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公开(公告)号:US5167854A
公开(公告)日:1992-12-01
申请号:US402207
申请日:1989-09-01
IPC分类号: C12S3/04 , C01B15/10 , C11D3/02 , C11D3/37 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D3/50 , C11D7/54 , C11D17/00 , C11D17/04 , C11D17/08 , D06L3/02 , D06L3/11 , D06M11/00 , D06M11/79 , D06M16/00 , D06M23/12
CPC分类号: C11D3/02 , C11D17/0039 , C11D17/041 , C11D3/3761 , C11D3/38672 , C11D3/3937 , C11D3/3942 , C11D3/3945 , C11D3/42 , C11D3/505
摘要: The invention relates to a bleaching composition containing an oxidant bleach and enzyme granules, in which enzyme stability is prolonged without undue loss of solubility despite intimate contact of said enzyme granules and said oxidant bleach, comprising:an oxidant bleach, selected from the group consisting of alkali-metal peroborates, alkali metal percarbonates, hydrogen peroxide adducts, and mixtures thereof and hydrolase enzyme granules comprising a hydrolase enzyme core and a water soluble alkali metal silicate coating substantially encapsulating said core, said coating including at least one protective agent, said agent being selected from the group consisting of transition metals; reducing agents; and mixtures thereof. Sodium percarbonate is a preferred oxidant, while transition metals combined with a sodium silicate coating provide enhanced storage stability to the enzymes thereby coated.
摘要翻译: 本发明涉及含有氧化剂漂白剂和酶颗粒的漂白组合物,其中酶稳定性延长而不会导致溶解度的不适当损失,尽管所述酶颗粒和所述氧化剂漂白剂的密切接触,包括:氧化剂漂白剂,其选自 碱金属过硼酸盐,碱金属过碳酸盐,过氧化氢加合物及其混合物,以及包含水解酶核心和基本上包封所述核心的水溶性碱金属硅酸盐涂层的水解酶颗粒,所述涂层包括至少一种保护剂,所述试剂为 选自过渡金属; 还原剂; 及其混合物。 过碳酸钠是优选的氧化剂,而与硅酸钠涂层结合的过渡金属提供了对由此被涂覆的酶提供的储存稳定性。
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公开(公告)号:US5254287A
公开(公告)日:1993-10-19
申请号:US821522
申请日:1992-01-13
IPC分类号: C11D3/02 , C11D3/37 , C11D3/386 , C11D3/39 , C11D3/42 , C11D3/50 , C11D17/00 , C11D17/04 , C01B15/055
CPC分类号: C11D17/041 , C11D17/0039 , C11D3/02 , C11D3/3761 , C11D3/38672 , C11D3/3937 , C11D3/3942 , C11D3/3945 , C11D3/42 , C11D3/505
摘要: The invention relates to a bleaching composition containing an oxidant bleach and enzyme granules, in which enzyme stability is prolonged without undue loss of solubility despite intimate contact of said enzyme granules with said oxidant bleach. In the invention, an oxidant is selected from the group consisting of alkali metal perborates, alkali metal percarbonates, hydrogen peroxide adducts, and mixtures thereof, and combined with an enzyme which is coated substantially completely by a water soluble polymer, in which an additive selected from the group consisting of reducing agents, a transition metal, and mixtures thereof is incorporated to enhance enzyme stability.
摘要翻译: 本发明涉及一种含有氧化剂漂白剂和酶颗粒的漂白组合物,其中酶稳定性延长而不会导致溶解度的不适当损失,尽管所述酶颗粒与所述氧化剂漂白剂密切接触。 在本发明中,氧化剂选自碱金属过硼酸盐,碱金属过碳酸盐,过氧化氢加合物及其混合物,并与基本上完全由水溶性聚合物涂覆的酶组合,其中选择添加剂 由还原剂,过渡金属及其混合物组成的组合以提高酶的稳定性。
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公开(公告)号:US5112514A
公开(公告)日:1992-05-12
申请号:US675240
申请日:1991-03-25
申请人: Steven A. Bolkan , Kelly J. Brodbeck , Kevin J. Brodbeck , David L. Deleeuw , Dale S. Steichen , Bruce B. Strand , Richard J. V. Suk , Kathleen D. Szuch , Alfred G. Zielske
发明人: Steven A. Bolkan , Kelly J. Brodbeck , Kevin J. Brodbeck , David L. Deleeuw , Dale S. Steichen , Bruce B. Strand , Richard J. V. Suk , Kathleen D. Szuch , Alfred G. Zielske
IPC分类号: C07C409/24 , C11D3/39
CPC分类号: C11D3/3935 , C11D3/3907
摘要: The present invention provides stable bleach activator granules comprising:a) a peroxygen bleach activator having the structure: ##STR1## wherein R is C.sub.1-20 branched or straight chain alkyl, alkoxylated alkyl, cycloalkyl, alkenyl, aryl, substituted aryl, alkylaryl; R' and R" are independently H, C.sub.1-4 alkyl, aryl; and L is a leaving group;b) a pliable binding material selected from materials having a melting completion temperature of greater than about 40.degree. C.; and, optionally,c) a filler material.These bleach activator granules are combined with a detergent base which contains an oxidant bleach to provide an activated oxidant detergent composition.
