公开(公告)号：US09206370B2

公开(公告)日：2015-12-08

申请号：US13717783

申请日：2012-12-18

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Kristen Amanda Lyon ,  Eugenio Sanchez ,  Charles Lambert Baker, Jr. ,  Beatrice Marie Gooding ,  Frank Cheng-Yu Wang

IPC: C10M105/02 ,  C10M105/04 ,  C10M105/06 ,  C10M177/00 ,  C10M109/02

CPC classification number: C10M105/06 ,  C10G2300/1011 ,  C10G2400/10 ,  C10M105/04 ,  C10M109/02 ,  C10M177/00 ,  C10M2203/0206 ,  C10M2203/022 ,  C10M2203/045 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2230/02 ,  C10N2230/74 ,  C10N2260/02 ,  C10N2270/00 ,  Y02P30/20

Abstract: Provided are lube base stocks produced from renewable biological sources with improved low temperature properties. In one form, the lube base stock includes from 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) of less than or equal to 0.85 at −35° C. The base stocks are useful as in formulated lubricant compositions requiring improved low temperature properties.

Abstract translation: 提供了由具有改进的低温性能的可再生生物源生产的润滑油基础油料。 在一种形式中，润滑油基料包含10至35wt。 ％石蜡，40至70wt。 ％环环烷烃，0〜40wt。 组合的2-环环烷烃和芳族化合物，并且1-环环烷烃与链烷烃的比例为1.8至5.0，粘度指数为100至160.润滑油基料的14℃水平为2〜101％ 在大气中的现代14C水平，并且在-35℃下产生CCS比率（Cold Crank Simulator（CCS）粘度与Walther方程式的预测CCS粘度）小于或等于0.85。基础油有用作 在需要改进的低温性能的配方润滑剂组合物中。

公开(公告)号：US20130217606A1

公开(公告)日：2013-08-22

申请号：US13717805

申请日：2012-12-18

Applicant: Exxonmobil Research And Engineering Company

Inventor： Kun Wang ,  Kristen Amanda Lyon ,  Eugenio Sanchez ,  Charles Lambert Baker, Jr. ,  Beatrice Marie Gooding ,  Frank Cheng-Yu Wang

IPC: C10M129/60 ,  C10M129/40

CPC classification number: C10M129/60 ,  C10G2300/1011 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M105/04 ,  C10M129/40 ,  C10M169/041 ,  C10M2203/0206 ,  C10M2203/04 ,  C10M2205/06 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/025 ,  C10N2220/029 ,  C10N2230/10 ,  C10N2230/74 ,  C10N2270/00 ,  Y02P30/20 ,  C10M2205/04

Abstract: Provided are lubricant compositions from renewable biological sources with improved properties and methods of making and using such compositions. In one form, the lubricant composition includes from 20 to 99.8 wt. % of a lube base stock produced from a renewable biological source and an effective amount of one or more lubricant additives. The lube base stock includes 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio of less than or equal to 0.85 at −35° C. The lubricant compositions exhibit improved solvency and % thickening when blended with a viscosity modifier.

Abstract translation: 提供了具有改进性质的可再生生物源的润滑剂组合物和制备和使用这些组合物的方法。 在一种形式中，润滑剂组合物包含20至99.8wt。 从可再生生物源产生的润滑油基础油的百分比和有效量的一种或多种润滑剂添加剂。 润滑油基料包含10至35wt。 ％石蜡，40至70wt。 ％环环烷烃，0〜40wt。 组合的2-环环烷烃和芳族化合物，并且1-环环烷烃与链烷烃的比例为1.8至5.0，粘度指数为100至160.润滑油基料的14℃水平为2〜101％ 在大气中的现代14℃水平，并且在-35℃下产生小于或等于0.85的CCS比。当与粘度调节剂混合时，润滑剂组合物显示出改善的溶解力和增稠％。

