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    Random copolymers of poly(arylene sulfide)s and process therefor
    2.
    发明授权
    Random copolymers of poly(arylene sulfide)s and process therefor 失效
    聚（亚芳基硫醚）的无规共聚物及其工艺

    公开(公告)号：US5268449A

    公开(公告)日：1993-12-07

    申请号：US976857

    申请日：1992-11-16

    申请人： Dwayne R. Senn ,  Rex L. Bobstein ,  Owen H. Decker ,  Carlton E. Ash ,  Darryl R. Fahey ,  Jon F. Geibel

    发明人： Dwayne R. Senn ,  Rex L. Bobstein ,  Owen H. Decker ,  Carlton E. Ash ,  Darryl R. Fahey ,  Jon F. Geibel

    IPC分类号： C08G75/02 ,  C08G75/14

    CPC分类号： C08G75/0236

    摘要： A random copolymer composed of at least one arylene sulfide segment and at least one arylene aulfide sulfone segment is prepared by contacting at least one dihaloaromatic sulfide having a formula of X--Ar(R).sub.n --S--Ar.sup.1 (R.sup.1).sub.n --X.sup.1, with a mixture comprising at least one sulfur source and at least one dihaloaromatic sulfone having a formula of X.sup.2 --Ar.sup.2 (R.sup.2).sub.n --S(O.sub.2)--Ar.sup.3 (R.sup.3).sub.n --X.sup.3 in the presence of a polar organic compound under polymerization conditions to synthesize a random copolymer; where X, X.sup.1, X.sup.2, and X.sup.3 can be the same or different halogens and are each selected from the group consisting of fluorine, chlorine, bromine and iodine; Ar, Ar.sup.1, Ar.sup.2, and Ar.sup.3 are each an arylene group; R, R.sup.1, R.sup.2, and R.sup.3 are each selected from the group consisting of hydrogen and hydrocarbyl radical in which the hydrocarbyl radical can be alkyl, cycloalkyl, alkenyl, and aryl radicals; and n is a whole number from 0 to 4. The total number of carbon atoms in each molecule represented by X--Ar(R).sub.n --S--Ar.sup.1 (R.sup.1).sub.n --X.sup.1 and X.sup.2 --Ar.sup.2 (R.sup.2).sub.n --S(O.sub.2)--Ar.sup.3 (R.sup.3)--X.sup.3 is in the range of from about 12 to about 54.

    摘要翻译： 通过将至少一种具有式X-Ar（R）nS-Ar1（R1）n-X1的二卤代芳族硫醚与至少一种亚芳基硫醚链段与至少一个亚芳基硫醚砜链段组成的无规共聚物与 混合物，在极性有机化合物的存在下，在聚合条件下，包含至少一种硫源和至少一种具有式X2-Ar2（R2）nS（O2）-Ar3（R3）n-X3的二卤代芳砜，合成无规 共聚物 其中X，X1，X2和X3可以是相同或不同的卤素，并且各自选自氟，氯，溴和碘; Ar，Ar 1，Ar 2和Ar 3各自为亚芳基; R，R 1，R 2和R 3各自选自氢和烃基，其中烃基可以是烷基，环烷基，烯基和芳基; 由X-Ar（R）nS-Ar1（R1）n-X1和X2-Ar2（R2）nS（O2）-Ar3表示的每个分子中的碳原子总数 （R3）-X3在约12至约54的范围内。

    Process for preparing poly(arylene sulfide) polymers using waste material
    4.
    发明授权
    Process for preparing poly(arylene sulfide) polymers using waste material 失效
    使用废料制备聚（亚芳基硫醚）聚合物的方法

    公开(公告)号：US06281326B1

    公开(公告)日：2001-08-28

    申请号：US08120305

    申请日：1993-09-13

    申请人： Carlton E. Ash ,  Jon F. Geibel

    发明人： Carlton E. Ash ,  Jon F. Geibel

    IPC分类号： C08G7514

    CPC分类号： C08J11/06 ,  C08G75/0259 ,  C08J2381/02 ,  Y02W30/701

    摘要： A process is provided for producing a poly(arylene sulfide) polymer which employs waste material comprising poly(arylene sulfide) polymer that is normally discarded or otherwise disposed of, wherein the waste stream is contacted with a polymerization reaction mixture under polymerization conditions. The waste material can optionally contain other components such as cyclic and linear oligomers, inorganic salts, polar organic compounds and water.

