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    Thermoplastic elastomers
    1.
    发明授权
    Thermoplastic elastomers 失效
    热塑性弹性体

    公开(公告)号：US5278245A

    公开(公告)日：1994-01-11

    申请号：US957494

    申请日：1992-10-07

    申请人： Donn A. DuBois ,  Carl L. Willis

    发明人： Donn A. DuBois ,  Carl L. Willis

    IPC分类号： C08F297/02 ,  C08F297/04

    CPC分类号： C08F297/048

    摘要： Block copolymers of particular structure comprising blocks of polymerized alkenyl aromatic compound and polymerized conjugated alkadiene, as well as selectively hydrogenated derivatives thereof, are functionalized by the presence of additional polar blocks of polymerized alkyl methacrylate.

    摘要翻译： 包含聚合的链烯基芳族化合物和聚合的共轭二烯嵌段的特定结构的嵌段共聚物以及其选择性氢化的衍生物通过存在其它聚合的甲基丙烯酸烷基酯的极性嵌段官能化。

    Thermoplastic elastomers
    2.
    发明授权
    Thermoplastic elastomers 失效
    热塑弹性体

    公开(公告)号：US5194510A

    公开(公告)日：1993-03-16

    申请号：US525812

    申请日：1990-05-21

    申请人： Donn A. DuBois ,  Carl L. Willis

    发明人： Donn A. DuBois ,  Carl L. Willis

    IPC分类号： C08F297/02 ,  C08F297/04

    CPC分类号： C08F297/048

    摘要： Block copolymers useful in formulations of adhesives, coatings, and lubricating oils have a particular structure comprising blocks of a polymerized alkenyl aromatic compound such as styrene, an internal block of a polymerized conjugated alkadiene such as butadiene, as well as selectively hydrogenated derivatives thereof, and a polar block of a polymerized alkyl methacrylate such as t-butyl methacrylate.

    Polymers of alkoxystyrenes and a process to produce polymers of alkoxystyrenes
    4.
    发明授权
    Polymers of alkoxystyrenes and a process to produce polymers of alkoxystyrenes 失效
    烷氧基聚合物的聚合物和生产聚合物的方法

    公开(公告)号：US5073610A

    公开(公告)日：1991-12-17

    申请号：US589364

    申请日：1990-09-28

    申请人： Donn A. DuBois

    发明人： Donn A. DuBois

    IPC分类号： C08F12/22

    CPC分类号： C08F12/22

    摘要： A process to polymerize alkoxystyrenes utilizing a zeolite as the initiator is provided. Polymers of p-methoxystyrene having number average molecular weights in excess of 1.times.10.sup.6 are prepared by room temperature polymerization. The invention also provides a high molecular weight polymer of alkoxystyrenes which has a broad molecular weight distribution.

    摘要翻译： 提供了使用沸石作为引发剂使烷氧基苯乙烯聚合的方法。 通过室温聚合制备数均分子量超过1×10 6的对甲氧基苯乙烯的聚合物。 本发明还提供具有宽分子量分布的高分子量聚合物的烷氧基苯乙烯。

    Anionically polymerized block copolymers of ethylene and cyclic siloxane monomers
    5.
    发明授权
    Anionically polymerized block copolymers of ethylene and cyclic siloxane monomers 失效
    乙烯和环状硅氧烷单体的阴离子聚合嵌段共聚物

    公开(公告)号：US5618903A

    公开(公告)日：1997-04-08

    申请号：US634078

    申请日：1996-04-17

    申请人： Ronald J. Hoxmeier ,  Donn A. DuBois ,  Jeffrey G. Southwick

    发明人： Ronald J. Hoxmeier ,  Donn A. DuBois ,  Jeffrey G. Southwick

    IPC分类号： C08G77/442

    CPC分类号： C08G77/442

    摘要： This invention relates to anionically polymerized block copolymers comprised of at least one block polyethylene and at least one block of a polymerized cyclic siloxane monomer, e.g., polydimethylsiloxane. Block copolymers with multiple "arms" may be formed by coupling these living diblocks with polyfunctional coupling agents. One copolymer for use in wax release coatings has an overall weight average molecular weight of 1500 to 100,000, a polyethylene block weight average molecular weight of less than 4100, and a polyethylene content of less than 55 percent by weight. Another copolymer for use in extruded release coating films prepared by blending the copolymer with a film grade polymer has an overall molecular weight of less than 20,000 and a polyethylene block molecular weight of less than 3700.

