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1.发明授权4-(N-benzyl-N-methylamino)pyridine acid salts and use in preparation of polymer-supported catalysts 失效4-（N-苄基-N-甲基氨基）吡啶酸盐，并用于制备聚合物负载的催化剂
公开(公告)号：US5183895A
公开(公告)日：1993-02-02
申请号：US836257
申请日：1992-02-18
IPC分类号： C07D213/74
CPC分类号： C07D213/74
摘要： A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.
摘要翻译： 交联聚合物负载的4-（N-苄基-N-甲基氨基）吡啶材料及其高产率制备并具有有效物理和催化性能的方法。 聚合物负载催化剂的特征在于在含有纤维素的水相存在下，含有相应的乙烯基取代的吡啶单体，苯乙烯单体和合适的交联剂和产生自由基的催化剂的有机相的悬浮共聚 醚衍生物作为稳定剂。 乙烯基取代的吡啶单体的纯化酸盐可用于聚合并稳定存储为固体或水溶液。
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2.发明授权
公开(公告)号：US4968806A
公开(公告)日：1990-11-06
申请号：US352980
申请日：1989-05-17
IPC分类号： B01J31/06 , C07D213/74 , C08F12/00 , C08F12/26 , C08F26/06 , C08F212/14 , C08F226/06
CPC分类号： C07D213/74 , C08F12/26
摘要： A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.
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3.发明授权4-(N-benzyl-N-methylamino)pyridine acid salts and use in preparation of polymer-supported catalysts 失效4-（N-苄基-N-甲基氨基）吡啶酸盐，并用于制备聚合物负载的催化剂
公开(公告)号：US5147954A
公开(公告)日：1992-09-15
申请号：US609393
申请日：1990-11-05
IPC分类号： C07D213/74 , C08F12/26
CPC分类号： C07D213/74 , C08F12/26
摘要： A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.
摘要翻译： 交联聚合物负载的4-（N-苄基-N-甲基氨基）吡啶材料及其高产率制备并具有有效物理和催化性能的方法。 聚合物负载的催化剂的特征在于在含有相应的乙烯基取代的吡啶单体，苯乙烯单体和合适的交联剂和产生自由基的催化剂的有机相的悬浮共聚， 纤维素醚衍生物作为稳定剂。 乙烯基取代的吡啶单体的纯化酸盐可用于聚合并稳定存储为固体或水溶液。
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公开(公告)号：US4413099A
公开(公告)日：1983-11-01
申请号：US301040
申请日：1981-09-10
CPC分类号： C08F8/04
摘要： A new polymer composition comprised substantially of monomeric units having the formula ##STR1## or its acid salt, wherein R.sub.1 is an alkyl group having from 1 to about 20 carbon atoms or an arylalkyl group having from 7 to about 12 carbon atoms, and R.sub.2 is hydrogen or an alkyl group having from 1 to about 10 carbon atoms. A process for preparing the new polymer comprising the step of hydrogenating the quaternary salt of the pyridine precursor of the polymer under mild reaction conditions and in the presence of a hydrogenation catalyst selected from the Group VIII metals. A further step for preparing the free base polymer from the acid salt by reacting the same under mild conditions with a basic material such as sodium hydroxide.
摘要翻译： 一种新的聚合物组合物，其基本上由式（Ⅰ）或其酸式盐的单体单元组成，其中R1是具有1至约20个碳原子的烷基或具有7至约12个碳原子的芳基烷基，R2是 氢或具有1至约10个碳原子的烷基。 一种制备新聚合物的方法，包括在温和的反应条件下和在选自第Ⅷ族金属的氢化催化剂存在下氢化聚合物的吡啶前体的季盐的步骤。 通过使其在温和条件下与碱性物质如氢氧化钠反应，由酸性盐制备游离碱性聚合物的另一步骤。
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5.发明授权Polymer-supported 4-(N-benzyl-N-methylamino)pyridine catalyst and process for same 失效聚合物负载的4-（N-苄基-N-甲基氨基）吡啶催化剂及其方法
公开(公告)号：US5229479A
公开(公告)日：1993-07-20
申请号：US699694
申请日：1991-05-14
IPC分类号： C07D213/74 , C08F2/18
CPC分类号： C07D213/74
摘要： A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. The catalyst is further characterized by its yield in excess of 90% by weight and by its predominant and generally spherical and smooth bead form and substantially uniform size that is efficiently hard and durable and possesses sufficient catalytic activity for effective use in acylation, alkylation or other related reactions.
