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公开(公告)号：US20220251283A1
公开(公告)日：2022-08-11
申请号：US17433045
申请日：2020-02-14
发明人： Mihir Bhagat , Charmaine Bennett , Youlong Zhu , SonBinh T. Nguyen , Linda Broadbelt , Justin M. Notestein , Matthew E. Belowich , Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
摘要： A method of producing a polyether alcohol that includes feeding an initiator into a reactor, feeding one or more monomers into the reactor, feeding a polymerization catalyst into the reactor, the polymerization catalyst being a Lewis acid catalyst having a general formula M(R1)1(R2)1(R3)1(R4)0 or 1, separate from feeding the initiator into the reactor, feeding a hydrogen bond acceptor additive into the reactor, the hydrogen bond acceptor additive being a C2 to C20 organic molecule having at least two hydroxyl groups, of which two hydroxyl groups are situated in 1,2-, 1,3-, or 1,4- positions on the organic molecule, and allowing the initiator to react with the one or more monomers in the presence of the polymerization catalyst and the hydrogen bond acceptor additive to form a polyether alcohol having a number average molecular weight greater than a number average molecular weight of the initiator.
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公开(公告)号：US11993675B2
公开(公告)日：2024-05-28
申请号：US17433045
申请日：2020-02-14
发明人： Mihir Bhagat , Charmaine Bennett , Youlong Zhu , SonBinh T. Nguyen , Linda Broadbelt , Justin M. Notestein , Matthew E. Belowich , Arjun Raghuraman , William H. Heath , Sukrit Mukhopadhyay , Heather A. Spinney , David R. Wilson
CPC分类号： C08G18/48 , C08G18/10 , C08G65/005 , C08G65/2609 , C08G65/2654 , C08G65/266
摘要： A method of producing a polyether alcohol that includes feeding an initiator into a reactor, feeding one or more monomers into the reactor, feeding a polymerization catalyst into the reactor, the polymerization catalyst being a Lewis acid catalyst having a general formula M(R1)1(R2)1(R3)1(R4)0 or 1, separate from feeding the initiator into the reactor, feeding a hydrogen bond acceptor additive into the reactor, the hydrogen bond acceptor additive being a C2 to C20 organic molecule having at least two hydroxyl groups, of which two hydroxyl groups are situated in 1,2-, 1,3-, or 1,4-positions on the organic molecule, and allowing the initiator to react with the one or more monomers in the presence of the polymerization catalyst and the hydrogen bond acceptor additive to form a polyether alcohol having a number average molecular weight greater than a number average molecular weight of the initiator.
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公开(公告)号：US20230098987A1
公开(公告)日：2023-03-30
申请号：US17786672
申请日：2020-12-17
发明人： Angela I. Padilla-Acevedo , Andrew J. Young , Roger L. Kuhlman , Susan Brown , Matthew E. Belowich , David R. Neithamer , Jerzy Klosin , David M. Pearson , Leslie E. O'Leary , Joseph F. DeWilde
IPC分类号： C08F110/02
摘要： Embodiments are directed towards a use of a supported gas-phase biphenylphenol polymerization catalyst to make a polymer via a gas-phase polymerization process, wherein the supported gas-phase biphenylphenol polymerization catalyst is made from a gas-phase biphenylphenol polymerization precatalyst of Formula I.
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公开(公告)号：US20220290077A1
公开(公告)日：2022-09-15
申请号：US17632678
申请日：2020-09-23
摘要： A fabric care composition is provided, comprising: a fabric care benefit agent; and a deposition aid polymer is provided, comprising >50 to 99 wt % of structural units of formula (I) wherein R1 is selected from hydrogen, —C1-4 alkyl and —CH2OR3; wherein R3 is selected from —C1-12 alkyl and phenyl; and 1 to
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公开(公告)号：US20240150502A1
公开(公告)日：2024-05-09
申请号：US18277331
申请日：2022-02-10
发明人： Ruth Figueroa , Angela I. Padilla-Acevedo , Andrew J. Young , Roger L. Kuhlman , Susan Brown , Matthew E. Belowich , David R. Neithamer , Jerzy Klosin , David M. Pearson , Leslie E. O'Leary , Mari S. Rosen , Joseph F. DeWilde
IPC分类号： C08F4/62 , C08F4/02 , C08F210/02
CPC分类号： C08F4/62193 , C08F4/025 , C08F210/02
摘要： Embodiments are directed towards a use of a supported biphenylphenol polymerization catalyst to make a polymer via a slurry-phase polymerization process, where the supported biphenylphenol polymerization catalyst is made from a biphenylphenol polymerization precatalyst of Formula I.
