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    Method for the preparation of metal carbene complexes
    1.
    发明授权
    Method for the preparation of metal carbene complexes 失效
    金属卡宾络合物的制备方法

    公开(公告)号：US06844442B2

    公开(公告)日：2005-01-18

    申请号：US10474813

    申请日：2002-04-15

    申请人： David Milstein ,  Mark Gandelman ,  Nissan Ashkenazi ,  Boris Rybtchinski

    发明人： David Milstein ,  Mark Gandelman ,  Nissan Ashkenazi ,  Boris Rybtchinski

    IPC分类号： C07C381/00 ,  C07F15/00 ,  B01J31/00 ,  C07F9/22

    CPC分类号： C07F15/0046 ,  C07C381/00 ,  C07F15/002

    摘要： The present invention provides a process for preparing a metal carbene complex of formula (I): wherein M is a transition metal atom selected from the group consisting of ruthenium, rhodium, iron, cobalt, osmium and iridium; L denotes neutral donor ligands ligated to said metal, such groups being the same or different; X is an anionic ligand; R1 and R2 are each independently selected from the group consisting of hydrogen, substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C2-C20 alkenyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted vinyl, a is 2 or 3 and b is 1 or 2, such process comprising reacting a sulfur ylide of the formula Ar2S═CR1R2 or its precursor with an appropriate metal complex comprising a transition metal atom selected from the group consisting of ruthenium, rhodium, iron, cobalt, osmium and iridium, said metal complex being also in dimeric form, at a temperature between +80° C. and −80° C., in an inert solvent and under inert atmosphere.

    摘要翻译： 本发明提供了制备式（I）的金属卡宾络合物的方法：其中M是选自钌，铑，铁，钴，锇和铱的过渡金属原子; L表示与所述金属连接的中性供体配体，这些基团相同或不同; X是阴离子配体; R 1和R 2各自独立地选自氢，取代或未取代的C 1 -C 20烷基，取代或未取代的C 2 -C 20烯基，取代或未取代的环烷基，取代或未取代的杂环烷基，取代或未取代的芳基，取代或未取代的杂芳基， 取代或未取代的乙烯基，a为2或3，b为1或2，该方法包括使式Ar 2 S = CR 1 R 2或其前体的硫叶立德与包含过渡金属原子的合适的金属络合物 选自钌，铑，铁，钴，锇和铱，所述金属络合物也是二聚体形式，在+ 80℃和-80℃之间的温度下，在惰性溶剂中，在惰性溶剂 大气层。

    Diarylphosphine- and dialkylphosphine-containing compounds, processes of preparing same and uses thereof as tridentate ligands
    3.
    发明授权
    Diarylphosphine- and dialkylphosphine-containing compounds, processes of preparing same and uses thereof as tridentate ligands 有权
    含二芳基膦和二烷基膦的化合物，其制备方法和用途作为三齿配体

    公开(公告)号：US08318960B2

    公开(公告)日：2012-11-27

    申请号：US12779093

    申请日：2010-05-13

    申请人： Mark Gandelman ,  Elaine Melissa Schuster ,  Gennady Nisnevich

    发明人： Mark Gandelman ,  Elaine Melissa Schuster ,  Gennady Nisnevich

    IPC分类号： C07F9/02

    CPC分类号： C07D249/04 ,  B01J31/189 ,  B01J31/226 ,  B01J2231/4261 ,  B01J2531/0244 ,  B01J2531/824 ,  B01J2531/828 ,  C07F9/5013 ,  C07F9/5304 ,  C07F9/6518 ,  C07F9/65583 ,  C07F15/006 ,  C40B30/08 ,  C40B40/04 ,  C40B40/16

    摘要： A novel process of preparing tridentate ligands containing one or more of a diarylphosphine and/or dialkylphosphine electron donating groups are disclosed. Use of this process for preparing a combinatorial library of such tridentate ligands and of organometallic complexes containing same is also disclosed. Further disclosed are novel diarylphosphine-containing and dialkylphosphine-containing compounds that can serve as tridentate ligands (e.g., pincer ligands), combinatorial libraries of such tridentate ligands, organometallic complexes containing these ligands (e.g., pincer complexes), and combinatorial libraries of such complexes. Methods utilizing these libraries for screening for candidate organometallic catalysts are also disclosed. Novel precursor molecules useful for preparing the tridentate ligands and processes of preparing same are also disclosed.

    摘要翻译： 公开了一种制备含有一个或多个二芳基膦和/或二烷基膦给电子基团的三齿配体的新方法。 还公开了该方法用于制备这种三齿配体的组合文库和含有它们的有机金属络合物的用途。 还公开了可以用作三齿配体（例如夹心配体）的新型含二芳基膦和含二烷基膦的化合物，这种三齿配体的组合文库，含有这些配体的有机金属配合物（例如夹心络合物）和这种配合物的组合文库 。 还公开了利用这些文库筛选候选有机金属催化剂的方法。 还公开了可用于制备三齿配体的新型前体分子及其制备方法。

    Diarylphosphine-containing compounds, processes of preparing same and uses thereof as tridentate ligands
    4.
    发明授权
    Diarylphosphine-containing compounds, processes of preparing same and uses thereof as tridentate ligands 失效
    含二芳基膦的化合物，其制备方法及其作为三齿配体的用途

    公开(公告)号：US08481746B2

    公开(公告)日：2013-07-09

    申请号：US12465719

    申请日：2009-05-14

    申请人： Mark Gandelman ,  Elaine Melissa Schuster

    发明人： Mark Gandelman ,  Elaine Melissa Schuster

    IPC分类号： C07F17/02

    CPC分类号： C07F15/006 ,  B01J31/189 ,  B01J31/226 ,  B01J2231/4261 ,  B01J2531/824 ,  B01J2531/828 ,  C07F9/6518 ,  C07F9/65583 ,  C40B30/08 ,  C40B40/04 ,  C40B40/16

    摘要： A novel process of preparing tridentate ligands containing a diarylphosphine electron donating group are disclosed. Use of this process for preparing a combinatorial library of such tridentate ligands and of organometallic complexes containing same is also disclosed. Further disclosed are novel diarylphosphine-containing compounds that can serve as tridentate ligands (e.g., pincer ligands), combinatorial libraries of such tridentate ligands, organometallic complexes containing these ligands (e.g., pincer complexes), and combinatorial libraries of such complexes. Methods utilizing these libraries for screening for candidate organometallic catalysts are also disclosed.

    摘要翻译： 公开了一种制备含有二芳基膦给电子基团的三齿配体的新方法。 还公开了该方法用于制备这种三齿配体的组合文库和含有它们的有机金属络合物的用途。 还公开了可用作三齿配体（例如夹心配体）的新型二芳基膦化合物，这种三齿配体的组合文库，含有这些配体的有机金属络合物（例如夹心络合物）以及这些配合物的组合文库。 还公开了利用这些文库筛选候选有机金属催化剂的方法。