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1.发明授权
公开(公告)号：US4322489A
公开(公告)日：1982-03-30
申请号：US142636
申请日：1980-04-22
IPC分类号： C08F12/00 , C08F26/00 , C08F26/06 , C08F212/14 , C08F226/06 , G03C8/56 , G03G7/00
CPC分类号： G03C8/56 , C08F226/06 , Y10S430/142
摘要： Copolymeric mordant materials containing recurring units according to the following formula are disclosed: ##STR1## In such copolymers, each of R.sup.1, R.sup.2 and R.sup.3 can independently be alkyl; substituted alkyl; cycloalkyl; aryl; aralkyl; alkaryl; or at least two of R.sup.1, R.sup.2 and R.sup.3, together with the quaternary nitrogen atom to which they are bonded, can complete a saturated or unsaturated, substituted or unsubstituted nitrogen-containing heterocyclic ring; and X is an anion. The molar ratio of a:b can range from about 0.1:1 to about 10:1, e.g., about 0.3:1 to about 3:1.The copolymeric mordant materials can be utilized as image-receiving layers and in photographic products and processes of the diffusion transfer type. The mordants are especially adapted to the production of dye images free of objectionable haze, yellowing or related image defects.
摘要翻译： 公开了含有根据下式的重复单元的共聚媒染材料：在这种共聚物中，R 1，R 2和R 3中的每一个可以独立地为烷基; 取代的烷基; 环烷基 芳基; 芳烷基 烷芳基 或R 1，R 2和R 3中的至少两个与它们所键合的季氮原子一起可以完成饱和或不饱和的，取代或未取代的含氮杂环; X为阴离子。 a：b的摩尔比可以为约0.1:1至约10:1，例如约0.3:1至约3:1。 共聚媒染材料可以用作图像接收层，以及在扩散转移型的照相产品和方法中。 媒染剂特别适用于不产生令人反感的浑浊，变黄或相关图像缺陷的染料图像。
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公开(公告)号：US4424326A
公开(公告)日：1984-01-03
申请号：US361422
申请日：1982-03-24
IPC分类号： C08F226/06 , G03C8/56 , G03C1/40
CPC分类号： C08F226/06 , G03C8/56
摘要： Copolymeric mordant materials containing recurring units according to the following formula are disclosed: ##STR1## In such copolymers, each of R.sup.1, R.sup.2 and R.sup.3 can independently be alkyl; substituted alkyl; cycloalkyl; aryl; aralkyl; alkaryl; or at least two of R.sup.1, R.sup.2 and R.sup.3, together with the quaternary nitrogen atom to which they are bonded, can complete a saturated or unsaturated, substituted or unsubstituted nitrogen-containing heterocyclic ring; and X is an anion. The molar ratio of a:b can range from about 0.1:1 to about 10:1, e.g., about 0.3:1 to about 3:1. The copolymeric mordant materials can be utilized as image-receiving layers and in photographic products and processes of the diffusion transfer type. The mordants are especially adapted to the production of dye images free of objectionable haze, yellowing or related image defects.
摘要翻译： 公开了含有根据下式的重复单元的共聚媒染材料：在这种共聚物中，R 1，R 2和R 3中的每一个可以独立地为烷基; 取代的烷基; 环烷基 芳基; 芳烷基 烷芳基 或R 1，R 2和R 3中的至少两个与它们所键合的季氮原子一起可以完成饱和或不饱和的，取代或未取代的含氮杂环; X为阴离子。 a：b的摩尔比可以为约0.1:1至约10:1，例如约0.3:1至约3:1。 共聚媒染材料可以用作图像接收层，以及在扩散转移型的照相产品和方法中。 媒染剂特别适用于不产生令人反感的浑浊，变黄或相关图像缺陷的染料图像。
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公开(公告)号：US4294907A
公开(公告)日：1981-10-13
申请号：US143281
申请日：1980-04-24
摘要： Diffusion transfer films and processes are disclosed wherein the processing composition includes a light-reflecting pigment and an optical filter agent, and the image-receiving layer carries over it a layer containing a substantially non-diffusible agent adapted to decolorize optical filter agent immediately adjacent the interface between said processing composition and said decolorizing layer.
