公开(公告)号：US20160272586A1

公开(公告)日：2016-09-22

申请号：US15072780

申请日：2016-03-17

Applicant: Ecolab USA Inc.

Inventor： Jonathan Masere ,  Andrew R. Neilson ,  Russell P. Watson

IPC: C07D211/94 ,  C07C7/20

CPC classification number: C07D211/94 ,  C07C7/20 ,  C07C67/62 ,  C07C11/167 ,  C07C15/46 ,  C07C69/54 ,  C07C11/18

Abstract: The present invention generally relates to compounds and methods for inhibiting the radical polymerization of unsaturated compounds, particularly vinyl monomers. More particularly, it relates to the use of stable hydroxyl amines to inhibit the polymerization of unsaturated compounds (e.g., vinyl monomers) wherein said stable hydroxylamine is soluble in organic solvents, particularly hydrocarbon solvents consisting of unsaturated and, therefore, polymerizable constituents.

Abstract translation: 本发明一般涉及抑制不饱和化合物，特别是乙烯基单体的自由基聚合的化合物和方法。 更具体地说，本发明涉及使用稳定的羟基胺来抑制不饱和化合物（例如乙烯基单体）的聚合，其中所述稳定的羟胺可溶于有机溶剂，特别是由不饱和烃和因此可聚合成分组成的烃溶剂。

公开(公告)号：US11186540B2

公开(公告)日：2021-11-30

申请号：US16925165

申请日：2020-07-09

Applicant: Ecolab USA Inc.

Inventor： Anahita Khanlari ,  Andrew R. Neilson

IPC: C07C233/20 ,  C07C231/02 ,  C07C15/24 ,  C10G75/04 ,  C07D211/76 ,  C07D211/94 ,  C09K15/18 ,  C07C31/20 ,  C10G9/16

Abstract: Disclosed are compositions and methods for preventing or reducing polymer formation and polymer deposition in equipment used in petrochemical processes. An antifoulant composition includes a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents. A method of preventing or reducing fouling of process equipment used in an industrial process is also described. The method includes introducing into the process equipment an antifoulant composition, the antifoulant composition comprising a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents.

公开(公告)号：US20160176788A1

公开(公告)日：2016-06-23

申请号：US14993950

申请日：2016-01-12

Applicant: ECOLAB USA INC.

Inventor： Ramon Colorado, JR. ,  Vincent E. Lewis ,  Robert A. Geiger ,  Jessica M. Hancock ,  Andrew R. Neilson

IPC: C07C7/20 ,  B01J19/00

CPC classification number: C07C7/20 ,  B01J19/002 ,  B01J2219/00164 ,  B01J2219/00254 ,  C08F2/38 ,  C08F2438/02

Abstract: Disclosed herein are systems and methods for monitoring and controlling a nitroxide-based polymerization inhibitor in vinyl-based monomers. A dosage of the nitroxide-based polymerization inhibitor is provided in the vinyl-based monomers. A residual concentration of the nitroxide-based polymerization inhibitor is measured substantially in real time, and an optimized dosage of the nitroxide-based polymerization inhibitor is provided in response to the measured residual concentration.

Abstract translation: 本文公开了用于在乙烯基类单体中监测和控制基于氮氧化物的阻聚剂的系统和方法。 在乙烯基类单体中提供了基于氮氧化物的阻聚剂的用量。 基本上实时测量基于氮氧化物的阻聚剂的残留浓度，并且响应于测量的残留浓度提供基于氮氧化物的阻聚剂的优化剂量。

公开(公告)号：US20140228604A1

公开(公告)日：2014-08-14

申请号：US13765508

申请日：2013-02-12

Applicant: ECOLAB USA INC.

Inventor： Ramon Colorado, JR. ,  Vincent Lewis ,  Robert A. Geiger ,  Jessica Hancock ,  Andrew R. Neilson

IPC: C07C7/20

CPC classification number: C07C7/20 ,  B01J19/002 ,  B01J2219/00164 ,  B01J2219/00254 ,  C08F2/38 ,  C08F2438/02

Abstract: Disclosed herein are systems and methods for monitoring and controlling a nitroxide-based polymerization inhibitor in vinyl-based monomers. A dosage of the nitroxide-based polymerization inhibitor is provided in the vinyl-based monomers. A residual concentration of the nitroxide-based polymerization inhibitor is measured substantially in real time, and an optimized dosage of the nitroxide-based polymerization inhibitor is provided in response to the measured residual concentration.

Abstract translation: 本文公开了用于在乙烯基类单体中监测和控制基于氮氧化物的阻聚剂的系统和方法。 在乙烯基类单体中提供了基于氮氧化物的阻聚剂的用量。 基本上实时测量基于氮氧化物的阻聚剂的残留浓度，并且响应于测量的残留浓度提供基于氮氧化物的阻聚剂的优化剂量。

公开(公告)号：US11180578B2

公开(公告)日：2021-11-23

申请号：US16510053

申请日：2019-07-12

Applicant: Ecolab USA Inc.

Inventor： Jonathan Masere ,  Andrew R. Neilson ,  Bassam Alnasleh ,  Ramon Colorado, Jr.

IPC: C08F2/40 ,  C08F12/30 ,  C08F12/36 ,  C08F20/06 ,  C08F20/18 ,  C08F20/44 ,  C08F26/06 ,  C08K5/00 ,  C08K5/08 ,  C08K5/17 ,  C08K5/3435

Abstract: Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition, which use an N—O polymerization inhibitor, a quinone methide polymerization retarder, and an amine stabilizer having a primary and/or secondary amine group. In a mixture, the amine-based stabilizer can prevent antagonistic effects and can provide greater antipolymerant activity. In turn, the mixture inhibits apparatus fouling and improves the purity of monomer streams.

