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    Modified poly(aryl ether ketones) derived from biphenol
    3.
    发明授权
    Modified poly(aryl ether ketones) derived from biphenol 失效
    衍生自联苯酚的改性聚（芳醚酮）

    公开(公告)号：US4829143A

    公开(公告)日：1989-05-09

    申请号：US56092

    申请日：1987-05-29

    申请人： Robert A. Clendinning ,  Donald R. Kelsey

    发明人： Robert A. Clendinning ,  Donald R. Kelsey

    IPC分类号： C08G65/40

    CPC分类号： C08G65/4012

    摘要： Described herein are poly(aryl ether ketones) derived from biphenol which can be improved by incorporating bisphenol comonomers. The resulting polymers have lower melting points while the Tg is essentially unchanged resulting in good mechanical and crystallization properties.

    摘要翻译： 这里描述的是可以通过引入双酚共聚单体而改进的来自联苯酚的聚（芳基醚酮）。 所得聚合物具有较低的熔点，而Tg基本上不变，导致良好的机械和结晶性能。

    Modified poly(aryl ether ketones) derived from biphenol
    5.
    发明授权
    Modified poly(aryl ether ketones) derived from biphenol 失效
    衍生自联苯酚的改性聚（芳醚酮）

    公开(公告)号：US4766197A

    公开(公告)日：1988-08-23

    申请号：US924068

    申请日：1986-10-28

    申请人： Robert A. Clendinning ,  Donald R. Kelsey

    发明人： Robert A. Clendinning ,  Donald R. Kelsey

    IPC分类号： C08G65/34 ,  C08G65/40

    CPC分类号： C08G65/4012

    摘要： Described herein are poly(aryl ether ketones) derived from biphenol which can be improved by incorporating bisphenol comonomers. The resulting polymers have lower melting points while the Tg is essentially unchanged resulting in good mechanical and crystallization properties.

    摘要翻译： 这里描述的是可以通过引入双酚共聚单体而改进的来自联苯酚的聚（芳基醚酮）。 所得聚合物具有较低的熔点，而Tg基本上不变，导致良好的机械和结晶性能。

    Phenolic allyl ethers
    7.
    发明授权
    Phenolic allyl ethers 失效
    酚醛烯丙基醚

    公开(公告)号：US5578686A

    公开(公告)日：1996-11-26

    申请号：US505926

    申请日：1995-07-24

    申请人： Pen-Chung Wang ,  Donald R. Kelsey

    发明人： Pen-Chung Wang ,  Donald R. Kelsey

    IPC分类号： C08J3/24 ,  C07C41/16 ,  C07C43/20 ,  C07C43/215 ,  C08F290/00 ,  C08F299/00 ,  C08K5/13 ,  C08L79/08 ,  C08L65/00

    CPC分类号： C07C43/215 ,  C08L79/085

    摘要： A phenolic allyl ether is provided which can be prepared by reacting a polyphenol with an allyl halide, said polyphenol described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbomane linking moiety, L' is a divalent cycloaliphatic moiety, Allyl is a phenolic allyl ether group, and each of m and n is a number within the range of 0 to about 10. Such phenolic allyl ethers include the reaction product of allyl halide with the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyelohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting phenolic allyl ether resins are useful as processing agents for polymaleimides.

    摘要翻译： 提供了一种酚类烯丙基醚，其可以通过使多酚与烯丙基卤化物反应来制备，所述多酚通过其中Ar是芳族部分的式“IMAGE”描述，L是二价环己烷并联硼烷连接部分，L'是二价脂环族 部分，烯丙基是酚烯丙基醚基团，m和n各自为0至约10的数。这种酚类烯丙基醚包括烯丙基卤与苯酚加成反应产物的反应产物 环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯。 所得酚醛烯丙基醚树脂可用作聚马来酰亚胺的加工剂。

    Transition metal hydrides as co-catalysts for olefin polymerization
    9.
    发明授权
    Transition metal hydrides as co-catalysts for olefin polymerization 失效
    过渡金属氢化物作为烯烃聚合的助催化剂

    公开(公告)号：US5276119A

    公开(公告)日：1994-01-04

    申请号：US997802

    申请日：1992-12-29

    申请人： Donald R. Kelsey

    发明人： Donald R. Kelsey

    IPC分类号： C08F4/76 ,  C08G61/08

    CPC分类号： C08G61/08 ,  Y10S526/943

    摘要： An improved olefin metathesis catalyst system is disclosed. The catalyst system comprises a transition metal halide metathesis catalyst and an organo transition metal hydride co-catalyst of the formulaL.sub.x --M--Hwherein M is a group IVB transition metal including zirconium, titanium or hafnium; L is a ligand selected independently from the group of hydrogen, halide and organic ligands such as an optionally substituted C.sub.1-20 alkyl or alkenyl, an optionally substituted C.sub.3-20 cycloalkyl or cycloalkenyl having 3 to 6 carbon atoms in the ring, an optionally substituted C.sub.5-20 cycloakadienyl having 5 carbon atoms in the cycloalkadienyl ring, or an optionally substituted C.sub.6-20 aryl or fused aryl, where at least one L is a cycloalkadienyl; and x is one less than the valence of M. The optional substitutions on the organic ligands include halogens, preferably chloride or flouride; C.sub.1-6 alkyl; C.sub.1-6 alkoxy; and C.sub.1-6 haloalkyl. The preferred ligand is a C.sub.5-20 cycloalkadienyl having 5 carbon atoms in the cycloalkadienyl group, e.g. cyclopentadienyl. The co-catalysts of this invention are combined with molybdenum or tungsten metathesis catalysts to provide an active catalytic system for the polymerization of cycloolefins, such as dicyclopentadiene.

    摘要翻译： 公开了改进的烯烃复分解催化剂体系。 催化剂体系包括过渡金属卤化物复分解催化剂和式Lx-M-H的有机过渡金属氢化物助催化剂，其中M是含有锆，钛或铪的IVB族过渡金属; L是独立地选自氢，卤化物和有机配体如任选取代的C 1-20烷基或烯基，任选取代的C 3-20环烷基或环中具有3至6个碳原子的环烯基的配体，任选取代的 在环二烯基环中具有5个碳原子的C 5-20环烷二烯基，或任选取代的C 6-20芳基或稠合芳基，其中至少一个L是环二烯基; 且x小于M的化合价。有机配体上的任选取代包括卤素，优选氯化物或氟化物; C 1-6烷基; C 1-6烷氧基 和C 1-6卤代烷基。 优选的配体是在环烷二烯基中具有5个碳原子的C 5-20环烷二烯基， 环戊二烯基。 本发明的助催化剂与钼或钨复分解催化剂组合以提供用于环烯烃如二环戊二烯聚合的活性催化体系。