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109 条记录 (耗时 0.034 秒)

    Hindered amine light stabilizer, methods of making, and compositions
    6.
    发明授权
    Hindered amine light stabilizer, methods of making, and compositions 失效
    受阻胺光稳定剂，制备方法和组合物

    公开(公告)号：US07538130B2

    公开(公告)日：2009-05-26

    申请号：US11234898

    申请日：2005-09-26

    申请人： Donald H. Campbell ,  Donald L. St. Aubin ,  Walter H. Ohrbom ,  John E. Boisseau

    发明人： Donald H. Campbell ,  Donald L. St. Aubin ,  Walter H. Ohrbom ,  John E. Boisseau

    IPC分类号： A61K31/421 ,  A61K31/5375 ,  C07D263/04 ,  C07D265/04

    CPC分类号： C08K5/35

    摘要： A compound in which n is 0, 1, 2, or 3; R1, R2, R7, and R8 are each independently alkyl group, including cycloalkyl, an alkylaryl group, or an aryl group, optionally with one or more heteroatoms, with the proviso that R1 and R2 can together form a cycloalkylene group and, independently, R7 and R8 can together form a cycloalkylene group; Y is an oxygen free radical, a sulfur free radical, OR9 or SR9; R3, R4, R5, R6, and R9 are each independently H or an alkyl group, a cycloalkyl group, an aryl group, or an alkylaryl group, optionally with one or more heteroatoms; and compositions, such as basecoat and clearcoat coating compositions, containing such compounds.

    摘要翻译： n为0,1,2或3的化合物; R 1，R 2，R 7和R 8各自独立地为烷基，包括环烷基，烷基芳基或芳基，任选具有一个或多个杂原子，条件是R 1和R 2可以一起形成亚环烷基， R7和R8可以一起形成亚环烷基; Y是氧自由基，无硫自由基，OR9或SR9; R 3，R 4，R 5，R 6和R 9各自独立地为H或烷基，环烷基，芳基或烷基芳基，任选具有一个或多个杂原子; 以及含有这些化合物的组合物，如底漆和透明涂料涂料组合物。

    Carbamate functional addition polymers and method for their preparation
    7.
    发明授权
    Carbamate functional addition polymers and method for their preparation 失效
    氨基甲酸酯官能加成聚合物及其制备方法

    公开(公告)号：US07342075B2

    公开(公告)日：2008-03-11

    申请号：US10957556

    申请日：2004-10-01

    申请人： Swaminathan Ramesh ,  Paul J. Harris ,  Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin ,  Ulrike Röckrath

    发明人： Swaminathan Ramesh ,  Paul J. Harris ,  Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin ,  Ulrike Röckrath

    IPC分类号： C08F8/28

    CPC分类号： C08F220/06 ,  C08F8/00 ,  C08F8/14 ,  C08F220/08 ,  C08F222/20 ,  C08F222/22 ,  C08L2312/00 ,  C09D133/14 ,  C09D201/025 ,  C08F265/06

    摘要： Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C═C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C═C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.

    摘要翻译： 公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。 该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C-C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C-C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。 还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

    Functional addition polymers and a method for their preparation
    8.
    发明授权
    Functional addition polymers and a method for their preparation 有权
    官能加成聚合物及其制备方法

    公开(公告)号：US07232863B2

    公开(公告)日：2007-06-19

    申请号：US10957568

    申请日：2004-10-01

    申请人： Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin ,  Swaminathan Ramesh ,  Paul J. Harris ,  Ulrike Röckrath

    发明人： Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin ,  Swaminathan Ramesh ,  Paul J. Harris ,  Ulrike Röckrath

    IPC分类号： C08F8/14

    CPC分类号： C08F222/20 ,  C08F8/14 ,  C08F220/06 ,  C08F220/08 ,  C08F222/22 ,  C08G18/00 ,  C09D201/025 ,  Y10T428/31511 ,  C08F265/06

    摘要： Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C═C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.

    摘要翻译： 公开了一种从线性不饱和酸酐制造非功能性加成聚合物的方法。 该方法使线性不饱和酸酐化合物，活性氢化合物和环氧化合物反应，使得发生以下三个反应中的每一个：（i）可聚合的CC键的聚合，（ii）酸酐官能团的开环 的线性不饱和酸酐化合物，以产生酸官能团，和（iii）由酸酐开环产生的酸官能团与环氧化合物的反应。 在反应（iii）时，由酸酐开环产生的酸官能团可以选自烯属不饱和单体，聚合物或两者。 在一个实施方案中，该方法不包括物理去除任何酸官能单体或聚合产物。 还公开了可固化涂料组合物和涂布的基材。

    Method for modified aminoplast compounds, aminoplasts obtained thereby and coatings containing the same
    9.
    发明授权
    Method for modified aminoplast compounds, aminoplasts obtained thereby and coatings containing the same 失效
    修饰氨基塑料化合物的方法，由此获得的氨基塑料和含有它们的涂层

