摘要:
Disclosed is a process for producing a zinc pyrithione product having an acceptable white or off-white color and containing substantially no undesired 2-hydroxypyridine-N-oxide or metal salt complexes thereof, by(1) making sodium pyrithione by reacting a 2-halopyridine-N-oxide with sodium hydrosulfide and sodium carbonate (or a mixture of sodium carbonate and sodium hydroxide) under selected addition temperatures and reaction temperatures and in selected mole ratios; followed by(2) making zinc pyrithione by reacting the sodium pyrithione with a zinc salt.
摘要:
Powder coating formulations include as a component thereof a silane formula I: where R1 is a hydrocarbon, acyl, alkylsilyl or alkoxysilyl group; R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent organic linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with silanes of formula I.
摘要:
A process for producing aldehydes and, more specifically, a process employing a vapor phase reaction in the presence of a molten nitrate salt catalyst.
摘要:
Powder coating formulations which include as a component thereof a silyl carbamate of the formula: where R1 is a hydrocarbon or acyl group; R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; X is an m-valent organic group; m is 1-6; and, either A=NH and B=O, or A=O and B=NH. The silanes are useful as crosslinkers and/or adhesion promoters.
摘要:
A high energy explosive or propellant composition having low vulnerability to unplanned stimuli and containing a polyurethane polyacetal elastomer binder. Also claimed is a process for producing this composition.
摘要:
Disclosed are selected O-(2-trichloromethyl-4-pyrimidinyl)-O,O-dialkyl phosphorothionates and O-(2-trichloromethyl-4-pyrimidinyl)-O,O-dialkyl phosphoronates having the formula: ##STR1## wherein Y is an atom selected from the group consisting of sulfur and oxygen; R is a lower alkyl group having 1 to 4 carbon atoms; R.sup.1 is hydrogen, a lower alkyl group having 1 to 4 carbon atoms, halo or nitro; and R.sup.2 is a lower alkyl group having 1 to 4 carbon atoms or an amino group. These compounds have been found to exhibit insecticidal activity.
摘要:
Disclosed are selected 2-trichloromethyl-4-pyrimidinyl carboxylic esters having the formula: ##STR1## wherein R is a lower alkyl group having 1 to 4 carbon atoms, a lower alkenyl group having 1 to 4 carbon atoms a lower halo alkyl group having 1 to 4 carbon atoms or an unsubstituted or substituted phenyl group; R.sup.1 is hydrogen or halo; and R.sup.2 is a lower alkyl group having 1 to 4 carbon atoms. These compounds are disclosed to be agricultural fungicides.
摘要:
Disclosed are selected 2-acyl- or 2-thioacyl-1-trichloroacetimidoylhydrazines having the formula: ##STR1## wherein X is an atom selected from the group consisting of oxygen and sulfur; and R is a hydrogen, lower alkyl or lower alkoxy group having 1 to 4 carbon atoms, or an unsubstituted or substituted phenyl group. These compounds are disclosed to be agricultural fungicides.
摘要:
The present invention relates to a composition being an aqueous dispersion of a polyurethane in water, said composition comprising water and the reaction product of (a) a water-dispersible isocyanate-terminated polyurethane prepolymer having an isocyanate content of between 1 and 15% by weight. The prepolymer comprises the following: an organic polyisocyanate adduct mixture having an average isocyanate functionality of between 2.0 and 4.0, and (b) an isocyanate reactive chain extender having a specified ratio of isocyanate reactive moiety to isocyanate index of the polyisocyanate adduct mixture. The polyisocyanate mixture must contain some dimer; however, other polyisocyanates, such as diisocyanates and polyisocyanate trimers, are advantageously added to the mixture. Also disclosed is a process for preparing this composition, and a method for coating a substrate with the composition.
摘要:
This invention relates to a catalyst composition comprising the reaction product of (a) an inorganic substrate containing a reactive hydroxyl group and selected from the group consisting of silica compounds, alumina compounds, and combinations thereof, (b) a catalyst containing terminal unsaturation and selected from the group consisting of 4-dialkylamino pyridines, 4-(N-arylalkyl-N-alkyl)amino pyridines, and combinations thereof, and (c) a hydrosilane. Also disclosed is a process for making the catalyst composition, as well as the catalyst composition by empirical structural formula.