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1.发明申请公开(公告)号：US20140151040A1
公开(公告)日：2014-06-05
申请号：US13896255
申请日：2013-05-16
申请人： Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young , Russell Evan Cooper , Matthew Bernard Zielinski , Mark Anthony Emanuele , Brian Christopher Llewellyn , Dennis John O'Rear
发明人： Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young , Russell Evan Cooper , Matthew Bernard Zielinski , Mark Anthony Emanuele , Brian Christopher Llewellyn , Dennis John O'Rear
摘要： Methods and systems relate to the in-situ removal of heavy metals such as mercury, arsenic, etc., from produced fluids such as gases and crudes from a subterranean hydrocarbon-bearing formation. A sufficient amount of a fixing agent is injected into formation with a dilution fluid. The fixing agent reacts with the heavy metals forming precipitate, or is extracted heavy metals into the dilution fluid as soluble complexes. In one embodiment, the heavy metal precipitates remain in the formation. After the recovery of the produced fluid, the dilution fluid containing the heavy metal complexes is separated from the produced fluid, generating a treated produced fluid having a reduced concentration of heavy metals. In one embodiment, the dilution fluid is water, and the wastewater containing the heavy metal complexes after recovery can be recycled by injection into a reservoir.
摘要翻译： 方法和系统涉及从地下含烃地层的产生的流体（例如气体和原油）中原位去除重金属如汞，砷等。 用稀释液注入足量的固定剂。 固定剂与重金属形成沉淀物反应，或将重金属萃取到稀释液中作为可溶性络合物。 在一个实施方案中，重金属沉淀物保留在地层中。 在回收所产生的流体之后，将含有重金属配合物的稀释液与所产生的流体分离，产生具有降低的重金属浓度的经处理的生产流体。 在一个实施方案中，稀释流体是水，并且在回收之后含有重金属络合物的废水可以通过注入回收到储存器中。
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公开(公告)号：US20130306310A1
公开(公告)日：2013-11-21
申请号：US13895612
申请日：2013-05-16
申请人： Darrell Lynn Gallup , Sujin Yean , Lyman Arnold Young , Dennis John O'Rear , Russell Evan Cooper
发明人： Darrell Lynn Gallup , Sujin Yean , Lyman Arnold Young , Dennis John O'Rear , Russell Evan Cooper
摘要： A method for simultaneously transporting and removing trace amount levels of heavy metals from produced fluids such as crude oil, with the injection of a fixing agent into the pipeline for use in transporting the produced fluid. A sufficient amount of the fixing agent is injected into the pipeline containing the produced fluid and a dilution fluid. The fixing agent reacts with the heavy metals forming precipitate or soluble complexes in the dilution. The dilution fluid containing the heavy metal complexes is separated from the produced fluid, generating a treated produced fluid having a reduced concentration of heavy metals. In one embodiment, the dilution fluid is water, and the wastewater containing the heavy metal complexes after recovery can be recycled by injection into a reservoir.
摘要翻译： 一种从生产的流体如原油中同时输送和除去痕量的重金属的方法，其中将固定剂注入管道中用于输送所产生的流体。 将足量的固定剂注入含有所生产的流体和稀释液的管道中。 固定剂与稀释液中形成沉淀物或可溶性络合物的重金属反应。 将含有重金属络合物的稀释液与所产生的流体分离，产生处理后的重金属浓度降低的产物。 在一个实施方案中，稀释流体是水，并且在回收之后含有重金属配合物的废水可以通过注入回收到储存器中。
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公开(公告)号：US20130306311A1
公开(公告)日：2013-11-21
申请号：US13895754
申请日：2013-05-16
申请人： Russell Evan Cooper , Dennis John O'Rear , Darrell Lynn Gallup , Lyman Arnold Young , Sujin Yean
发明人： Russell Evan Cooper , Dennis John O'Rear , Darrell Lynn Gallup , Lyman Arnold Young , Sujin Yean
CPC分类号： C10G21/08 , B01D53/64 , B01D2257/602 , C10G2300/201 , C10G2300/205 , E21B43/34 , E21B43/40
摘要： Trace amount levels of non-volatile mercury in crude oil are reduced by contacting the crude oil with a water stream containing at least a monatomic water-soluble sulfur species such as sulfides and hydrosulfides. The non-volatile mercury is extracted into the water phase forming a mercury rich wastewater, yielding a treated crude oil having at less than 50% of the original non-volatile mercury level. The wastewater can disposed or recycled by injection into a reservoir. In one embodiment, the water stream consists essentially of produced water.