摘要翻译: 本发明提供稳定的漂白活化剂颗粒,其包含:a)具有以下结构的过氧漂白活化剂:其中R为C 1-20支链或直链烷基,烷氧基化烷基,环烷基,烯基,芳基,取代的芳基,烷基芳基; R'和R“独立地是H,C 1-4烷基,芳基; L是离去组; b)选自具有大于约40℃的熔融完成温度的材料的柔韧粘合材料; 和任选地,c)填料。 这些漂白活化剂颗粒与含有氧化剂漂白剂以提供活化的氧化剂洗涤剂组合物的洗涤剂底物组合。
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公开(公告)号:US5002691A
公开(公告)日:1991-03-26
申请号:US258225
申请日:1988-10-14
申请人: Steven A. Bolkan , Kelly I. Brodbeck , Kevin J. Brodbeck , David L. Deleeuw , Dale S. Steichen , Bruce B. Strand , Richard J. V. Suk , Kathleen D. Szuch , Alfred G. Zielske
发明人: Steven A. Bolkan , Kelly I. Brodbeck , Kevin J. Brodbeck , David L. Deleeuw , Dale S. Steichen , Bruce B. Strand , Richard J. V. Suk , Kathleen D. Szuch , Alfred G. Zielske
IPC分类号: C11D7/54 , C07C409/24 , C11D3/39 , C11D17/06 , D06L3/02
CPC分类号: C11D3/3935 , C11D3/3907
摘要: The present invention provides stable bleach activator granules comprising:a) a peroxygen bleach activator having the structure: ##STR1## wherein R is C.sub.1-20 branched or straight chain alkyl, alkoxylated alkyl, cycloalkyl, alkenyl, aryl, substituted aryl, alkylaryl; R' and R" are independently H, C.sub.1-4 alkyl, aryl; and L is a leaving group;b) a pliable binding material selected from materials having a melting completion temperature of greater than about 40.degree. C.; and, optionally,c) a filler material.These bleach activator granules are combined with a detergent base which contains an oxidant bleach to provide an activated oxidant detergent composition.
摘要翻译: 本发明提供稳定的漂白活化剂颗粒,其包含:a)具有以下结构的过氧漂白活化剂:其中R为C 1-20支链或直链烷基,烷氧基化烷基,环烷基,烯基,芳基,取代的芳基,烷基芳基; R'和R“独立地是H,C 1-4烷基,芳基; L是离去组; b)选自具有大于约40℃的熔融完成温度的材料的柔韧粘合材料; 和任选地,c)填料。 这些漂白活化剂颗粒与含有氧化剂漂白剂以提供活化的氧化剂洗涤剂组合物的洗涤剂底物组合。
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公开(公告)号:US5589448A
公开(公告)日:1996-12-31
申请号:US474353
申请日:1995-06-07
申请人: Michael Koerner , David L. Deleeuw
发明人: Michael Koerner , David L. Deleeuw
CPC分类号: C11D3/38636 , C11D1/825 , C11D1/8255 , C11D17/0026 , C11D3/38618 , C11D3/38627 , C11D3/38645 , C11D1/72 , C11D1/722
摘要: The invention provides a high water liquid enzyme prewash composition essentially free of hydrotropes, solvents and dispersants other than nonionic surfactants, and combines: a) effective amounts of a hydrolase enzyme stabilized with a soluble alkaline earth salt; b) a more hydrophilic, first nonionic surfactant having an HLB of greater than about 11; c) a more hydrophobic, second nonionic surfactant having an HLB of less than or equal to about 11; d) at least 80% or greater water; wherein the difference in HLB between said first and second nonionic surfactants is at least about 2, and said nonionic surfactants interact with said water to form an opalescent, structured liquid, said structured liquid both suspending said hydrolase and protecting said hydrolase against deactivation with said water. Suitable adjuncts, such as mildewstats/bacteristats, fragrances and dyes can be included.
摘要翻译: 本发明提供了一种基本上不含除非离子表面活性剂之外的水溶助长剂,溶剂和分散剂的高水液体酶预洗组合物,并且组合:a)有效量的用可溶性碱土盐稳定的水解酶; b)HLB大于约11的更亲水的第一非离子表面活性剂; c)HLB小于或等于约11的更疏水的第二非离子表面活性剂; d)至少80%以上的水; 其中所述第一和第二非离子表面活性剂之间的HLB差异为至少约2,并且所述非离子表面活性剂与所述水相互作用以形成乳光的结构化液体,所述结构化液体均悬浮所述水解酶并保护所述水解酶免受所述水失活 。 可以包括合适的助剂,如防霉剂/抑菌剂,香料和染料。
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