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公开(公告)号：US11548835B2
公开(公告)日：2023-01-10
申请号：US16757694
申请日：2018-10-11
Applicant: Dow Global Technologies LLC
Inventor： Alexey Kirilin , Adam Chojecki , Kyle C. Andrews , Vera P. Santos Castro , Aysegul Ciftci Sandikci , Davy L. S. Nieskens , Peter E. Groenendijk , Andrzej Malek
Abstract: A process for preparing C2 to C5 olefins includes introducing a feed stream comprising hydrogen and at least one carbon-containing component selected from the group consisting of CO, CO2, and mixtures thereof into a reaction zone. The feed stream is contacted with a hybrid catalyst in the reaction zone, and a product stream is formed that exits the reaction zone and includes C2 to C5 olefins. The hybrid catalyst includes a methanol synthesis component and a solid microporous acid component that is selected from molecular sieves having 8-MR access and having a framework type selected from the group consisting of CHA, AEI, AFX, ERI, LTA, UFI, RTH, and combinations thereof. The methanol synthesis component comprises a metal oxide support and a metal catalyst. The metal oxide support includes titania, zirconia, hafnia or mixtures thereof, and the metal catalyst includes zinc.
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2.发明申请公开(公告)号：US20220088574A1
公开(公告)日：2022-03-24
申请号：US17417955
申请日：2019-12-16
Applicant: Dow Global Technologies LLC
Inventor： Alexey Kirilin , Adam Chojecki , Glenn Pollefeyt , Davy L.S. Nieskens , Kyle C. Andrews , Vera P. Santos Castro , Joseph F. DeWilde , David F. Yancey , Andrzej Malek
Abstract: A method for preparing C2 to C5 paraffins includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. Converting the feed stream into a product stream including C2 to C5 paraffins in the presence of a hybrid catalyst. The hybrid catalyst includes a microporous catalyst component; and a metal oxide catalyst component selected from (A) a bulk material consisting of gallium oxide, (B) gallium oxide present on a titanium dioxide support material, and (C) a mixture of gallium oxide and at least one promoter present on a support material selected from Group 4 of the IUPAC periodic table of elements.
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3.发明申请公开(公告)号：US20220080392A1
公开(公告)日：2022-03-17
申请号：US17417846
申请日：2019-12-16
Applicant: Dow Global Technologies LLC
Inventor： Adam Chojecki , Alexey Kirilin , Andrzej Malek , Joseph F. DeWilde , Vera P. Santos Castro , David F. Yancey , Kyle C. Andrews
Abstract: A process for preparing C2 to C4 olefins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. The feed stream is converted into a product stream including C2 to C4 olefins in the reaction zone in the presence of the hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component comprising gallium oxide and phase pure zirconia, and a microporous catalyst component.
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公开(公告)号：US20150191638A1
公开(公告)日：2015-07-09
申请号：US14417414
申请日：2013-08-21
Applicant: Dow Global Technologies LLC
Inventor： David G. Barton , Adam Chojecki , Paul R. Elowe , Beata A. Kilos
CPC classification number: C09K5/00 , B01J23/10 , B01J37/0201 , B01J37/031 , B01J37/08 , C07C41/09 , C07C43/275
Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst comprises a mixture of two or more of (a) an oxide of a light rare earth element, (b) an oxide of a medium rare earth element, (c) an oxide of a heavy rare earth element, or (d) an oxide of yttrium.
Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂包含（a）轻稀土元素的氧化物，（b）中等稀土元素的氧化物，（c）重稀土元素的氧化物或（d ）钇氧化物。
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公开(公告)号：US09051252B2
公开(公告)日：2015-06-09
申请号：US14385910
申请日：2013-05-29
Applicant: Dow Global Technologies LLC
Inventor： David G. Barton , Adam Chojecki , Paul R. Elowe , Beata A. Kilos , Eric E. Stangland
CPC classification number: C07C41/09 , B01J21/066 , B01J27/10 , B01J35/002 , B01J35/1009 , B01J35/1038 , B01J37/0201 , B01J37/031 , C09K5/10 , C07C43/275
Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst is an oxide of a light rare earth element, wherein the light earth element is lanthanum, praseodymium, neodymium, or mixtures thereof.
Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂是轻稀土元素的氧化物，其中轻质土元素是镧，镨，钕或其混合物。
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Patent Agency Ranking
公开(公告)号：US20240352341A1
公开(公告)日：2024-10-24
申请号：US18683043
申请日：2022-08-17
Applicant: Dow Global Technologies LLC
Inventor： Daniela Ferrari , Barry B. Fish , Kevin Blann , Glenn Pollefeyt , Cheng L. Chung , Manish Sharma , Alexey Kirilin , Adam Chojecki , Andrzej Malek
IPC: C10G27/04
CPC classification number: C10G27/04 , C10G2300/1081 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018
Abstract: A method for converting alkanes to olefins includes contacting a feed stream comprising alkanes with an oxidative dehydrogenation that does not comprise tellurium catalyst in a reaction zone and dehydrogenating the alkanes without a co-feed of oxygen to yield a product stream having olefins. The oxidative dehydrogenation catalyst has the formula: MovVwNbyAzOx, where v is 1.0, w is from 0.1 to 0.5, y is from 0.001 to 0.3, A is Bi, Sb, Pr, or mixtures thereof, z is from 0.01 to 0.3, and x charge-balances the structure. The oxidative dehydrogenation catalyst has a crystallographic structure with Pba2-32 space group, characterized by reflections determined with Cu-Kα X-ray diffraction (XRD) as follows.