    摘要翻译： 本发明涉及由至少一个嵌段聚乙烯和至少一个聚合的环状硅氧烷单体例如聚二甲基硅氧烷组成的阴离子聚合嵌段共聚物。 可以通过将这些活性二嵌段与多官能偶联剂偶联来形成具有多个“臂”的嵌段共聚物。 用于蜡剥离涂料的一种共聚物的总重均分子量为1500-100,000，聚乙烯嵌段重均分子量小于4100，聚乙烯含量小于55重量％。 通过将共聚物与膜级聚合物共混制备的用于挤出脱模涂膜的另一种共聚物的总分子量小于20,000，聚乙烯嵌段分子量小于3700。

    Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones
    6.
    发明授权
    Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones 失效
    通过从官能化聚烯烃骨架生长阴离子聚合物链来制备接枝嵌段共聚物的方法

    公开(公告)号：US5543458A

    公开(公告)日：1996-08-06

    申请号：US381242

    申请日：1995-01-31

    申请人： Ronald J. Hoxmeier ,  Robert C. Job ,  Bridget A. Spence ,  Donn A. DuBois

    发明人： Ronald J. Hoxmeier ,  Robert C. Job ,  Bridget A. Spence ,  Donn A. DuBois

    IPC分类号： C08F8/42 ,  C08F255/00 ,  C08F275/00

    CPC分类号： C08F275/00 ,  C08F255/00 ,  C08F8/42

    摘要： A graft block copolymer is comprised of a completely saturated olefinic backbone with pendant anionic polymer side chains. The polymer is produced by copolymerizing an .alpha.-olefin with a monomer which contains a functional group which can be metallated so an anionic monomer can be polymerized therefrom, metallating the copolymer by reaction with metal alkyl or aryl compound and a metallation activator, and growing anionic polymer side chains from the copolymer backbone by reacting an anionically polymerized monomer with the metallated copolymer.

    摘要翻译： 接枝嵌段共聚物由具有侧阴离子聚合物侧链的完全饱和的烯属主链组成。 该聚合物是通过使α-烯烃与含有可被金属化的官能团的单体共聚制备的，因此阴离子单体可从其中聚合，通过与金属烷基或芳基化合物和金属化活化剂的反应使共聚物金属化，并且阴离子生长 聚合物侧链通过使阴离子聚合的单体与金属化共聚物反应而由共聚物主链形成。

    Grafted polymers having reactive groups at the base
    9.
    发明授权
    Grafted polymers having reactive groups at the base 失效
    在基体上具有反应性基团的接枝聚合物

    公开(公告)号：US5397841A

    公开(公告)日：1995-03-14

    申请号：US163809

    申请日：1993-12-08

    申请人： Donn A. DuBois ,  Robert J. Sutherland

    发明人： Donn A. DuBois ,  Robert J. Sutherland

    IPC分类号： C08G81/02 ,  C08L33/06 ,  C08L33/00

    CPC分类号： C08G81/021

    摘要： The present invention provides grafted polymers that have pendent functional groups on the core of the polymer wherein the core is a polymerized alkylmethacrylate having a number average molecular weight from 500 to 1,000,000. The arms of the grafted polymer comprise anionically polymerized segments that have number average molecular weights from 1,000 to 300,000.

    摘要翻译： 本发明提供了在聚合物芯上具有侧基官能团的接枝聚合物，其中核是聚合的数均分子量为500至1,000,000的甲基丙烯酸烷基酯。 接枝聚合物的臂包含数均分子量为1,000至300,000的阴离子聚合的链段。

    Butadiene polymers having terminal silyl groups
    10.
    发明授权
    Butadiene polymers having terminal silyl groups 失效
    具有末端甲硅烷基的丁二烯聚合物

    公开(公告)号：US5336726A

    公开(公告)日：1994-08-09

    申请号：US29866

    申请日：1993-03-11

    申请人： Donn A. DuBois

    发明人： Donn A. DuBois

    IPC分类号： C07F7/18 ,  C08C19/44 ,  C08F4/42 ,  C08F4/58 ,  C08F8/04 ,  C08F8/42 ,  C08F36/06 ,  C08F136/00 ,  C08F136/06 ,  C08G81/02 ,  C08F297/04

    CPC分类号： C08G81/021 ,  C08C19/44 ,  C08F36/06

    摘要： Hydrogenated butadiene polymers having terminal silyl groups are prepared from a (4-vinylphenylene)dimethyl(t-butyl)silyl ether which is added to the polymer chain as a silyl ether initiator or an endcapping agent, or both. The silyl groups are then converted to phenolic groups. The polymers are useful in making coatings, sealants, binders, and block copolymers with polyesters, polyamides, and polycarbonates.

    摘要翻译： 具有末端甲硅烷基的氢化丁二烯聚合物由作为甲硅烷基醚引发剂或封端剂加入到聚合物链中的（4-乙烯基亚苯基）二甲基（叔丁基）甲硅烷基醚或二者制备。 然后将甲硅烷基转化为酚基。 聚合物可用于制备涂料，密封剂，粘合剂和与聚酯，聚酰胺和聚碳酸酯的嵌段共聚物。