    摘要翻译： 提供了一种生产聚（亚芳基硫醚）聚合物的方法，该聚合物采用通常废弃或以其他方式处理的聚（亚芳基硫醚）聚合物的废料，其中在聚合条件下废物流与聚合反应混合物接触。 废料可以任选地含有其它组分，例如环状和线性低聚物，无机盐，极性有机化合物和水。

    Process for the removal of lower molecular weight fractions of poly(arylene sulfide) polymers
    6.
    发明授权
    Process for the removal of lower molecular weight fractions of poly(arylene sulfide) polymers 失效
    去除聚（亚芳基硫醚）聚合物的较低分子量馏分的方法

    公开(公告)号：US5334701A

    公开(公告)日：1994-08-02

    申请号：US965489

    申请日：1992-10-23

    申请人： Carlton E. Ash ,  Jon F. Geibel ,  Randy L. Hagenson ,  David A. Soules

    发明人： Carlton E. Ash ,  Jon F. Geibel ,  Randy L. Hagenson ,  David A. Soules

    IPC分类号： C08G75/02 ,  C08G75/06 ,  C08G75/14

    CPC分类号： C08G75/0281

    摘要： A method is provided for selectively extracting the lower molecular weight fraction of a poly(arylene sulfide) polymer by contacting the polymer with a polar organic compound and a promoter compound to form a less dense polymer-lean liquid phase and a more dense polymer-rich liquid phase, separating the polymer-lean liquid phase from the polymer-rich liquid phase, and recovering the polymer from the polymer-rich phase. Alternatively, either of the phases can be isolated and polar organic compound and optionally promoter can be added to form two new phases, followed by isolation of the new polymer-rich phase. This process can be repeated as often as desired or practicable in order to recover polymer having a desired molecular weight and/or molecular weight distribution.

    摘要翻译： 提供了一种通过使聚合物与极性有机化合物和助催化剂化合物接触以选择性地提取聚（亚芳基硫醚）聚合物的较低分子量部分以形成较不致密的贫聚合物稀相的液相和更致密的聚合物丰富的方法 液相，从富含聚合物的液相中分离富聚合物的液相，并从富聚合物相中回收聚合物。 或者，可以分离任一相，并且可以加入极性有机化合物和任选的助催化剂以形成两个新相，随后分离新的富聚合物相。 为了回收具有所需分子量和/或分子量分布的聚合物，可以按需要或可行地重复该过程。

    Process for preparing high molecular weight poly(arylene sulfide) polymers using lithium salts
    7.
    发明授权
    Process for preparing high molecular weight poly(arylene sulfide) polymers using lithium salts 失效
    使用锂盐制备高分子量聚（亚芳基硫醚）聚合物的方法

    公开(公告)号：US5929203A

    公开(公告)日：1999-07-27

    申请号：US965647

    申请日：1992-10-23

    申请人： Carlton E. Ash ,  Jon F. Geibel ,  Harold D. Yelton

    发明人： Carlton E. Ash ,  Jon F. Geibel ,  Harold D. Yelton

    IPC分类号： C08G75/02 ,  C08G75/14

    CPC分类号： C08G75/0259 ,  C08G75/025

    摘要： A process is provided for producing a high molecular weight poly(arylene sulfide) polymer employing at least one dihaloaromatic compound, a sulfur source, a polar organic compound, a lithium salt which is soluble in the polar organic compound, and water in an amount less than about 1.75 moles of water per mole of sulfur under polymerization conditions. The pressure and temperature are chosen to allow the volatile reactants to be maintained in liquid form in the reaction mixture.

