摘要:
A polyester/polycarbonate blend having superior thermal stability and superior color stability is disclosed. The polyester/polycarbonate blend comprises: (a) P(ET-CT) (poly(ethylene terephthalate-co-1,4-cyclohexylene dimethylene terephthalate) which is copolymerized with 1,4-cyclohexanedimethanol (CHDM) of 40 to 90 mol % with respect to total diol components; (b) polyethylene terephthalate (PET); (c) polycarbonate (PC); and (d) germanium of 1 to 100 ppm (weight ratio) with respect to total polyester/polycarbonate blend, wherein with respect to total polyester/polycarbonate blend, the amount of the P(ET-CT) and PET is 50 to 90 weight %, the amount of the PET is 1 to 6 times in weight ratio with respect to the P(ET-CT), and the amount of the PC is 10 to 50 weight %.
摘要:
A method for preparing polyester copolymer containing amide link, which can reduce the phase separation of a polyester component and an amide component by improving the compatibility therebetween is disclosed. The method for preparing polyester copolymer comprises the step of polymerizing macrocyclic polyester oligomer and cyclic amide monomer. Wherein, it is preferable that the macrocyclic polyester oligomer is obtained by reacting bis(hydroxyalkyl)ester with dicarboxylic acid chloride in the presence of unhindered amine, and the bis(hydroxyalkyl)ester is obtained by. depolymerizing polyester. resin. Also, lit is preferable that the cyclic amide monomer is E-caprolactam having a cyclic structure and having 2 or more carbon atoms, and the amount of the macrocyclic polyester oligomer is 5 to 99% by weight with respect to total amount of the macrocyclic polyester oligomer and the cyclic amide monomer.