公开(公告)号：US20200339504A1

公开(公告)日：2020-10-29

申请号：US16925165

申请日：2020-07-09

Applicant: Ecolab USA Inc.

Inventor： Anahita Khanlari ,  Andrew R. Neilson

IPC: C07C233/20 ,  C07C231/02 ,  C07C15/24 ,  C10G75/04 ,  C07D211/76 ,  C07D211/94 ,  C09K15/18 ,  C07C31/20 ,  C10G9/16

Abstract: Disclosed are compositions and methods for preventing or reducing polymer formation and polymer deposition in equipment used in petrochemical processes. An antifoulant composition includes a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents. A method of preventing or reducing fouling of process equipment used in an industrial process is also described. The method includes introducing into the process equipment an antifoulant composition, the antifoulant composition comprising a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents.

公开(公告)号：US09266797B2

公开(公告)日：2016-02-23

申请号：US13765508

申请日：2013-02-12

Applicant: Ecolab USA Inc.

Inventor： Ramon Colorado, Jr. ,  Vincent Lewis ,  Robert A. Geiger ,  Jessica Hancock ,  Andrew R. Neilson

IPC: C07C2/04 ,  C07C7/20 ,  C08F2/38

CPC classification number: C07C7/20 ,  B01J19/002 ,  B01J2219/00164 ,  B01J2219/00254 ,  C08F2/38 ,  C08F2438/02

Abstract: Disclosed herein are systems and methods for monitoring and controlling a nitroxide-based polymerization inhibitor in vinyl-based monomers. A dosage of the nitroxide-based polymerization inhibitor is provided in the vinyl-based monomers. A residual concentration of the nitroxide-based polymerization inhibitor is measured substantially in real time, and an optimized dosage of the nitroxide-based polymerization inhibitor is provided in response to the measured residual concentration.

Abstract translation: 本文公开了用于在乙烯基类单体中监测和控制基于氮氧化物的阻聚剂的系统和方法。 在乙烯基类单体中提供了基于氮氧化物的阻聚剂的用量。 基本上实时测量基于氮氧化物的阻聚剂的残留浓度，并且响应于测量的残留浓度提供基于氮氧化物的阻聚剂的优化剂量。

公开(公告)号：US11174439B2

公开(公告)日：2021-11-16

申请号：US16326035

申请日：2017-08-23

Applicant: Ecolab USA, Inc. ,  SABIC Global Technologies B.V.

Inventor： Jerome Vachon ,  Anthoni van Zijl ,  Fabrice Cuoq ,  Steven Leen ,  Carlo Geijselaers ,  Andrew R. Neilson ,  Russell P Watson

IPC: C10G9/16 ,  C09K8/524 ,  C07C4/04 ,  C23F14/02 ,  C02F1/68 ,  C10G75/04 ,  C23F15/00 ,  C02F101/32 ,  C02F103/36

Abstract: Disclosed herein are methods for reducing fouling caused by process water present within a water recycling loop of a pyrolysis plant. Fouling is caused by phase separation and accumulation of materials from the process water on equipment surfaces. The method includes applying a total of about 5 ppm to 500 ppm total of a first polymerization inhibitor and second polymerization inhibitor to the process water to form a treated process water, wherein the first polymerization inhibitor has a pygas-water partition coefficient of about 0.0001 to 9 and the second polymerization inhibitor has a pygas-water partition coefficient of about 1000 to 50,000.

公开(公告)号：US20200017610A1

公开(公告)日：2020-01-16

申请号：US16510053

申请日：2019-07-12

Applicant: Ecolab USA Inc.

Inventor： Jonathan Masere ,  Andrew R. Neilson ,  Bassam Alnasleh ,  Ramon Colorado, JR.

IPC: C08F2/40 ,  C08K5/08 ,  C08K5/00 ,  C08K5/17 ,  C08K5/3435 ,  C08F12/30 ,  C08F20/06 ,  C08F20/18 ,  C08F20/44 ,  C08F12/36 ,  C08F26/06

Abstract: Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition, which use an N—O polymerization inhibitor, a quinone methide polymerization retarder, and an amine stabilizer having a primary and/or secondary amine group. In a mixture, the amine-based stabilizer can prevent antagonistic effects and can provide greater antipolymerant activity. In turn, the mixture inhibits apparatus fouling and improves the purity of monomer streams.

公开(公告)号：US20180244605A1

公开(公告)日：2018-08-30

申请号：US15903779

申请日：2018-02-23

Applicant: ECOLAB USA INC.

Inventor： Anahita Khanlari ,  Andrew R. Neilson

IPC: C07C233/20 ,  C07C231/02 ,  C07C15/24 ,  C07C31/20 ,  C07D211/76 ,  C07D211/94 ,  C09K15/18 ,  C10G75/04

Abstract: Disclosed are compositions and methods for preventing or reducing polymer formation and polymer deposition in equipment used in petrochemical processes. An antifoulant composition includes a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents. A method of preventing or reducing fouling of process equipment used in an industrial process is also described. The method includes introducing into the process equipment an antifoulant composition, the antifoulant composition comprising a combination of one or more antioxidants; one or more antipolymerants; one or more dispersants; and one or more solvents.