Method for preparing polyester copolymer containing amide link
    1.
    发明申请
    Method for preparing polyester copolymer containing amide link 审中-公开
    制备含有酰胺键的聚酯共聚物的方法

    公开(公告)号:US20070167604A1

    公开(公告)日:2007-07-19

    申请号:US10585240

    申请日:2004-12-31

    IPC分类号: C08G63/02

    摘要: A method for preparing polyester copolymer containing amide link, which can reduce the phase separation of a polyester component and an amide component by improving the compatibility therebetween is disclosed. The method for preparing polyester copolymer comprises the step of polymerizing macrocyclic polyester oligomer and cyclic amide monomer. Wherein, it is preferable that the macrocyclic polyester oligomer is obtained by reacting bis(hydroxyalkyl)ester with dicarboxylic acid chloride in the presence of unhindered amine, and the bis(hydroxyalkyl)ester is obtained by. depolymerizing polyester. resin. Also, lit is preferable that the cyclic amide monomer is E-caprolactam having a cyclic structure and having 2 or more carbon atoms, and the amount of the macrocyclic polyester oligomer is 5 to 99% by weight with respect to total amount of the macrocyclic polyester oligomer and the cyclic amide monomer.

    摘要翻译: 公开了一种制备含有酰胺键的聚酯共聚物的方法,其可通过改善聚酯组分和酰胺组分之间的相容性来降低聚酯组分和酰胺组分的相分离。 制备聚酯共聚物的方法包括聚合大环聚酯低聚物和环酰胺单体的步骤。 其中,优选大环聚酯低聚物是通过使双(羟基烷基)酯与二羧酰氯在不受阻碍的胺存在下反应而获得的,双(羟烷基)酯是通过获得的。 解聚聚酯。 树脂。 此外,点亮的是优选环酰胺单体是具有环状结构且具有2个或更多个碳原子的ε-己内酰胺,并且大环聚酯低聚物的量相对于大环聚酯的总量为5〜99重量% 低聚物和环酰胺单体。

    POLYESTER/POLYCARBONATE BLEND HAVING EXCELLENT THERMAL STABILITY AND COLOR STABILITY
    2.
    发明申请
    POLYESTER/POLYCARBONATE BLEND HAVING EXCELLENT THERMAL STABILITY AND COLOR STABILITY 审中-公开
    具有极好的热稳定性和颜色稳定性的聚酯/聚碳酸酯混合物

    公开(公告)号:US20130217835A1

    公开(公告)日:2013-08-22

    申请号:US13881583

    申请日:2011-10-28

    IPC分类号: C08L67/03

    摘要: A polyester/polycarbonate blend having superior thermal stability and superior color stability is disclosed. The polyester/polycarbonate blend comprises: (a) P(ET-CT) (poly(ethylene terephthalate-co-1,4-cyclohexylene dimethylene terephthalate) which is copolymerized with 1,4-cyclohexanedimethanol (CHDM) of 40 to 90 mol % with respect to total diol components; (b) polyethylene terephthalate (PET); (c) polycarbonate (PC); and (d) germanium of 1 to 100 ppm (weight ratio) with respect to total polyester/polycarbonate blend, wherein with respect to total polyester/polycarbonate blend, the amount of the P(ET-CT) and PET is 50 to 90 weight %, the amount of the PET is 1 to 6 times in weight ratio with respect to the P(ET-CT), and the amount of the PC is 10 to 50 weight %.

    摘要翻译: 公开了具有优异的热稳定性和优异的颜色稳定性的聚酯/聚碳酸酯共混物。 聚酯/聚碳酸酯共混物包括:(a)P(ET-CT)(聚对苯二甲酸乙二醇酯 - 共1,4-亚环己基二亚甲基对苯二甲酸酯),其与1,4-环己烷二甲醇(CHDM)共聚40-40% 相对于总二醇组分;(b)聚对苯二甲酸乙二醇酯(PET);(c)聚碳酸酯(PC);和(d)相对于总聚酯/聚碳酸酯共混物为1〜100ppm(重量比)的锗, 对于总聚酯/聚碳酸酯共混物,P(ET-CT)和PET的量为50至90重量%,PET的量相对于P(ET-CT)为1至6倍重量比, PC的量为10〜50重量%。