Composition, energy storage device, and related processes
    1.
    发明授权
    Composition, energy storage device, and related processes 有权
    组成,储能装置及相关工艺

    公开(公告)号:US08603671B2

    公开(公告)日:2013-12-10

    申请号:US12977471

    申请日:2010-12-23

    IPC分类号: H01M6/04

    摘要: A positive electrode composition is provided. The composition includes at least one electroactive metal, such as titanium, vanadium, niobium, molybdenum, nickel, cobalt, chromium, manganese, silver, antimony, cadmium, tin, lead, and zinc. The composition further includes iron, at least one first alkali metal halide; and an electrolyte salt. The electrolyte salt can be based on a reaction product of a second alkali metal halide and an aluminum halide, and has a melting point of less than about 300 degrees Celsius. An article, an energy storage device, and an uninterruptable power supply device that includes the positive electrode composition are also described; as is a method of forming the energy storage device.

    摘要翻译: 提供正极组合物。 该组合物包括至少一种电活性金属,例如钛,钒,铌,钼,镍,钴,铬,锰,银,锑,镉,锡,铅和锌。 所述组合物还包含铁,至少一种第一碱金属卤化物; 和电解质盐。 电解质盐可以基于第二碱金属卤化物和卤化铝的反应产物,并且具有小于约300摄氏度的熔点。 还描述了包括正电极组合物的物品,能量存储装置和不间断电源装置; 形成能量存储装置的方法也是如此。

    Method of charging an electrochemical cell
    2.
    发明授权
    Method of charging an electrochemical cell 有权
    电化学电池的充电方法

    公开(公告)号:US08988047B2

    公开(公告)日:2015-03-24

    申请号:US13599469

    申请日:2012-08-30

    摘要: A method of pulse charging a secondary electrochemical storage cell is provided. The secondary cell includes a negative electrode comprising an alkaline metal; a positive electrode comprising at least one transition metal halide; a molten salt electrolyte comprising alkaline metal haloaluminate; and a solid electrolyte partitioning the positive electrode from the negative electrode, such that a first surface of the solid electrolyte is in contact with the positive electrode, and a second surface of the solid electrolyte is in contact with the negative electrode. The method of charging includes polarizing the cell by applying a polarizing voltage greater than about 0.1 V above the cell's rest potential for a first predetermined period of time; depolarizing the cell for a second predetermined period of time; and repeating the polarizing and depolarizing steps until a charging end-point is reached.

    摘要翻译: 提供了一种对二次电化学蓄电池进行脉冲充电的方法。 二次电池包括含有碱金属的负极; 包含至少一种过渡金属卤化物的正电极; 包含碱金属卤代铝酸盐的熔盐电解质; 以及将正极与负极分隔开的固体电解质,使得固体电解质的第一表面与正极接触,固体电解质的第二表面与负极接触。 充电方法包括通过在电池的静止电位之上施加大于约0.1V的极化电压来使电池偏振第一预定时间段; 使细胞去极化第二预定时间段; 并重复极化和去极化步骤直到达到充电终点。

    COMPOSITION, ENERGY STORAGE DEVICE, AND RELATED PROCESSES
    4.
    发明申请
    COMPOSITION, ENERGY STORAGE DEVICE, AND RELATED PROCESSES 审中-公开
    组合物,能量储存装置及相关方法

    公开(公告)号:US20120219843A1

    公开(公告)日:2012-08-30

    申请号:US13034184

    申请日:2011-02-24

    IPC分类号: H01M10/0562 H01M6/00 H01M2/18

    摘要: A positive electrode composition is provided. The positive electrode composition includes at least one electroactive metal selected from the group consisting of titanium, vanadium, niobium, molybdenum, nickel, cobalt, chromium, manganese, silver, antimony, cadmium, tin, lead, iron, and zinc. The composition further includes sodium iodide, present in an amount in a range from about 0.1 weight percent to about 0.9 weight percent, based on the weight of the positive electrode composition; a first alkali metal halide; and an electrolyte salt comprising a reaction product of a second alkali metal halide and an aluminum halide, wherein the electrolyte salt has a melting point of less than about 300 degrees Celsius. Related devices, such as a UPS device, also form embodiments of this invention.