摘要翻译： 公开了扩散转移膜和方法，其中处理组合物包括光反射颜料和滤光剂，并且图像接收层携带包含基本上不可扩散剂的层，其适于使邻近的光学滤光剂脱色 所述处理组合物和所述脱色层之间的界面。
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4.发明授权
公开(公告)号：US4621156A
公开(公告)日：1986-11-04
申请号：US309914
申请日：1981-10-08
IPC分类号： G03C8/48 , C07C109/12
CPC分类号： G03C8/48
摘要： Optical filter agents and photographic products and processes using same are disclosed. The optical filter agents are pH-sensitive hydrazone compounds conforming to the following structural formula: ##STR1## where R is any group which can provide a double bond for conjugation with the ##STR2## portion of the compound to provide light-absorbing capability or color for the agent at a pH above its pKa, X is a substituent of R providing at least one electron-withdrawing group and each R' can be defined as any substituent that does not impair the light-absorbing capacity of the compound at a pH above the pKa thereof. The pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The pH-sensitive optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurrence of fogging during in-light development.
摘要翻译： 公开了使用其的光学过滤剂和照相产品和方法。 光学过滤剂是符合以下结构式的pH敏感腙化合物：其中R是可以提供双键与化合物的
部分缀合以提供光吸收能力或颜色的任何基团 对于高于其pKa的pH的试剂，X是提供至少一个吸电子基团的R的取代基，并且每个R'可以被定义为在上述pH下不影响化合物的光吸收能力的任何取代基 其pKa。 pH敏感的光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。 pH敏感的光学过滤剂可用于照相胶片单元和用于保护光敏元件免于在光照显影过程中发生起雾的过程。 -
5.发明授权Polymeric pH-sensitive optical filter agents having hydrazone moieties attached thereto 失效具有连接有腙部分的聚合物pH敏感光学滤光剂
公开(公告)号：US4468494A
公开(公告)日：1984-08-28
申请号：US250401
申请日：1981-04-02
CPC分类号： G03C8/48
摘要： Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosenstive elements against the occurence of fogging during in-light development.
摘要翻译： 公开了聚合物光学滤光剂和使用它们的照相产品和方法。 聚合物光学过滤剂是pH敏感的光学过滤剂，其包含具有以下腙部分的聚合物主链单元：其中R是能够提供双键以与该部分的“IMAGE”部分缀合以提供光的基团 - 在高于其pKa的pH下的试剂的吸收能力，X表示提供至少一个吸电子基团的R的取代基。 聚合物pH敏感光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。 聚合物光学滤光剂可用于照相胶片单元和用于保护光敏光敏元件免于在光照显影过程中发生雾化的过程。
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6.发明授权
公开(公告)号：US4298676A
公开(公告)日：1981-11-03
申请号：US89559
申请日：1979-10-29
CPC分类号： G03C8/48
摘要： Optical filter agents and photographic products and processes using same are disclosed. The optical filter agents are pH-sensitive hydrazone compounds conforming to the following structural formula: ##STR1## where R is any group which can provide a double bond for conjugation with the ##STR2## portion of the compound to provide light-absorbing capability or color for the agent at a pH above its pKa, X is a substituent of R providing at least one electron-withdrawing group and each R' can be defined as any substituent that does not impair the light-absorbing capacity of the compound at a pH above the pKa thereof. The pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The pH-sensitive optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
摘要翻译： 公开了使用其的光学过滤剂和照相产品和方法。 光学过滤剂是符合以下结构式的pH敏感腙化合物：其中R是可以提供双键与化合物的
部分缀合以提供光吸收能力或颜色的任何基团 对于高于其pKa的pH的试剂，X是提供至少一个吸电子基团的R的取代基，并且每个R'可以被定义为在上述pH以上不会损害化合物的光吸收能力的任何取代基 其pKa。 pH敏感的光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。 pH敏感的光学滤光剂可用于照相胶片单元和用于保护光敏元件的过程，以防止在光照显影过程中发生起雾。 -
7.发明授权Polymeric optical filter agents and photographic products and processes containing same 失效聚合物光学滤光剂和含有它们的摄影产品和方法
公开(公告)号：US4269925A
公开(公告)日：1981-05-26
申请号：US089558
申请日：1979-10-29
CPC分类号： G03C8/48
摘要： Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
摘要翻译： 公开了聚合物光学滤光剂和使用它们的照相产品和方法。 聚合物光学过滤剂是pH敏感的光学过滤剂，其包含具有以下腙部分的聚合物主链单元：其中R是能够提供双键以与该部分的“IMAGE”部分缀合以提供光的基团 - 在高于其pKa的pH下的试剂的吸收能力，X表示提供至少一个吸电子基团的R的取代基。 聚合物pH敏感光学过滤剂在高于pKa的pH下具有高度着色的光吸收形式，并且在低于pKa的pH下基本上不吸收。 聚合物光学滤光剂可用于照相胶片单元和用于保护光敏元件免于在光照显影过程中发生起雾的过程。
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公开(公告)号：US4124388A
公开(公告)日：1978-11-07
申请号：US793061
申请日：1977-05-02
CPC分类号： G03C8/56 , Y10S430/142
摘要： Photographic film units and photographic products using an acetal of a hydroxylated polymer and a formyl benzyl quaternary salt(s) as a mordant for diffusible dye image-providing materials.