    公开(公告)号：US5777048A

    公开(公告)日：1998-07-07

    申请号：US667261

    申请日：1996-06-20

    申请人： Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin

    发明人： Walter H. Ohrbom ,  Donald H. Campbell ,  Donald L. St. Aubin

    IPC分类号： C08G12/40 ,  C08G18/80 ,  C09D161/20 ,  C09D201/00 ,  C09D201/02 ,  C08F8/30

    CPC分类号： C09D201/025 ,  C08G12/40 ,  C08G18/8077 ,  C09D161/20 ,  C09D201/02

    摘要： A method for reducing the molecular weight of aminoplast compounds, the aminoplast compounds obtained thereby, and coating compositions containing said aminoplast compounds are provided. The reduced molecular weight aminoplasts are obtained by reacting (a) an aminoplast compound, having a total number (y) of reactive substituents on the amino nitrogens of the aminoplast, where y=(E.times.M) and E=equivalents per mole of aminoplast and M=total number of moles of aminoplast, wherein the reactive substituents are selected from the group consisting of --NH, alkylol, alkoxy, alkoxyalkyl, and mixtures thereof and(b) at least one carbamate compound selected from the group consisting of unsubstituted and substituted primary carbamate compounds, unsubstituted and substituted secondary carbamate compounds and mixtures thereof, in the presence of primary or secondary alcohols, at temperatures under 150.degree. C., and at pressures ranging between atmospheric pressure and 20 atm pressure, to form a functionalized aminoplast compound, wherein at least one and up to (y-1) of the amino substituents on the aminoplast are substituted with the carbamate functionality.

    摘要翻译： 提供了降低氨基塑料化合物的分子量，由此获得的氨基塑料化合物和含有所述氨基塑料化合物的涂料组合物的方法。 通过使（a）在氨基塑料的氨基氮上具有总数（y）的反应性取代基的氨基塑料化合物，其中y =（ExM）和E =每摩尔氨基塑料的当量和M =氨基塑料的总摩尔数，其中反应性取代基选自-NH，羟烷基，烷氧基，烷氧基烷基及其混合物，和（b）至少一种选自未取代和取代的伯 氨基甲酸酯化合物，未取代和取代的仲氨基甲酸酯化合物及其混合物，在初级醇或仲醇的存在下，在150℃的温度和在大气压和20atm压力之间的压力下形成官能化的氨基塑料化合物，其中 氨基塑料上氨基取代基的至少一个和至多（y-1）被氨基甲酸酯官能团取代。

    Carbamate functional addition polymers and a method for their preparation
    10.
    发明授权
    Carbamate functional addition polymers and a method for their preparation 失效
    氨基甲酸酯官能加成聚合物及其制备方法

    公开(公告)号：US07179861B2

    公开(公告)日：2007-02-20

    申请号：US10815327

    申请日：2004-04-01

    申请人： Donald H. Campbell ,  Donald L. St. Aubin ,  Walter H. Ohrbom

    发明人： Donald H. Campbell ,  Donald L. St. Aubin ,  Walter H. Ohrbom

    IPC分类号： C08F8/30

    CPC分类号： C09D201/025 ,  C08F222/20 ,  C08F222/22

    摘要： A carbamate or terminal urea functional vinyl polymer is prepared by reacting a compound having an hydroxyl group and a carbamate group, terminal urea group, or a group that can be converted to a carbamate or terminal urea group, with a cyclic carboxylic acid anhydride group to form an ester bond and a free acid group from the anhydride; and reacting the free acid group with a compound having an epoxide group. The cyclic carboxylic acid anhydride group may be pendant to a vinyl polymer, or one of the compound having an hydroxyl group, a compound having the cyclic carboxylic acid anhydride group, and the compound having an epoxide group may have polymerizable ethylenic unsaturation that is polymerized, optionally with one or more copolymerizable monomers to form a vinyl polymer. When the compound having an hydroxyl group has a group that can be converted to a carbamate or terminal urea group, the group is converted to the carbamate or terminal urea group after step (a). The carbamate or terminal urea functional vinyl polymer may be included in a coating composition. The coating composition may be applied to a substrate and cured to form a cured coating on the substrate.

    摘要翻译： 通过将具有羟基和氨基甲酸酯基的化合物，末端脲基团或可转化为氨基甲酸酯或末端脲基团的化合物与环状羧酸酐基团反应制备氨基甲酸酯或末端脲官能乙烯基聚合物， 从酸酐形成酯键和游离酸基团; 并使游离酸基与具有环氧基的化合物反应。 环状羧酸酐基可以侧链至乙烯基聚合物，或具有羟基的化合物，具有环状羧酸酐基的化合物和具有环氧基的化合物之间可具有可聚合的烯属不饱和基团， 任选地与一种或多种可共聚单体形成乙烯基聚合物。 当具有羟基的化合物具有可以转化为氨基甲酸酯或末端脲基团的基团时，在步骤（a）之后将该基团转化为氨基甲酸酯或末端脲基团。 氨基甲酸酯或末端脲官能的乙烯基聚合物可以包括在涂料组合物中。 涂料组合物可以施加到基底上并固化以在基底上形成固化的涂层。