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1.发明授权Composition formed of mercaptans which can be used in a process for the flotation of ores 有权由硫醇组成的组合物，可用于矿石浮选的过程公开(公告)号：US07014048B2
公开(公告)日：2006-03-21
申请号：US10863935
申请日：2004-06-09
申请人： Didier Anglerot , Annie Commarieu , Thierry Aubert
发明人： Didier Anglerot , Annie Commarieu , Thierry Aubert
CPC分类号： B03D1/014 , B03D1/008 , B03D1/012 , B03D2201/02 , B03D2203/02 , B03D2203/025 , B03D2203/04 , C22B1/00 , C22B11/04
摘要： Composition intended for the flotation of ores, comprising: from 70 to 95% of a combination (A) of n-dodecyl mercaptan (or NDM) and of tert-dodecyl mercaptan (or TDM), the NDM/TDM ratio by weight of which is between 0.5 and 1.5, and from 5 to 30% of a product (B) composed of one or more aromatic or aliphatic compounds comprising from 4 to 100 carbon atoms, preferably from 5 to 40, and having one or two —OH groups. Process for the recovery by flotation of metal compounds of value present in ores employing it.
摘要翻译： 用于矿石浮选的组合物，包括：70-95％的正十二烷基硫醇（或NDM）和叔十二烷基硫醇（或TDM）的组合（A），其重量的NDM / TDM比例 是由包含4至100个碳原子，优选5至40个并且具有一个或两个-OH基团的一种或多种芳族或脂族化合物组成的产物（B）的0.5至1.5％和5至30％。 通过浮选使用它的矿石中存在的金属化合物进行回收的方法。
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2.发明申请Composition formed of mercaptans which can be used in a process for the flotation of ores 有权由硫醇组成的组合物，可用于矿石浮选的过程公开(公告)号：US20050167339A1
公开(公告)日：2005-08-04
申请号：US10863935
申请日：2004-06-09
申请人： Didier Anglerot , Annie Commarieu , Thierry Aubert
发明人： Didier Anglerot , Annie Commarieu , Thierry Aubert
CPC分类号： B03D1/014 , B03D1/008 , B03D1/012 , B03D2201/02 , B03D2203/02 , B03D2203/025 , B03D2203/04 , C22B1/00 , C22B11/04
摘要： Composition intended for the flotation of ores, comprising: from 70 to 95% of a combination (A) of n-dodecyl mercaptan (or NDM) and of tert-dodecyl mercaptan (or TDM), the NDM/TDM ratio by weight of which is between 0.5 and 1.5, and from 5 to 30% of a product (B) composed of one or more aromatic or aliphatic compounds comprising from 4 to 100 carbon atoms, preferably from 5 to 40, and having one or two —OH groups. Process for the recovery by flotation of metal compounds of value present in ores employing it.
摘要翻译： 用于矿石浮选的组合物，其包含：70-95％的正十二烷基硫醇（或NDM）和叔十二烷基硫醇（或TDM）的组合（A），其重量的NDM / TDM比例 是由包含4至100个碳原子，优选5至40个并且具有一个或两个-OH基团的一种或多种芳族或脂族化合物组成的产物（B）的0.5至1.5％和5至30％。 通过浮选使用它的矿石中存在的金属化合物进行回收的方法。
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公开(公告)号：US06235198B1
公开(公告)日：2001-05-22
申请号：US09078414
申请日：1998-05-14
申请人： Annie Commarieu , Francis Humblot
发明人： Annie Commarieu , Francis Humblot
IPC分类号： C07C31506
CPC分类号： C07C315/06 , C07C317/04
摘要： To purify a dimethyl sulphoxide (DMSO), it is placed in contact with a plurality of cation exchange resins at least one of which is a resin of sulphonic type in —SO3H or —SO3NH4 form, it being possible for the other or others to be of chelating type. The DMSO thus obtained has an iron cation content lower than 1 ppb and a sodium cation content lower than 2 ppb.
摘要翻译： 为了纯化二甲基亚砜（DMSO），将其与多个阳离子交换树脂接触，其中至少一种是-SO 3 H或-SO 3 NH 4形式的磺酸树脂，其他或其它可能是 的螯合型。 由此获得的DMSO具有低于1ppb的铁阳离子含量和低于2ppb的钠阳离子含量。
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公开(公告)号：US07227046B2
公开(公告)日：2007-06-05
申请号：US10466814
申请日：2002-01-08
申请人： Annie Commarieu
发明人： Annie Commarieu
摘要： The continuous process for manufacturing bisphenol A according to the invention, by reacting phenol and acetone in the presence of a strong acid catalyst and a co-catalyst, is carried out using as co-catalyst a dithio ether of general formula: in which the symbols R and R′ each represent a hydrogen atom, an alkyl radical or a phenyl radical, and the symbol R″ represents an optionally substituted alkyl radical.