公开(公告)号：US09206372B2

公开(公告)日：2015-12-08

申请号：US13717805

申请日：2012-12-18

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Kristen Amanda Lyon ,  Eugenio Sanchez ,  Charles Lambert Baker, Jr. ,  Beatrice Marie Gooding ,  Frank Cheng-Yu Wang

IPC: C10M105/02 ,  C10M105/04 ,  C10M129/60 ,  C10M129/40 ,  C10M169/04

CPC classification number: C10M129/60 ,  C10G2300/1011 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2400/10 ,  C10M105/04 ,  C10M129/40 ,  C10M169/041 ,  C10M2203/0206 ,  C10M2203/04 ,  C10M2205/06 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/025 ,  C10N2220/029 ,  C10N2230/10 ,  C10N2230/74 ,  C10N2270/00 ,  Y02P30/20 ,  C10M2205/04

Abstract: Provided are lubricant compositions from renewable biological sources with improved properties and methods of making and using such compositions. In one form, the lubricant composition includes from 20 to 99.8 wt. % of a lube base stock produced from a renewable biological source and an effective amount of one or more lubricant additives. The lube base stock includes 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio of less than or equal to 0.85 at −35° C. The lubricant compositions exhibit improved solvency and % thickening when blended with a viscosity modifier.

Abstract translation: 提供了具有改进性质的可再生生物源的润滑剂组合物和制备和使用这些组合物的方法。 在一种形式中，润滑剂组合物包含20至99.8wt。 从可再生生物源产生的润滑油基础油的百分比和有效量的一种或多种润滑剂添加剂。 润滑油基料包含10至35wt。 ％石蜡，40至70wt。 ％环环烷烃，0〜40wt。 组合的2-环环烷烃和芳族化合物，并且1-环环烷烃与链烷烃的比例为1.8至5.0，粘度指数为100至160.润滑油基料的14℃水平为2〜101％ 在大气中的现代14℃水平，并且在-35℃下产生小于或等于0.85的CCS比。当与粘度调节剂混合时，润滑剂组合物显示出改善的溶解力和增稠％。

公开(公告)号：US20130190544A1

公开(公告)日：2013-07-25

申请号：US13717783

申请日：2012-12-18

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Kristen Amanda Lyon ,  Eugenio Sanchez ,  Charles Lambert Baker, Jr. ,  Beatrice Marie Gooding ,  Frank Cheng-Yu Wang

IPC: C10M105/06

CPC classification number: C10M105/06 ,  C10G2300/1011 ,  C10G2400/10 ,  C10M105/04 ,  C10M109/02 ,  C10M177/00 ,  C10M2203/0206 ,  C10M2203/022 ,  C10M2203/045 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2230/02 ,  C10N2230/74 ,  C10N2260/02 ,  C10N2270/00 ,  Y02P30/20

Abstract: Provided are lube base stocks produced from renewable biological sources with improved low temperature properties. In one form, the lube base stock includes from 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) of less than or equal to 0.85 at −35° C. The base stocks are useful as in formulated lubricant compositions requiring improved low temperature properties.

Abstract translation: 提供了由具有改进的低温性能的可再生生物源生产的润滑油基础油料。 在一种形式中，润滑油基料包含10至35wt。 ％石蜡，40至70wt。 ％环环烷烃，0〜40wt。 组合的2-环环烷烃和芳族化合物，并且1-环环烷烃与链烷烃的比例为1.8至5.0，粘度指数为100至160.润滑油基料的14℃水平为2〜101％ 在大气中的现代14C水平，并且在-35℃下产生CCS比率（Cold Crank Simulator（CCS）粘度与Walther方程式的预测CCS粘度）小于或等于0.85。基础油有用作 在需要改进的低温性能的配方润滑剂组合物中。

公开(公告)号：US20180143168A1

公开(公告)日：2018-05-24

申请号：US15723415

申请日：2017-10-03

Applicant: ExxonMobil Research and Engineering Company

Inventor： Frank Cheng-Yu Wang ,  Changyub Paek ,  Kuangnan Qian ,  Francis X. Kelly

