff , Peter David Phelps , Ganesh Kailasam , Paul Edward Howson , Elliott West Shanklin , Lioba Maria Kloppenburg , David Bruce Hall , Pradeep Jeevaji Nadkarni , Daniel Joseph Brunelle
IPC分类号： C08G606
CPC分类号： C08G73/12 , C08G65/48 , C08G73/1046 , C08G75/23
摘要： Aromatic polyethers are prepared by displacement polymerization reaction in the presence of a water-immiscible solvent with boiling point at atmospheric pressure of greater than 110° C. and a density ratio to water of greater than 1.1:1 at 20-25° C. The polyethers are purified by processes comprising aqueous extraction, or filtration, or a combination thereof.
摘要翻译： 在大气压大于110℃的沸点和水分密度比大于1.1：1的水不混溶溶剂存在下，通过置换聚合反应制备芳族聚醚。 聚醚通过包括水提取或过滤或其组合的方法纯化。
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7.发明授权Aqueous hexasubstituted guanidinium chlorides and methods for their preparation and use 失效六取代氯化胍水溶液及其制备和使用方法公开(公告)号：US06570038B1
公开(公告)日：2003-05-27
申请号：US09591426
申请日：2000-06-09
IPC分类号： C07C27902
CPC分类号： C08G73/1021 , C07C277/00
摘要： Hexasubstituted guanidinium chlorides are prepared by a method which affords them in high yield as aqueous solutions, optionally also containing alkali metal chlorides. The solutions may be employed as sources of hexasubstituted guanidinium salts useful as phase transfer catalysts for the reaction of alkali metal salts of dihydroxyaromatic compounds with substituted imides to form polyetherimides or their intermediates.
摘要翻译： 六取代的胍基氯化物通过以高产率提供它们作为水溶液，任选还含有碱金属氯化物的方法制备。 该溶液可用作六取代胍盐的源，其可用作用于使二羟基芳族化合物与取代酰亚胺的碱金属盐反应形成聚醚酰亚胺或其中间体的相转移催化剂。
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公开(公告)号：US06576739B2
公开(公告)日：2003-06-10
申请号：US09735871
申请日：2000-12-14
IPC分类号： C08G6400
摘要： High molecular weight polycarbonates are prepared from hindered bisphenols in a reaction sequence involving conversion of the hindered bisphenol to the corresponding bischloroformate and subsequent treatment with an amine catalyst and aqueous base to effect polymerization by hydrolysis and condensation of the bischloroformate groups. Tertiary aliphatic and cycloaliphatic amine catalysts bearing at least one methyl group are found to be especially effective in promoting this polymerization reaction. Reaction rates and selectivities are shown to be superior to known methods employing tertiary amines lacking methyl groups attached to nitrogen, such as triethylamine. The inclusion of chain stoppers allows the preparation of well defined mixtures of polycarbonate oligomers from hindered bisphenols. Additionally, the methodology may be used to prepare symmetrical diaryl carbonates from hindered phenols.
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9.发明授权公开(公告)号：US06392079B1
公开(公告)日：2002-05-21
申请号：US09281498
申请日：1999-03-30
IPC分类号： C07C6996
摘要： A continuous process for the preparation of monofunctional aromatic chloroformates (MAC) having the structure (I) wherein n is an integer from 1 to 5, and R1 represents hydrogen, a branched or unbranched alkyl group having from 1-15 carbon atoms, an aryl group which may be substituted or unsubstituted, a cycloaliphatic group which may be substituted or unsubstituted, or an arylalkyl group which may be substituted or unsubstituted, the method comprising the steps of a) introducing 1) an aqueous caustic solution; 2) a carbonyl chloride; 3) at least one monofunctional hydroxyaromatic compound; and 4) at least one inert organic solvent into a continuous reaction system; and b) effecting contact between 1), 2), 3) and 4) for a time and at conditions sufficient to produce a MAC of structure (I).
摘要翻译： 制备具有结构（I）的单官能芳族氯甲酸酯（MAC）的连续方法，其中n为1至5的整数，并且R 1表示氢，具有1-15个碳原子的支链或非支链烷基，芳基 可以被取代或未取代的基团，可被取代或未取代的脂环族基团或可被取代或未取代的芳基烷基，所述方法包括以下步骤：a）引入1）苛性碱水溶液; 2）碳酰氯; 3 ）至少一种单官能羟基芳族化合物; 和4）至少一种惰性有机溶剂进入连续反应体系; 和b）在足以产生结构（I）的MAC的条件下，在1），2），3）和4）之间进行接触。
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10.发明授权公开(公告)号：US07126022B2
公开(公告)日：2006-10-24
申请号：US10141633
申请日：2002-05-08
IPC分类号： C07C69/96
摘要： The specification describes a continuous process for the preparation of monofunctional aromatic chloroformates (MAC) having the structure (I) wherein n is an integer from 1 to 5, and R1 represents hydrogen, a branched or unbranched alkyl group having from 1–15 carbon atoms, an aryl group which may be substituted or unsubstituted, a cycloaliphatic group which may be substituted or unsubstituted, or an arylalkyl group which may be substituted or unsubstituted.
摘要翻译： 该说明书描述了制备具有结构（I）的单官能芳族氯甲酸酯（MAC）的连续方法，其中n是1至5的整数，R 1代表氢，支链或非支链烷基 具有1-15个碳原子的基团，可被取代或未取代的芳基，可以被取代或未取代的脂环族基团，或可被取代或未取代的芳基烷基。
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