摘要翻译： 通过使苯酚和丙酮在强酸催化剂和助催化剂存在下反应制备本发明的双酚A的连续方法使用通式如下的二硫醚作为助催化剂进行：其中符号 R和R'各自表示氢原子，烷基或苯基，符号R“表示任选取代的烷基。
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公开(公告)号：US20130084643A1
公开(公告)日：2013-04-04
申请号：US13518827
申请日：2010-12-22
申请人： Annie Commarieu , Fabrice Aubertin , Nicolas Crowther , Cédric Louis , Pascal Perriat , Matteo Martini , Olivier Tillement
发明人： Annie Commarieu , Fabrice Aubertin , Nicolas Crowther , Cédric Louis , Pascal Perriat , Matteo Martini , Olivier Tillement
CPC分类号： E21B47/00 , B82Y15/00 , C09K8/03 , C09K8/58 , C09K11/06 , C09K11/592 , E21B47/1015 , G01N21/64 , Y10S977/773 , Y10S977/902
摘要： The present invention relates to the development of tracer fluids, more generally, that of aqueous liquids, intended to be injected under pressure in an oil reservoir, for example from an injection well up to a production well.The object of the invention is to propose a new method of study of a solid medium, i.e. an oil reservoir, by diffusion of a liquid (i.e. injection waters) containing tracers, through said solid medium, which is simple to implement and economical and which remedies the drawbacks of the known tracers for injection waters of oil reservoirs.This method essentially consisting of injecting, in this solid medium, an injection liquid comprising a nanoparticle-based tracer having average dimensions comprised between 20 and 200 nm, detectable by means of one or several S signals at dilutions of less than or equal to 10−7, adapted to form a stable colloidal suspension in a saline medium, at least a portion of which is constituted of a core and a coating provided with an adjustable hydrophilic-lipophilic balance (HLB) and comprising at least one organic and/or organosilicon component; recovering the liquid having diffused; and analyzing this liquid having diffused to measure the quantity of tracer by detection of the signal or signals S.
摘要翻译： 本发明涉及示踪流体的开发，更一般地说，旨在在储油器中例如从注入井到生产井的压力下注入含水液体。 本发明的目的是提出一种通过所述固体介质通过扩散含有示踪剂的液体（即注射水）的固体介质，即储油器的研究的新方法，所述固体介质易于实施和经济，并且其中 弥补了油藏注射水已知示踪剂的缺点。 该方法基本上包括在该固体培养基中注入含有平均尺寸在20和200nm之间的纳米颗粒型示踪剂的注射液，其可以通过少于或等于10- 7，适于在盐水介质中形成稳定的胶体悬浮液，其至少一部分由芯和具有可调亲水亲油平衡（HLB）的涂层构成，并且包含至少一种有机和/或有机硅组分 ; 回收扩散的液体; 并且通过检测信号或信号S来分析扩散的液体来测量示踪剂的量。
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6.发明授权
公开(公告)号：US5801283A
公开(公告)日：1998-09-01
申请号：US842396
申请日：1997-04-24
申请人： Jean Ollivier , Annie Commarieu
发明人： Jean Ollivier , Annie Commarieu
IPC分类号： C07C303/02 , C07C303/22 , C07C303/44 , C07C309/04 , C07C309/80 , C07C143/70
CPC分类号： C07C303/22 , C07C303/44
摘要： The process for the purification of an alkanesulphonyl chloride (ASC) in order to reduce the sulphate content thereof consists in washing the alkanesulphonyl chloride with water or with an aqueous solution of an acid having a pH of between -0.57 and 7 and then in separating the alkanesulphonyl chloride thus purified from the aqueous phase. This purified ASC leads, by total hydrolysis, to alkanesulphonic acid with a low content of sulphuric acid.