IPC: G01N30/60

CPC classification number: G01N30/6034 ,  G01N30/463 ,  G01N30/78 ,  G01N30/8693 ,  G01N33/28 ,  G01N2030/8854

Abstract: Methods to generate a model of composition for a petroleum sample can include providing a petroleum sample to a two-dimensional gas chromatograph coupled with at least one detector. The chromatograph can have first and second columns. The chromatograph can be adapted to output data for each detector representing first and second dimension retention times corresponding to the first and second columns, respectively. The data representing the first and second dimension retention times for each detector based on the petroleum sample can be obtained from the chromatograph. Molecular components of the petroleum sample can be identified based at least in part on the first and second dimension retention times for each detector. The identified molecular components of the petroleum sample can be quantified based at least in part on integrated peaks of the first and second dimension retention times for each detector to generate a model of composition of the petroleum sample.

公开(公告)号：US09574138B2

公开(公告)日：2017-02-21

申请号：US14096277

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Virginia M. Roberts ,  Paul D. Oldenburg ,  Suzzy Chen Hsi Ho ,  Michel Daage ,  Frank Cheng-Yu Wang

IPC: C10G3/00 ,  C10M105/04

CPC classification number: C10G3/50 ,  C10G3/44 ,  C10M105/04 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.

Abstract translation: 提供了从可再生饲料源制备饱和烃的方法。 在一个实施方案中，用于从生物来源的原料生产润滑油基础油料和/或柴油燃料的方法包括：在氢存在下在单个反应器中使原料与包含第一催化剂和第二催化剂的催化剂组分接触，其中 第一催化剂包括酸性物质，碱性物质或两者的组合，其中第二催化剂是包含水热稳定粘合剂的氢化催化剂。

公开(公告)号：US20140174980A1

公开(公告)日：2014-06-26

申请号：US13796326

申请日：2013-03-12

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY

Inventor： Stephen Harold Brown ,  Frank Cheng-Yu Wang ,  Stephen Mark Davis ,  Cathleen Yung

IPC: C10C1/20

CPC classification number: C10C1/205 ,  C10G9/36 ,  C10G45/44 ,  C10G69/06 ,  C10L1/04 ,  C10L1/1616 ,  C10L2200/0438 ,  C10L2290/543

Abstract: Provided is a hydrocarbon tar. The tar has 75 wt % or more of aromatics of 10 carbons to 75 carbons based on the total weight of the tar. The aromatics exhibit 40% to 80% aromaticity. The tar has a boiling point of from 300° F. to 1350° F. There is also a fuel oil composition having the tar therein. There are also processes for making the hydrocarbon tar.

Abstract translation: 提供烃焦油。 基于焦油的总重量，焦油具有75重量％或更多的10个碳至75个碳的芳族化合物。 芳烃具有40％至80％的芳香度。 焦油的沸点为300°F至1350°F。还有一种在其中具有焦油的燃料油组合物。 还有制备烃焦油的方法。

公开(公告)号：US20140171699A1

公开(公告)日：2014-06-19

申请号：US14096277

申请日：2013-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： Kun Wang ,  Virginia M. Roberts ,  Paul D. Oldenburg ,  Suzzy Chen Hsi Ho ,  Michel Daage ,  Frank Cheng-Yu Wang

IPC: C10G3/00 ,  C10M105/04

CPC classification number: C10G3/50 ,  C10G3/44 ,  C10M105/04 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.

Abstract translation: 提供了从可再生饲料源制备饱和烃的方法。 在一个实施方案中，用于从生物来源的原料生产润滑油基础油料和/或柴油燃料的方法包括：在氢存在下在单个反应器中将原料与包含第一催化剂和第二催化剂的催化剂组分接触，其中 第一催化剂包括酸性物质，碱性物质或两者的组合，其中第二催化剂是包含水热稳定粘合剂的氢化催化剂。