摘要翻译： 交联聚合物负载的4-（N-苄基-N-甲基氨基）吡啶材料及其高产率制备并具有有效物理和催化性能的方法。 聚合物负载的催化剂的特征在于在含有相应的乙烯基取代的吡啶单体，苯乙烯单体和合适的交联剂和产生自由基的催化剂的有机相的悬浮共聚， 纤维素醚衍生物作为稳定剂。 催化剂的特征还在于其产率超过90重量％，其主要和通常为球形和平滑的珠粒形式和基本上均匀的尺寸，其有效硬度和耐久性并且具有足够的催化活性，有效用于酰化，烷基化或其它 相关反应。
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公开(公告)号：US5180822A
公开(公告)日：1993-01-19
申请号：US750467
申请日：1991-08-27
IPC分类号： C07D213/38 , C07D213/74 , C07D401/04 , C08F12/26 , C08F12/32
CPC分类号： C07D401/04 , C07D213/38 , C07D213/74 , C08F12/26 , C08F12/32 , C22B3/42 , Y02P10/234
摘要： Described are preferred monomers including a vinylbenzyl moiety N-bonded to an alkylaminopyridinyl or pyridylimidazolyl function. Also described are preferred acid salts of such monomers. Additionally, preferred processes involving and resins formed from these preferred monomers are described. The preferred resins are highly selective for valuable heavy metal ions such as copper and demonstrate superior iron rejection values.
摘要翻译： 描述的是优选的单体，包括与烷基氨基吡啶基或吡啶基咪唑基官能团N-键合的乙烯基苄基部分。 还描述了这些单体的优选酸盐。 此外，描述了涉及由这些优选单体形成的优选方法和由这些优选的单体形成的树脂。 优选的树脂对于有价值的重金属离子如铜是高度选择性的并且表现出优异的铁排斥值。
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7.发明授权Polymer-supported 4-(N-benzyl-N-methylamino)pyridine catalyst and process for same 失效聚合物负载的4-（N-苄基-N-甲基氨基）吡啶催化剂及其方法
公开(公告)号：US5015706A
公开(公告)日：1991-05-14
申请号：US247152
申请日：1988-09-21
IPC分类号： B01J31/06 , C07D213/74 , C08F2/08 , C08F12/00 , C08F26/06 , C08F212/14 , C08F226/06
CPC分类号： C07D213/74
摘要： A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterizd by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. The catalyst is further characterized by its yield in excess of 90% by weight and by its predominant and generally spherical and smooth bead form and substantially uniform size that is efficiently hard and durable and possesses sufficient catalytic activity for effective use in acylation, alkylation or other related reactions.
摘要翻译： 交联聚合物负载的4-（N-苄基-N-甲基氨基）吡啶材料及其高产率制备并具有有效物理和催化性能的方法。 聚合物负载的催化剂的特征是在含有相应的乙烯基取代的吡啶单体，苯乙烯单体和合适的交联剂和产生自由基的催化剂的有机相在含有 纤维素醚衍生物作为稳定剂。 催化剂的特征还在于其产率超过90重量％，其主要和通常为球形和平滑的珠粒形式和基本上均匀的尺寸，其有效硬度和耐久性并且具有足够的催化活性，有效用于酰化，烷基化或其它 相关反应。
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公开(公告)号：US5444137A
公开(公告)日：1995-08-22
申请号：US5291
申请日：1993-01-19
IPC分类号： C07D213/38 , C07D213/74 , C07D401/04 , C08F12/26 , C08F12/32 , C08F26/06 , C08F212/06 , C08F212/08
CPC分类号： C07D401/04 , C07D213/38 , C07D213/74 , C08F12/26 , C08F12/32 , C22B3/42 , Y02P10/234
摘要： Described are preferred monomers including a vinylbenzyl moiety N-bonded to an alkylaminopyridinyl or pyridylimidazolyl function. Also described are preferred acid salts of such monomers. Additionally, preferred processes involving and resins formed from these preferred monomers are described. The preferred resins are highly selective for valuable heavy metal ions such as copper and demonstrate superior iron rejection values.