    摘要翻译: 提供正极组合物。 正极组合物包括选自钛,钒,铌,钼,镍,钴,铬,锰,银,锑,镉,锡,铅,铁和锌中的至少一种电活性金属。 该组合物还包括以正电极组合物的重量计约0.1重量%至约0.9重量%的量的碘化钠; 第一碱金属卤化物; 以及包含第二碱金属卤化物和卤化铝的反应产物的电解质盐,其中电解质盐的熔点小于约300摄氏度。 相关设备,例如UPS设备,也形成本发明的实施例。

    METHOD OF CHARGING AN ELECTROCHEMICAL CELL
    6.
    发明申请
    METHOD OF CHARGING AN ELECTROCHEMICAL CELL 有权
    电化学电池充电方法

    公开(公告)号:US20140062412A1

    公开(公告)日:2014-03-06

    申请号:US13599469

    申请日:2012-08-30

    IPC分类号: H02J7/00

    摘要: A method of pulse charging a secondary electrochemical storage cell is provided. The secondary cell includes a negative electrode comprising an alkaline metal; a positive electrode comprising at least one transition metal halide; a molten salt electrolyte comprising alkaline metal haloaluminate; and a solid electrolyte partitioning the positive electrode from the negative electrode, such that a first surface of the solid electrolyte is in contact with the positive electrode, and a second surface of the solid electrolyte is in contact with the negative electrode. The method of charging includes polarizing the cell by applying a polarizing voltage greater than about 0.1 V above the cell's rest potential for a first predetermined period of time; depolarizing the cell for a second predetermined period of time; and repeating the polarizing and depolarizing steps until a charging end-point is reached.

    摘要翻译: 提供了一种对二次电化学蓄电池进行脉冲充电的方法。 二次电池包括含有碱金属的负极; 包含至少一种过渡金属卤化物的正电极; 包含碱金属卤代铝酸盐的熔盐电解质; 以及将正极与负极分隔开的固体电解质,使得固体电解质的第一表面与正极接触,固体电解质的第二表面与负极接触。 充电方法包括通过在电池的静止电位之上施加大于约0.1V的极化电压来使电池偏振第一预定时间段; 使细胞去极化第二预定时间段; 并重复极化和去极化步骤直到达到充电终点。

    COMPOSITION, ENERGY STORAGE DEVICE, AND RELATED PROCESSES
    8.
    发明申请
    COMPOSITION, ENERGY STORAGE DEVICE, AND RELATED PROCESSES 有权
    组合物,能量储存装置及相关方法

    公开(公告)号:US20120164524A1

    公开(公告)日:2012-06-28

    申请号:US12977471

    申请日:2010-12-23

    IPC分类号: H01M10/0561 H01M6/00 H01M4/38

    摘要: A positive electrode composition is provided. The positive electrode composition includes at least one electroactive metal, such as titanium, vanadium, niobium, molybdenum, nickel, cobalt, chromium, manganese, silver, antimony, cadmium, tin, lead, and zinc. The electroactive metal is present in an amount in a range from about 10 volume percent to about 20 volume percent, based on the volume of the positive electrode composition. The composition further includes iron, present in an amount in a range from about 0.2 volume percent to about 3 volume percent, based on the volume of the positive electrode composition; at least one first alkali metal halide; and an electrolyte salt. The electrolyte salt can be based on a reaction product of a second alkali metal halide and an aluminum halide, and has a melting point of less than about 300 degrees Celsius. An article, an energy storage device, and an uninterruptable power supply device that includes the positive electrode composition are also described; as is a method of forming the energy storage device.

    摘要翻译: 提供正极组合物。 正极组合物包括至少一种电活性金属,例如钛,钒,铌,钼,镍,钴,铬,锰,银,锑,镉,锡,铅和锌。 基于正极组合物的体积,电活性金属的存在量为约10体积%至约20体积%。 所述组合物还包含以所述正极组合物的体积计约0.2体积%至约3体积%的量存在的铁; 至少一种第一碱金属卤化物; 和电解质盐。 电解质盐可以基于第二碱金属卤化物和卤化铝的反应产物,并且具有小于约300摄氏度的熔点。 还描述了包括正电极组合物的物品,能量存储装置和不间断电源装置; 形成能量存储装置的方法也是如此。