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公开(公告)号：US06891073B2
公开(公告)日：2005-05-10
申请号：US10744883
申请日：2003-12-23
CPC分类号： C07C37/20 , B01J8/025 , B01J8/0292 , B01J2219/00006 , B01J2219/30215 , Y02P20/582 , C07C39/16 , C07C39/21
摘要： A method for producing bisphenol includes introducing a phenol and a ketone into a fixed, supported catalytic bed reactor system in a downflow mode, reacting the phenol and the ketone to form a reaction mixture, and recovering the bisphenol isomer from the reaction mixture. The preferred bisphenol isomer is bisphenol A, or p,p′-bisphenol A, produced from the reaction of phenol and acetone. The reactor for producing the bisphenol A from the reaction of phenol and acetone includes an ion exchange resin catalyst disposed in a bed and packing randomly distributed throughout the ion exchange resin catalyst to improve heat transfer efficiency and reduce compression of the catalyst bed.
摘要翻译： 一种生产双酚的方法包括将苯酚和酮引入固定的负载催化床反应器系统中，以下流方式，使苯酚和酮反应形成反应混合物，并从反应混合物回收双酚异构体。 优选的双酚异构体是由苯酚和丙酮的反应产生的双酚A或p，p'-双酚A。 由苯酚和丙酮反应制备双酚A的反应器包括：离子交换树脂催化剂，其布置在床上，随机分布在整个离子交换树脂催化剂中，以提高传热效率，减少催化剂床的压缩。
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公开(公告)号：US06703530B2
公开(公告)日：2004-03-09
申请号：US09683898
申请日：2002-02-28
IPC分类号： C07C3916
CPC分类号： C07C37/20 , B01J8/025 , B01J8/0292 , B01J2219/00006 , B01J2219/30215 , Y02P20/582 , C07C39/16 , C07C39/21
摘要： A method for producing bisphenol includes introducing a phenol and a ketone into a fixed, supported catalytic bed reactor system in a downflow mode, reacting the phenol and the ketone to form a reaction mixture, and recovering the bisphenol isomer from the reaction mixture. The preferred bisphenol isomer is bisphenol A, or p,p′-bisphenol A, produced from the reaction of phenol and acetone. The reactor for producing the bisphenol A from the reaction of phenol and acetone includes an ion exchange resin catalyst disposed in a bed and packing randomly distributed throughout the ion exchange resin catalyst to improve heat transfer efficiency and reduce compression of the catalyst bed.
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3.发明授权公开(公告)号：US06369190B1
公开(公告)日：2002-04-09
申请号：US09712321
申请日：2000-11-14
申请人： Mingjie Zhu , Allen Wai-Yee Ko
发明人： Mingjie Zhu , Allen Wai-Yee Ko
IPC分类号： C08G6400
CPC分类号： C08G64/406
摘要： This invention relates to a method for purifying a polycarbonate resin solution resulting from an interfacial polymerization process. More particularly, this invention provides for the use of at least one static mixer to facilitate separation of the catalyst used to prepare the polycarbonate from the polycarbonate resin solution.
摘要翻译： 本发明涉及由界面聚合方法得到的聚碳酸酯树脂溶液的净化方法。 更具体地说，本发明提供使用至少一种静态混合器来促进从聚碳酸酯树脂溶液中分离用于制备聚碳酸酯的催化剂。
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公开(公告)号：US06214892B1
公开(公告)日：2001-04-10
申请号：US09470735
申请日：1999-12-23
IPC分类号： C08J1104
CPC分类号： C08G63/89 , C08G64/403
摘要： This invention relates to a method of recovering a polymer from an organic mixture comprising polymer and an organic solvent, the method comprising: a) admixing an aqueous solution and the organic mixture by the application of a combined mechanical and hydraulic shear force, the combined mechanical and shear force being sufficient to form a liquid-liquid dispersion; b) removing the organic solvent from the liquid-liquid dispersion thereby forming a remaining solution; and c) separating the polymer from the remaining solution. In one embodiment the polymer is a polycarbonate prepared by the interfacial method, and the organic solvent is methylene chloride.