摘要翻译： 使用羟基化聚合物和甲酰苄基季盐的缩醛作为媒染剂的摄影胶片单元和摄影产品，用于可扩散染料图像提供材料。
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公开(公告)号：US5578424A
公开(公告)日：1996-11-26
申请号：US376037
申请日：1995-01-20
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
IPC分类号： B41M5/30 , B41M5/333 , C07C49/593 , G03C1/675 , G03C1/73 , G03F7/004 , G03C1/725 , G03C1/735 , G03C5/00
CPC分类号： C07C49/593 , B41M5/30 , G03C1/73 , G03F7/0045 , Y10S430/145 , Y10S430/146
摘要： Acid can be generated by exposing a mixture of a superacid precursor and a dye to actinic radiation of a first wavelength which does not, in the absence of the dye, cause decomposition of the superacid precursor to form the corresponding superacid, thereby causing absorption of the actinic radiation and decomposition of part of the superacid precursor, with formation of a protonated product derived from the dye, then irradiating the mixture with actinic radiation of a second wavelength, thereby causing decomposition of part of the remaining superacid precursor, with formation of unbuffered superacid. Preferably, following these irradiations, the imaging medium is heated while the superacid is admixed with a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed by the presence of the superacid. The acid generation process may be used for imaging by bringing the superacid or second acid into contact with an acid-sensitive material which changes color on contact with acid, or the superacid may be used to trigger polymerization, depolymerization or other reactions.
摘要翻译： 可以通过将超强酸前体和染料的混合物暴露于第一波长的光化辐射而产生酸，在第一波长的光化辐射下，在不存在染料的情况下，超级酸性前体不会分解形成相应的超强酸，从而引起吸收 光化辐射和部分超酸前体的分解，形成衍生自染料的质子化产物，然后用第二波长的光化辐射照射混合物，从而导致部分剩余的超酸前体分解，形成无缓冲的超酸 。 优选地，在这些照射之后，加热成像介质，同时将超强酸与能够热分解形成第二酸的次级酸发生剂混合，二次酸产生剂的热分解由超强酸的存在催化。 酸生成方法可以通过使超酸或第二酸与酸接触改变颜色的酸敏感材料接触而使用，或者超酸可用于引发聚合，解聚或其它反应。
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公开(公告)号：US5534388A
公开(公告)日：1996-07-09
申请号：US407576
申请日：1995-03-20
申请人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Mark R. Mischke , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
发明人： Jurgen M. Grasshoff , John L. Marshall , Richard A. Minns , Mark R. Mischke , Anthony J. Puttick , Lloyd D. Taylor , Stephen J. Telfer
IPC分类号： B41M5/30 , B41M5/333 , C07C49/593 , G03C1/675 , G03C1/73 , G03F7/004 , G03C1/725 , G03C1/735 , G03C5/00
CPC分类号： B41M5/30 , C07C49/593 , G03C1/73 , G03F7/0045
摘要： Acid can be generated by exposing a superacid precursor to actinic radiation effective to generate superacid from the superacid precursor and heating the superacid in admixture with a secondary acid generator capable of undergoing thermal decomposition to produce a secondary acid. The superacid catalyzes decomposition of the secondary acid generator, thus increasing the quantity of strong acid present in the medium. The resultant secondary acid can be used to effect a color change in an acid-sensitive material, so providing an imaging process.
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