摘要翻译： 通过使原油与至少含有单原子水溶性硫物质如硫化物和氢硫化物的水流接触来降低原油中微量的非挥发性汞。 非挥发性汞被提取到水相中，形成富含汞的废水，产生的处理原油的含量低于原始非挥发性汞含量的50％。 废水可以通过注入设置或回收到储存器中。 在一个实施方案中，水流基本上由生产的水组成。
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公开(公告)号：US09023123B2
公开(公告)日：2015-05-05
申请号：US13895850
申请日：2013-05-16
申请人： Dennis John O'Rear , Russell Evan Cooper , Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young
发明人： Dennis John O'Rear , Russell Evan Cooper , Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young
摘要： Trace levels of mercury in a natural gas are reduced by scrubbing the natural gas in an absorber with an aqueous solution comprising a water-soluble sulfur compound. The water-soluble sulfur compound reacts with a least a portion of the mercury in the natural gas to produce a treated natural gas with a reduced concentration of mercury, and a mercury containing sulfur-depleted solution which can be disposed by injection into a (depleted) underground formation. The produced water extracted with the natural gas from the underground formation can be recycled for use as the scrubbing solution. In one embodiment, a fresh source of water-soluble sulfur compound as feed to the absorber can be generated on-site by reacting an elemental sulfur source with a sulfur reagent in produced water.
摘要翻译： 通过用包含水溶性硫化合物的水溶液洗涤吸收器中的天然气来减少天然气中痕量的汞。 水溶性硫化合物与天然气中的至少一部分汞反应产生具有降低的汞浓度的经处理的天然气，以及含汞的贫硫溶液，其可以通过注入（耗尽的） ）地下形成。 用地下地层天然气提取的产水可以循环再用作洗涤液。 在一个实施方案中，作为进料到吸收器的新鲜水溶性硫化合物源可以通过在生产的水中使元素硫源与硫试剂反应而在现场产生。
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公开(公告)号：US09181497B2
公开(公告)日：2015-11-10
申请号：US13895754
申请日：2013-05-16
申请人： Russell Evan Cooper , Dennis John O'Rear , Darrell Lynn Gallup , Lyman Arnold Young , Sujin Yean
发明人： Russell Evan Cooper , Dennis John O'Rear , Darrell Lynn Gallup , Lyman Arnold Young , Sujin Yean
IPC分类号： E21B43/34 , E21B43/243 , B01D53/64 , C10G21/08 , E21B43/40
CPC分类号： C10G21/08 , B01D53/64 , B01D2257/602 , C10G2300/201 , C10G2300/205 , E21B43/34 , E21B43/40
摘要： Trace amount levels of non-volatile mercury in crude oil are reduced by contacting the crude oil with a water stream containing at least a monatomic water-soluble sulfur species such as sulfides and hydrosulfides. The non-volatile mercury is extracted into the water phase forming a mercury rich wastewater, yielding a treated crude oil having at less than 50% of the original non-volatile mercury level. The wastewater can disposed or recycled by injection into a reservoir. In one embodiment, the water stream consists essentially of produced water.
摘要翻译： 通过使原油与至少含有单原子水溶性硫物质如硫化物和氢硫化物的水流接触来降低原油中微量的非挥发性汞。 非挥发性汞被提取到水相中，形成富含汞的废水，产生的处理原油的含量低于原始非挥发性汞含量的50％。 废水可以通过注入设置或回收到储存器中。 在一个实施方案中，水流基本上由生产的水组成。
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公开(公告)号：US20140158353A1
公开(公告)日：2014-06-12
申请号：US13896242
申请日：2013-05-16
申请人： Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young , Russell Evan Cooper , Matthew Bernard Zielinski , Mark Anthony Emanuele , Brian Christopher Llewellyn , Dennis John O'Rear
发明人： Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young , Russell Evan Cooper , Matthew Bernard Zielinski , Mark Anthony Emanuele , Brian Christopher Llewellyn , Dennis John O'Rear
摘要： Methods and systems relate to the in-situ removal of heavy metals such as mercury, arsenic, etc., from produced fluids such as gases and crudes from a subterranean hydrocarbon-bearing formation. A sufficient amount of a fixing agent is injected into formation with a dilution fluid. The fixing agent reacts with the heavy metals forming precipitate, or is extracted heavy metals into the dilution fluid as soluble complexes. In one embodiment, the heavy metal precipitates remain in the formation. After the recovery of the produced fluid, the dilution fluid containing the heavy metal complexes is separated from the produced fluid, generating a treated produced fluid having a reduced concentration of heavy metals. In one embodiment, the dilution fluid is water, and the wastewater containing the heavy metal complexes after recovery can be recycled by injection into a reservoir.
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公开(公告)号：US20130306312A1
公开(公告)日：2013-11-21
申请号：US13895850
申请日：2013-05-16
申请人： Dennis John O'Rear , Russell Evan Cooper , Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young
发明人： Dennis John O'Rear , Russell Evan Cooper , Sujin Yean , Darrell Lynn Gallup , Lyman Arnold Young
摘要： Trace levels of mercury in a natural gas are reduced by scrubbing the natural gas in an absorber with an aqueous solution comprising a water-soluble sulfur compound. The water-soluble sulfur compound reacts with a least a portion of the mercury in the natural gas to produce a treated natural gas with a reduced concentration of mercury, and a mercury containing sulfur-depleted solution which can be disposed by injection into a (depleted) underground formation. The produced water extracted with the natural gas from the underground formation can be recycled for use as the scrubbing solution. In one embodiment, a fresh source of water-soluble sulfur compound as feed to the absorber can be generated on-site by reacting an elemental sulfur source with a sulfur reagent in produced water.