摘要翻译： 本发明涉及从包含聚合物和有机溶剂的有机混合物中回收聚合物的方法，该方法包括：a）通过应用组合的机械和液压剪切力混合水溶液和有机混合物，组合机械 剪切力足以形成液 - 液分散体; b）从液 - 液分散液中除去有机溶剂，从而形成剩余溶液; 和c）将聚合物与剩余溶液分离。在一个实施方案中，聚合物是通过界面方法制备的聚碳酸酯，有机溶剂是二氯甲烷。
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公开(公告)号：US08227556B2
公开(公告)日：2012-07-24
申请号：US13165353
申请日：2011-06-21
申请人： Allen Wai-Yee Ko , Michael L. Todt
发明人： Allen Wai-Yee Ko , Michael L. Todt
CPC分类号： C08J11/04 , C08L71/123 , Y02P20/143 , Y02W30/70 , Y10S264/911 , C08L2666/02
摘要： A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
摘要翻译： 一种热塑性组合物，其包含回收的聚（亚芳基醚），基于所述热塑性组合物的总重量计，所述热塑性组合物在第二回收热塑性塑料中的总重量为0.1重量％，所述第二回收热塑性塑料在处理时发出大于或等于10质量％的挥发物 热塑性组合物的温度; 0.025至4.0重量％，基于热塑性组合物的总重量，选自聚烯烃，丙烯腈 - 丁二烯 - 苯乙烯，聚碳酸酯，聚碳酸酯/丙烯腈 - 丁二烯 - 苯乙烯共混物，聚甲基丙烯酸甲酯，聚酰胺 ，聚酯，聚碳酸酯/聚酯共混物和两种或更多种前述第三种回收的热塑性塑料的组合，其中两种或更多种前述第三种回收的热塑性塑料的组合以小于或等于10重量％的量存在，基于 热塑性组合物的总重量; 和可选的原始热塑性塑料。
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公开(公告)号：US20110251325A1
公开(公告)日：2011-10-13
申请号：US13165353
申请日：2011-06-21
申请人： Allen Wai-Yee Ko , Michael L. Todt
发明人： Allen Wai-Yee Ko , Michael L. Todt
IPC分类号： C08L71/10 , C08L69/00 , C08L67/00 , C08L75/04 , C08L27/06 , C08L55/02 , C08L53/00 , C08K3/26 , C08K3/16 , C08K3/30 , C08L33/12 , C08K3/22
CPC分类号： C08J11/04 , C08L71/123 , Y02P20/143 , Y02W30/70 , Y10S264/911 , C08L2666/02
摘要： A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
摘要翻译： 一种热塑性组合物，其包含回收的聚（亚芳基醚），基于所述热塑性组合物的总重量计，所述热塑性组合物在第二回收热塑性塑料中的总重量为0.1重量％，所述第二回收热塑性塑料在处理时发出大于或等于10质量％的挥发物 热塑性组合物的温度; 0.025至4.0重量％，基于热塑性组合物的总重量，选自聚烯烃，丙烯腈 - 丁二烯 - 苯乙烯，聚碳酸酯，聚碳酸酯/丙烯腈 - 丁二烯 - 苯乙烯共混物，聚甲基丙烯酸甲酯，聚酰胺 ，聚酯，聚碳酸酯/聚酯共混物和两种或更多种前述第三种回收的热塑性塑料的组合，其中两种或更多种前述第三种回收的热塑性塑料的组合以小于或等于10重量％的量存在，基于 热塑性组合物的总重量; 和可选的原始热塑性塑料。
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公开(公告)号：US06489372B1
公开(公告)日：2002-12-03
申请号：US09690596
申请日：2000-10-17
申请人： Qiwei He , Paul Russell Wilson , Paul William Buckley , Allen Wai Yee Ko , Larry Allen Divins , William Lee Gately , Ganesh Kailasam
发明人： Qiwei He , Paul Russell Wilson , Paul William Buckley , Allen Wai Yee Ko , Larry Allen Divins , William Lee Gately , Ganesh Kailasam
IPC分类号： C08J1104
CPC分类号： C08G64/403 , C08G63/89 , C08J3/14
摘要： Polymer are removed from organic solvent-polymer mixtures by preparing a liquid-liquid dispersion of finely dispersed solvent droplets containing polymer in water, adding this liquid-liquid dispersion to a stirred vessel containing water or other suitable liquid and rapidly evaporating the solvent to produce a slurry of the polymer in a liquid from which the solid polymer particles are recovered.