摘要翻译： 用于纯化烷基磺酰氯（ASC）以降低其硫酸盐含量的方法在于用水或与pH在-0.57和7之间的酸的水溶液洗涤烷基磺酰氯，然后分离 由此从水相中纯化出烷基磺酰氯。 该纯化的ASC通过全部水解导致具有低含量硫酸的烷烃磺酸。
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公开(公告)号：US09260957B2
公开(公告)日：2016-02-16
申请号：US13518827
申请日：2010-12-22
申请人： Annie Commarieu , Fabrice Aubertin , Nicolas Crowther , Cédric Louis , Pascal Perriat , Matteo Martini , Olivier Tillement
发明人： Annie Commarieu , Fabrice Aubertin , Nicolas Crowther , Cédric Louis , Pascal Perriat , Matteo Martini , Olivier Tillement
CPC分类号： E21B47/00 , B82Y15/00 , C09K8/03 , C09K8/58 , C09K11/06 , C09K11/592 , E21B47/1015 , G01N21/64 , Y10S977/773 , Y10S977/902
摘要： The present invention relates to the development of tracer fluids, more generally, that of aqueous liquids, intended to be injected under pressure in an oil reservoir, for example from an injection well up to a production well.The object of the invention is to propose a new method of study of a solid medium, i.e. an oil reservoir, by diffusion of a liquid (i.e. injection waters) containing tracers, through said solid medium, which is simple to implement and economical and which remedies the drawbacks of the known tracers for injection waters of oil reservoirs.This method essentially consisting of injecting, in this solid medium, an injection liquid comprising a nanoparticle-based tracer having average dimensions comprised between 20 and 200 nm, detectable by means of one or several S signals at dilutions of less than or equal to 10−7, adapted to form a stable colloidal suspension in a saline medium, at least a portion of which is constituted of a core and a coating provided with an adjustable hydrophilic-lipophilic balance (HLB) and comprising at least one organic and/or organosilicon component; recovering the liquid having diffused; and analyzing this liquid having diffused to measure the quantity of tracer by detection of the signal or signals S.
摘要翻译： 本发明涉及示踪流体的开发，更一般地说，旨在在储油器中例如从注入井到生产井的压力下注入含水液体。 本发明的目的是提出一种通过所述固体介质通过扩散含有示踪剂的液体（即注射水）的固体介质，即储油器的研究的新方法，所述固体介质易于实施和经济，并且其中 弥补了油藏注射水已知示踪剂的缺点。 该方法基本上包括在该固体培养基中注入含有平均尺寸在20和200nm之间的纳米颗粒型示踪剂的注射液，其可以通过少于或等于10- 7，适于在盐水介质中形成稳定的胶体悬浮液，其至少一部分由芯和具有可调亲水亲油平衡（HLB）的涂层构成，并且包含至少一种有机和/或有机硅组分 ; 回收扩散的液体; 并且通过检测信号或信号S来分析扩散的液体以测量示踪剂的量。
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公开(公告)号：US5493058A
公开(公告)日：1996-02-20
申请号：US321701
申请日：1994-10-12
IPC分类号： B01J27/043 , B01J27/047 , B01J27/051 , C07B61/00 , C07C319/06 , C07C321/04
CPC分类号： C07C319/06
摘要： The invention relates to the manufacture of methyl mercaptan by catalytic hydrogenation of dimethyl disulphide on a catalyst based on sulphide(s) of at least one transition metal.The selectivity with respect to methyl mercaptan is considerably improved by working in the presence of water and/or hydrogen sulphide.
摘要翻译： 本发明涉及通过在基于至少一种过渡金属的硫化物的催化剂上二甲基二硫化物的催化氢化制备甲硫醇。 通过在水和/或硫化氢的存在下工作，相对于甲硫醇的选择性得到显着提高。
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公开(公告)号：US08853619B2
公开(公告)日：2014-10-07
申请号：US13094411
申请日：2011-04-26
CPC分类号： E21B47/1015 , E21B43/16 , G01N2030/8854
摘要： The invention concerns a method for surveying a subsurface formation containing hydrocarbons, comprising: injecting at least one tracer compound into the subsurface formation; recovering a fluid derived from the subsurface formation; detecting the tracer compound in the fluid by liquid chromatography analysis coupled with tandem mass spectrometry analysis, the liquid chromatography analysis being conducted with a stationary phase composed of particles having a mean size equal to or less than 2.1 μm.
摘要翻译： 本发明涉及一种用于测量含有烃的地下地层的方法，包括：将至少一种示踪剂化合物注入到地下地层中; 回收源自地下地层的流体; 通过液相色谱分析与串联质谱分析结合检测流体中的示踪剂化合物，液相色谱分析用平均尺寸等于或小于2.1μm的颗粒构成的固定相进行。
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公开(公告)号：US20110260051A1
公开(公告)日：2011-10-27
申请号：US13094411
申请日：2011-04-26
IPC分类号： H01J49/26
CPC分类号： E21B47/1015 , E21B43/16 , G01N2030/8854
摘要： The invention concerns a method for surveying a subsurface formation containing hydrocarbons, comprising: injecting at least one tracer compound into the subsurface formation; recovering a fluid derived from the subsurface formation; detecting the tracer compound in the fluid by liquid chromatography analysis coupled with tandem mass spectrometry analysis, the liquid chromatography analysis being conducted with a stationary phase composed of particles having a mean size equal to or less than 2.1 μm.
摘要翻译： 本发明涉及一种用于测量含有烃的地下地层的方法，包括：将至少一种示踪剂化合物注入到地下地层中; 回收源自地下地层的流体; 通过液相色谱分析与串联质谱分析结合检测流体中的示踪剂化合物，液相色谱分析用平均尺寸等于或小于2.1μm的颗粒构成的固定相进行。
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