摘要翻译： 描述的是优选的单体，包括与烷基氨基吡啶基或吡啶基咪唑基官能团N-键合的乙烯基苄基部分。 还描述了这些单体的优选酸盐。 此外，描述了涉及由这些优选单体形成的优选方法和由这些优选的单体形成的树脂。 优选的树脂对于有价值的重金属离子如铜是高度选择性的并且表现出优异的铁排斥值。
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公开(公告)号：US4420542A
公开(公告)日：1983-12-13
申请号：US436573
申请日：1982-10-25
申请人： Edward E. Sowers
发明人： Edward E. Sowers
CPC分类号： B27K3/156 , B27K3/22 , C08L97/02 , C08L39/08 , Y10S428/907 , Y10T428/662
摘要： An article and method for treating wood to promote preservation and inhibit fungi and bacteria attack, comprising the wood treated with a polymer with pendant groups containing pyridine rings complexed with copper. Treatment can include impregnating the wood through pressure, vacuum, soaking or other means or more superficial applications to the wood surface through brushing, painting, dipping or the like. Preferred are one-step and two-step procedures with poly-4-vinylpyridine as the polymer of choice and copper chloride or copper sulfate as the preferred copper ion source. Treatment can be with the monomer or homopolymer form, followed by polymerization and/or cross-linking in situ in the wood after application.
摘要翻译： 一种用于处理木材以促进保存和抑制真菌和细菌攻击的物品和方法，包括用含有与铜络合的吡啶环的侧基的聚合物处理的木材。 处理可以包括通过压力，真空，浸泡或其他方式或更多的表面应用将木材浸透到木材表面，通过刷涂，涂漆或浸渍等。 优选的是使用聚-4-乙烯基吡啶作为选择的聚合物和氯化铜或硫酸铜作为优选的铜离子源的一步和两步程序。 处理可以是单体或均聚物形式，然后在施用后在木材中原位聚合和/或交联。
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10.发明申请POLYMERS CONTAINING HEAT LABILE COMPONENTS ADSORBED ON POLYMERIC CARRIERS AND METHODS FOR THEIR PREPARATION 审中-公开含有聚合载体上的热可溶成分的聚合物及其制备方法公开(公告)号：US20130172436A1
公开(公告)日：2013-07-04
申请号：US13550165
申请日：2012-07-16
IPC分类号： C08K5/544
摘要： Compositions containing polymers and one or more heat labile and/or incompatible components adsorbed on carrier materials are provided. The heat labile components include materials that are inactivated, that volatilize, decompose, or undergo a chemical reaction or transformation at the polymer's processing temperatures (heat labile biocides). Incompatible components are materials that generally react or form gels or precipitates upon mixing. The carrier materials generally include inorganic or organic porous materials capable of remaining solid during processing temperatures. Methods for preparing the polymer compositions are provided.
摘要翻译： 提供了含有聚合物和吸附在载体材料上的一种或多种热不稳定和/或不相容成分的组合物。 热不稳定组分包括在聚合物的加工温度（热不稳定的杀生物剂）下失活，挥发，分解或经历化学反应或转化的物质。 不相容的组分是在混合时通常反应或形成凝胶或沉淀物的材料。 载体材料通常包括能够在加工温度下保持固体的无机或有机多孔材料。 提供了制备聚合物组合物的方法。
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