摘要翻译： 通过制备含有聚合物在水中的精细分散的溶剂液滴的液 - 液分散体，将该液 - 液分散体加入到含有水或其它合适液体的搅拌容器中并快速蒸发溶剂以产生聚合物，从而从有机溶剂 - 聚合物混合物中除去聚合物 聚合物在从其中回收固体聚合物颗粒的液体中的淤浆。
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公开(公告)号：US07964675B2
公开(公告)日：2011-06-21
申请号：US11032648
申请日：2005-01-10
申请人： Allen Wai-Yee Ko , Michael L. Todt
发明人： Allen Wai-Yee Ko , Michael L. Todt
CPC分类号： C08J11/04 , C08L71/123 , Y02P20/143 , Y02W30/70 , Y10S264/911 , C08L2666/02
摘要： A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
摘要翻译： 一种热塑性组合物，其包含回收的聚（亚芳基醚），基于所述热塑性组合物的总重量计，所述热塑性组合物在第二回收热塑性塑料中的总重量为0.1重量％，所述第二回收热塑性塑料在处理时发出大于或等于10质量％的挥发物 热塑性组合物的温度; 0.025至4.0重量％，基于热塑性组合物的总重量，选自聚烯烃，丙烯腈 - 丁二烯 - 苯乙烯，聚碳酸酯，聚碳酸酯/丙烯腈 - 丁二烯 - 苯乙烯共混物，聚甲基丙烯酸甲酯，聚酰胺 ，聚酯，聚碳酸酯/聚酯共混物和两种或更多种前述第三种回收的热塑性塑料的组合，其中两种或更多种前述第三种回收的热塑性塑料的组合以小于或等于10重量％的量存在，基于 热塑性组合物的总重量; 和可选的原始热塑性塑料。
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9.发明授权Batch process for the production of polycarbonate by interfacial polymerization 有权通过界面聚合生产聚碳酸酯的分批方法
公开(公告)号：US6103855A
公开(公告)日：2000-08-15
申请号：US281497
申请日：1999-03-30
申请人： James Manio Silva , David Michel Dardaris , Larry Ivis Flowers , James Franklin Hoover , Allen Wai-Yee Ko
发明人： James Manio Silva , David Michel Dardaris , Larry Ivis Flowers , James Franklin Hoover , Allen Wai-Yee Ko
摘要： A method of preparing a polycarbonate comprising the steps of:a) charging at least one dihydroxy compound, an inert solvent, water, caustic, carbonyl halide, and catalyst to a vessel, and maintaining the pH of the reaction mixture between about 4 and about 12 during charging; andb) within an interval of between 0 and about 90% of the total carbonyl halide addition to the vessel, activating a reaction system that produces monofunctional aromatic chloroformates (MAC) and introducing the MAC to the vessel within the interval of 0 to about 90% of the total carbonyl halide addition to the vessel; where the MAC reaction system is coupled with the vessel, and where means are provided for delivery of the MAC from the reaction system to the vessel.
摘要翻译： 一种制备聚碳酸酯的方法，包括以下步骤：a）将至少一种二羟基化合物，惰性溶剂，水，苛性碱，羰基卤化物和催化剂装入容器中，并将反应混合物的pH保持在约4和约 充电时12 和b）在添加到容器中的总羰基卤的0至约90％的间隔内，激活产生单官能芳族氯甲酸酯（MAC）并在0至约90的间隔内将MAC引入容器的反应体系 添加到容器中的总羰基卤的百分比; 其中MAC反应系统与容器结合，并且其中提供用于将MAC从反应系统输送到容器的装置。
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