    摘要翻译： 提供一种制备高分子量聚（亚芳基硫醚）聚合物的方法，其使用至少一种二卤代芳族化合物，硫源，极性有机化合物，可溶于极性有机化合物的锂盐和少量的水 在聚合条件下每摩尔硫约1.75摩尔水。 选择压力和温度以允许挥发性反应物在反应混合物中保持为液体形式。

    Epoxy resin curing compositions and epoxy resin systems including same
    8.
    发明授权
    Epoxy resin curing compositions and epoxy resin systems including same 有权
    环氧树脂固化组合物和包含其的环氧树脂体系

    公开(公告)号：US08796391B2

    公开(公告)日：2014-08-05

    申请号：US12642343

    申请日：2009-12-18

    申请人： Larry Steven Corley ,  Carlton E. Ash

    发明人： Larry Steven Corley ,  Carlton E. Ash

    IPC分类号： C08G65/32 ,  C08G59/56 ,  C08G59/50

    CPC分类号： C08G59/50 ,  C08G59/504 ,  C08G59/56

    摘要： Disclosed are epoxy resins exhibiting a highly favorable combination of tensile strength and elongation with respect to prior art epoxy systems. The elastomeric epoxy resin systems of the invention are prepared utilizing a curing agent containing at least one monoprimary amine, and are particularly useful in applications such as, for example, castings, potting, composites, crack sealing, coatings, adhesives, roofing materials, flooring or reinforced membranes.

    摘要翻译： 公开了相对于现有技术的环氧树脂体系，表现出非常有利的拉伸强度和伸长率组合的环氧树脂。 本发明的弹性体环氧树脂体系是使用含有至少一种单原子胺的固化剂制备的，并且特别适用于诸如铸件，灌封，复合材料，裂缝密封，涂料，粘合剂，屋顶材料，地板 或增强膜。

    Process for preparing arylene sulfide polymers
    10.
    发明授权
    Process for preparing arylene sulfide polymers 失效
    亚芳基硫醚聚合物的制备方法

    公开(公告)号：US5364928A

    公开(公告)日：1994-11-15

    申请号：US062084

    申请日：1993-05-14

    申请人： Carlton E. Ash

    发明人： Carlton E. Ash

    IPC分类号： C08G75/02 ,  C08G75/06 ,  C08G75/16

    CPC分类号： C08G75/0259

    摘要： A process for preparing high molecular weight arylene sulfide polymers by dehydrating an aqueous mixture of a sulfur source and a cyclic organic amide to form a dehydrated mixture, contacting the dehydrated mixture with a dihaloaromatic compound to produce a polymerization mixture, polymerizing the polymerization mixture and recovering the arylene sulfide polymer wherein an aqueous alkali metal carboxylate mixture is added to the polymerization mixture after the conversion of the dihaloaromatic compound is about 40 percent to about 30 minutes prior to entering into termination of the polymerization. In another embodiment, a process for preparing high molecular weight arylene sulfide polymers by contacting an essentially anhydrous sulfur source, a cyclic organic amide, and a dihaloaromatic compound to form a polymerization mixture, polymerizing the polymerization mixture and recovering the arylene sulfide polymer wherein an aqueous alkali metal carboxylate mixture is added to the polymerization mixture after the conversion of the dihaloaromatic compound is about 40 percent to about 30 minutes prior to entering into termination of the polymerization.

    摘要翻译： 通过使硫源和环状有机酰胺的水性混合物脱水以形成脱水混合物来制备高分子量亚芳基硫醚聚合物的方法，使脱水混合物与二卤代芳族化合物接触以产生聚合混合物，使聚合混合物聚合并回收 在二聚卤代芳族化合物的转化之后将聚合混合物中的碱金属羧酸盐水溶液混合物的亚芳基硫醚聚合物在聚合终止之前约为40至30分钟。 在另一个实施方案中，通过使基本上无水的硫源，环状有机酰胺和二卤代芳族化合物接触以形成聚合混合物来制备高分子量亚芳基硫醚聚合物的方法，使聚合混合物聚合并回收亚芳基硫醚聚合物，其中含水 在进行聚合终止之前，二卤代芳族化合物的转化率为约40％至约30分钟之后，向聚合混合物中加入碱金属羧酸盐混合物。