摘要翻译： 通过用包含水溶性硫化合物的水溶液洗涤吸收器中的天然气来减少天然气中痕量的汞。 水溶性硫化合物与天然气中的至少一部分汞反应产生具有降低的汞浓度的经处理的天然气，以及含汞的贫硫溶液，其可以通过注入（耗尽的） ）地下形成。 用地下地层天然气提取的产水可以循环再用作洗涤液。 在一个实施方案中，作为进料到吸收器的新鲜水溶性硫化合物源可以通过在生产的水中使元素硫源与硫试剂反应而在现场产生。
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公开(公告)号：US08728303B2
公开(公告)日：2014-05-20
申请号：US12950060
申请日：2010-11-19
IPC分类号： C10G27/00
CPC分类号： C10G27/00 , C02F1/722 , C02F2101/20 , C02F2103/10 , C10G27/12 , C10G2300/1033 , C10G2300/205 , C10G2300/308 , C10G2300/805
摘要： Trace element levels of heavy metals in crude oil are reduced by contacting the crude oil with an oxidizing agent, extracting heavy metals into a water phase for subsequent separation from the crude oil. The oxidizing agent is selected from the group of hydroperoxides, organic peroxides, inorganic peracids and salts thereof, organic peracids and salts thereof, and ozone. In one embodiment, the oxidizing agent converts heavy metals into the heavy metal cations in a water-oil emulsion, which can be subsequently separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, at least a complexing agent can be added to facilitate the removal by forming soluble heavy metal complexes in the water phase.
摘要翻译： 通过使原油与氧化剂接触，原油中重金属的微量元素含量降低，将重金属萃取到水相中，随后与原油分离。 氧化剂选自氢过氧化物，有机过氧化物，无机过酸及其盐，有机过酸及其盐和臭氧。 在一个实施方案中，氧化剂将重金属转化为水 - 油乳液中的重金属阳离子，水乳液可以随后与原油分离，用于具有降低的重金属含量的处理过的原油。 在一个实施方案中，可以加入至少一种络合剂以通过在水相中形成可溶性重金属络合物来促进去除。
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公开(公告)号：US08721874B2
公开(公告)日：2014-05-13
申请号：US12950637
申请日：2010-11-19
IPC分类号： C10G27/00
CPC分类号： C10G27/00 , C02F1/683 , C02F1/722 , C02F2103/10 , C10G27/12 , C10G29/06 , C10G29/12 , C10G29/20 , C10G53/14 , C10G2300/1033 , C10G2300/205 , C10G2300/308 , C10G2300/805
摘要： Trace element levels of heavy metals in crude oil are reduced by contacting the crude oil with an oxidizing agent, converting heavy metals into heavy metal cations for subsequent separation from the crude oil. At least a complexing agent is added to convert the heavy metal cations into soluble heavy metal complexes in a water phase, which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, the complexing agent is selected from the group of metal halides, and the oxidizing agent is selected from the group of organic peracids, inorganic peracids and salts thereof.
摘要翻译： 通过使原油与氧化剂接触，原油中重金属的痕量元素含量降低，将重金属转化成重金属阳离子，随后与原油分离。 加入至少一种络合剂，以将重金属阳离子转化成可与原油分离的水相中的可溶性重金属络合物，用于具有降低的重金属含量的处理过的原油。 在一个实施方案中，络合剂选自金属卤化物，氧化剂选自有机过酸，无机过酸及其盐。
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公开(公告)号：US20120125817A1
公开(公告)日：2012-05-24
申请号：US12950170
申请日：2010-11-19
CPC分类号： C10G27/00 , C02F1/683 , C02F1/722 , C02F2101/20 , C02F2103/10 , C10G27/12 , C10G2300/1033 , C10G2300/205 , C10G2300/308 , C10G2300/805
摘要： Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an oxidant such as oxyhalites, converting elemental mercury into heavy metal cations for subsequent separation from the crude oil. In an improved method for the removal of mercury, at least a complexing agent is added to convert the heavy metal cations into soluble heavy metal complexes in a water phase, which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, the complexing agent is selected from the group of metal halides.
摘要翻译： 通过使原油与氧化剂如卤氧化物接触，将元素汞重量转化为重金属阳离子，以便随后与原油分离，原油中的重金属如微量元素水平降低。 在一种改进的汞去除方法中，加入至少一种络合剂，以将重金属阳离子转化为可与原油分离的水相中的可溶性重金属络合物，使其具有降低水平的处理过的原油 的重金属。 在一个实施方案中，络合剂选自金属卤化物。
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