摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce ethylene, hydrogen chloride (HCl) and vinyl chloride monomer (VCM).
摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce vinylidene (1,1-dichloroethylene), hydrogen chloride and ethylene.
摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce ethylene, hydrogen chloride (HCl) and vinyl chloride monomer (VCM).
摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce vinylidene (1,1-dichloroethylene), hydrogen chloride and ethylene.
摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce ethylene, hydrogen chloride (HCl) and vinyl chloride monomer (VCM).
摘要:
The present invention provides a weir quench, an apparatus comprising a reactor and the weir quench and processes incorporating the same. The weir quench incorporates an inlet having an inner diameter (Di) and an upper chamber having an inner diameter (Duc), wherein the inlet inner diameter (Di) is at least 90% of the upper chamber inner diameter (Duc). The apparatus comprises a reactor having an outlet with an inner diameter fluidly coupled with the weir quench inlet, wherein the ratio of the reactor outlet inner diameter (Dr) to the weir quench inlet diameter (Di) is greater than one. The weir quench, and apparatus comprising a reactor and the weir no quench, are advantageously utilized in processes utilizing a limiting reagent.
摘要:
A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce ethylene, hydrogen chloride (HCl) and vinyl chloride monomer (VCM).
摘要:
A feedstream comprising hydrogen and a gas selected from carbon monoxide, carbon dioxide, or a combination thereof is converted to a product mixture containing a combination of saturated and unsaturated two carbon atom and three carbon atom hydrocarbons via contact with a mixed catalyst comprising a mixed metal oxide catalyst selected from a copper oxide, copper oxide/zinc oxide, copper oxide/alumina, copper oxide/zinc oxide/alumina catalyst, a zinc oxide/chromium oxide catalyst, or a combination thereof, in admixture with a molecular sieve catalyst having a CHA, AEI, AEL, AFI, BEA, or DDR framework type, or a combination of such molecular sieves. Exemplary molecular sieve catalysts include SAPO-34, SAPO-18, SAPO-5, and Beta. Advantages include reduced production of C1 hydrocarbons, C4 and higher hydrocarbons, or both; long catalyst lifetimes; desirable conversions; and desirable proportions of C2 and C3 paraffins.
摘要:
Processes for the production of chlorinated propenes are provided. The present processes make use of 1,2-dichloropropane, a by-product in the production of chlorohydrin, as a low cost starting material, alone or in combination with 1,2,3-trichloropropane. At least one dehydrochlorination is conducted in the gas phase, and is the first process step. The present processes can also generate anhydrous HCl as a byproduct that can be removed from the process and used as a feedstock for other processes, providing further time and cost savings.
摘要:
Processes for the production of chlorinated propenes are provided wherein a dehydrochlorination reaction occurs prior to a first chlorination reaction. The present processes make use of at least one reactor twice, i.e., at least two reactions occur in the same reactor. Cost and time savings are thus provided. Additional savings can be achieved by conducting more than two chlorination reactions, or all chlorination reactions, in one chlorination reactor, and/or by conducting more than two dehydrochlorination reactions, or all dehydrochlorination reactions, within a single dehydrochlorination reactor.