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公开(公告)号：US11976166B2
公开(公告)日：2024-05-07
申请号：US17298103
申请日：2019-12-02
CPC分类号： C08G65/2696 , C07C45/64 , C08G65/2612 , C08G2650/24
摘要： The present invention is method comprising the steps of a) contacting 4-hydroxyphenone and a salt thereof with propylene oxide in a reactor heated to a temperature in the range of from 100° C. to 200° C. to form a poly(propylene oxide)-benzophenone intermediate; then b) contacting the intermediate with ethylene oxide in the heated reactor to form an alkoxylated benzophenone substituted with propylene oxide groups and ethylene oxide groups. The method of the present invention is useful for preparing a non-volatile alkoxylated benzophenone photoinitiator that gives long lasting gloss retention in an exterior architectural coating.
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公开(公告)号：US20230095201A1
公开(公告)日：2023-03-30
申请号：US17790179
申请日：2021-01-27
发明人： Anne-Catherine Bédard , Matthew E. Belowich , Mari S. Rosen , Sandra Varinia Bernales Candia , David A. Babb , Clark H. Cummins , Richard J. Keaton , Matthew M. Yonkey
IPC分类号： C08G65/26
摘要： Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a cyclic amidine. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of cyclic amidine greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
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公开(公告)号：US20230092304A1
公开(公告)日：2023-03-23
申请号：US17790225
申请日：2021-01-27
发明人： Anne-Catherine Bédard , Matthew E. Belowich , Mari S. Rosen , Sandra Varinia Bernales Candia , David A. Babb , Clark H. Cummins , Richard J. Keaton , Matthew M. Yonkey , Peter J. Waller
IPC分类号： C08G65/26
摘要： Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a phosphorus-nitrogen base. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of phosphorus-nitrogen base greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
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公开(公告)号：US20220403061A1
公开(公告)日：2022-12-22
申请号：US17771854
申请日：2020-11-04
发明人： Angela I. Padilla-Acevedo , Andrew J. Young , Roger L. Kuhlman , Ruth Figueroa , Susan Brown , Matthew E. Belowich , David R. Neithamer , Jerzy Klosin , David M. Pearson , Mari S. Rosen , Bethany M. Neilson , Johnathan E. DeLorbe , Leslie E. O'Leary
摘要： Embodiments are directed towards the use of a supported biphenylphenol polymerization catalyst made from a biphenylphenol polymerization precatalyst of Formula I via a gas-phase or slurry-phase polymerization process under gas-phase or slurry-phase polymerization conditions to make a polymer.
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公开(公告)号：US20210238502A1
公开(公告)日：2021-08-05
申请号：US17049169
申请日：2019-05-09
发明人： Lin Wang , Robin P. Ziebarth , Matthew E. Belowich , Scott Backer , Paul Mercando , Yiyong He
IPC分类号： C11D3/22 , C11D11/00 , C11D17/06 , C11D1/72 , C11D3/33 , C11D3/20 , C11D3/10 , C11D3/30 , C11D3/04 , C11D3/36 , C11D3/386 , C11D3/39 , C11D3/395
摘要： An anhydrous mixed powder or mixed granule is provided including 1 to 10 wt % of oxidized maltodextrin; 10 to 60 wt % of an amino acid based builder; 1 to 87.7 wt % of an additional builder selected from the group consisting of carbonate builders, citrate builders, silicate builders, amino acid derived builders and mixtures thereof; a bleach activator; a surfactant; 0.1 to 7 wt % of a phosphonate; enzyme; 0 to 75 wt % of a filler; and
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