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公开(公告)号：US20230256424A1
公开(公告)日：2023-08-17
申请号：US18003843
申请日：2021-06-18
Applicant: Dow Global Technologies LLC
Inventor： Alexey Kirilin , Dean M. Millar , Adam Chojecki , Joseph F. DeWilde , Glenn Pollefeyt , Davy L.S. Nieskens , Andrzej Malek
CPC classification number: B01J29/505 , B01J29/7015 , B01J35/0006 , C07C1/043 , C10G2/33 , C10G2/50 , C07C2521/06 , C07C2523/08 , C10G2300/70 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/20
Abstract: A process for preparing C2 to C3 hydrocarbons may include introducing a feed stream including hydrogen gas and a carbon-containing gas comprising carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C3 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst may include a metal oxide catalyst component and a microporous catalyst component comprising 8-MR pore openings and may be derived from a natural mineral, the product stream comprises a combined C2 and C3 selectivity greater than 40 carbon mol%.
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8.发明申请公开(公告)号：US20230052682A1
公开(公告)日：2023-02-16
申请号：US17788144
申请日：2020-12-02
Applicant: Dow Global Technologies LLC
Inventor： Glenn Pollefeyt , Davy L.S. Nieskens , Alexey Kirilin , Adam Chojecki , Joseph F. Dewilde , Barry B. Fish , Andrzej Malek
IPC: C07C1/04
Abstract: A process for preparing C2 to C4 hydrocarbons includes introducing a feed stream into a reaction zone of a reactor, the feed stream comprising hydrogen gas and carbon monoxide. An additional stream is introduced into the reaction zone of the reactor, the additional stream comprising carbon dioxide. A combined stream that includes the feed stream and the additional stream is converted into a product stream comprising C2 to C4 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a mixed metal oxide catalyst component, and a microporous catalyst component. The process operates at a gas hourly space velocity in excess of 2500 hr-1 and effectively yields a net carbon dioxide selectivity of less than 5.0% and a productivity of C2-C4 hydrocarbons greater than 75 g hydrocarbons per kilogram of catalyst per hour.
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公开(公告)号：US09833774B2
公开(公告)日：2017-12-05
申请号：US15300139
申请日：2015-05-14
Applicant: Dow Global Technologies LLC
Inventor： Vera P. Santos Castro , Adam Chojecki , Garmt R. Meima , Adrianus Koeken , Matthijs Ruitenbeek , Thomas Davidian , Gascon Jorge , Michiel Makkee , Freek Kapteijn , Tim A. Wezendonk
CPC classification number: B01J23/78 , B01J27/22 , B01J31/1691 , B01J31/223 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/18 , B01J2231/648 , B01J2531/0216 , B01J2531/842 , C10G2/332 , C10G2300/70
Abstract: Preparation of a catalyst suitable for use in Fischer-Tropsch Synthesis reactions using a two step process in which the steps may be performed in either order. In step a), impregnate an iron carboxylate metal organic framework selected from a group consisting of iron-1,3,5-benzenetricarboxylate (Fe-(BTC), Basolite™ F-300 and/or MIL-100 (Fe)), iron-1,4 benzenedicarboxylate (MIL-101(Fe)), iron fumarate (MIL-88 A (Fe)), iron-1,4 benzenedicarboxylate (MIL-53 (Fe)), iron-1,4 benzenedicarboxylate (MIL-68 (Fe)) or iron azobenzenetetracarboxylate (MIL-127 (Fe)) with a solution of a promoter element selected from alkali metals and alkaline earth metals. In step b) thermally decompose the iron carboxylate metal organic framework under an inert gaseous atmosphere to yield a catalyst that is a porous carbon matrix having embedded therein a plurality of discrete aliquots of iron carbide. If desired, add a step intermediate between steps a) and b) or preceding step b) wherein the metal organic framework is impregnated with an oxygenated solvent solution of a polymerizable additional carbon source and the polymerizable additional carbon source is thereafter polymerized.
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公开(公告)号：US09452420B2
公开(公告)日：2016-09-27
申请号：US14417404
申请日：2013-08-21
Applicant: Dow Global Technologies LLC
Inventor： David G. Barton , Adam Chojecki , Paul R. Elowe , Beata A. Kilos
IPC: C07C41/09 , C09K5/00 , B01J27/10 , B01J23/10 , C01B11/00 , C01F17/00 , B01J37/03 , B01J37/08 , B01J37/02
CPC classification number: B01J27/10 , B01J23/10 , B01J37/0201 , B01J37/031 , B01J37/08 , C01B11/00 , C01F17/0043 , C07C41/09 , C09K5/00 , C07C43/275
Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst is an oxide of a medium rare earth element, wherein the medium rare earth element is samarium, europium, gadolinium, or mixtures thereof.
Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂是中等稀土元素的氧化物，其中中等稀土元素是钐，铕，钆或其混合物。
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