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公开(公告)号：US5945374A
公开(公告)日：1999-08-31
申请号：US995689
申请日：1997-12-22
IPC分类号： B41M5/035 , B41M5/00 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/50 , B41M5/52 , B41M5/38
CPC分类号： B41M5/38235 , B41M5/3856 , B41M5/52 , B41M5/385 , B41M5/3854 , B41M5/388 , B41M5/39 , B41M5/5227 , B41M5/5245 , Y10S428/913 , Y10S428/914
摘要： A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being:I) an electrically neutral, deprotonated, delocalized cationic dye precursor;II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a covalent linking group, E represents a moiety with basic properties and m is an integer of 1-3; orIII) a cationic dye precursor having the following structure: ##STR1## (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising an acidic salt formed from the reaction of a weak, nitrogen-containing base with a strong protic acid dissolved or dispersed in a polymeric binder.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示共价连接基团，E表示具有碱性的部分，m表示1-3的整数; 或III）具有以下结构的阳离子染料前体：（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合染料影像接收层接触，聚合染料影像接收层包含由弱含氮碱与溶解或分散在聚合物中的强质子酸反应形成的酸性盐 粘合剂
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公开(公告)号：US5928990A
公开(公告)日：1999-07-27
申请号：US995825
申请日：1997-12-22
申请人： Robert A. Guistina , Elizabeth G. Burns , Teh-Ming Kung , Kristine B. Lawrence , Richard C. VanHanehem
发明人： Robert A. Guistina , Elizabeth G. Burns , Teh-Ming Kung , Kristine B. Lawrence , Richard C. VanHanehem
IPC分类号： B41M5/385 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/50 , B41M5/52 , C08L67/02 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5218 , B41M5/5272 , B41M5/38207 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising:(I) a dye-donor element comprising a support having thereon sequentially repeating dye layer patches of a dye dispersed in a polymeric binder, at least one of the dye patches containing a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system; and(II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer comprising a polyester polymer which itself does not significantly reprotonate deprotonated cationic dyes which may be transferred from the dye-donor element, to which has been added a hydrated transition metal or metalloid salt of a strong acid;the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料顺序重复染料层贴片的载体，至少一种含有去质子化阳离子染料的染色剂，其能够 被染色成具有作为共轭体系的一部分的NH基团的阳离子染料; 和（II）染料接收元件，其包含其上具有聚合物染料影像接收层的聚合物染料影像接收层的载体，聚合物聚合物本身不会显着地再生可能从染料供体元件转移的去质子化的阳离子染料， 强酸的水合过渡金属或准金属盐; 染料接收元件与染料供体元件处于重叠关系，使得染料层与聚合染料影像接收层接触。
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公开(公告)号：US5789343A
公开(公告)日：1998-08-04
申请号：US879061
申请日：1997-06-19
申请人： Robert A. Guistina , Wayne A. Bowman , Elizabeth G. Burns , Susan L. Dawson , Kristine B. Lawrence , Richard C. VanHanehem
发明人： Robert A. Guistina , Wayne A. Bowman , Elizabeth G. Burns , Susan L. Dawson , Kristine B. Lawrence , Richard C. VanHanehem
IPC分类号： B41M5/385 , B41M5/00 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/50 , B41M5/52 , B41M5/35 , B41M5/38
CPC分类号： B41M5/385 , B41M5/52 , B41M5/5218 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/31855
摘要： A thermal dye transfer assemblage comprising: (I) a dye-donor element comprising a support having thereon sequentially repeating dye layer patches of a dye dispersed in a polymeric binder, at least one of the dye patches containing a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system; and (II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer comprising a vinyl polymer having no or only slight acidity and a hydrated transition metal or metalloid salt of a strong acid, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料顺序重复染料层贴片的载体，至少一种含有去质子化阳离子染料的染色剂，其能够 被染色成具有作为共轭体系的一部分的NH基团的阳离子染料; 和（II）染料接收元件，其包含其上具有聚合物染料影像接收层的载体，所述聚合染料影像接收层包含不具有或仅具有轻微酸性的乙烯基聚合物和强酸的水合过渡金属或准金属盐，所述染料接收元件为 与染料供体元件重叠的关系，使得染料层与聚合物染料影像接收层接触。
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4.发明授权
公开(公告)号：US5733846A
公开(公告)日：1998-03-31
申请号：US761055
申请日：1996-12-05
CPC分类号： B41M5/385 , B41M5/52 , B41M5/3854 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/24802 , Y10T428/31855
摘要： A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system, and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of i) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; and ii) a polymeric acid with a saturated hydrocarbon backbone capable of reprotonating the deprotonated cationic dye.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料是去质子化的阳离子染料，其能够被再赋色为阳离子染料， 作为共轭体系的一部分的NH基团，和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合物染料影像接收层接触，聚合染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; 和ii）具有能够使去质子化的阳离子染料重现的饱和烃主链的聚合酸。
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公开(公告)号：US5804531A
公开(公告)日：1998-09-08
申请号：US995728
申请日：1997-12-22
IPC分类号： B41M5/035 , B41M5/00 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , B41M5/38
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/3856 , B41M5/388 , B41M5/39 , B41M5/52 , B41M5/5227 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being: I) an electrically neutral, deprotonated, delocalized cationic dye precursor; II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a covalent linking group, E represents a moiety with basic properties and m is an integer of 1-3; or III) a cationic dye precursor having the following structure: ##STR1## (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a polyester ionomer comprising a polyester backbone containing units of a salt of a sulfonic acid or sulfonimide and a basic nitrogen-containing compound which has a pKa of its conjugate acid in the range from about 6 to about 10.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示共价连接基团，E表示具有碱性的部分，m表示1-3的整数; 或III）具有以下结构的阳离子染料前体：（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料接收元件处于重叠关系， 供体元件，使得染料层与染料影像接收层接触，染料影像接收层包含聚酯离聚物，其包含含有磺酸或磺酰亚胺盐和含碱性含氮化合物的单元的聚酯骨架 其共轭酸的pKa在约6至约10的范围内。
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6.发明授权
公开(公告)号：US5753590A
公开(公告)日：1998-05-19
申请号：US878717
申请日：1997-06-19
IPC分类号： B41M5/385 , B41M5/00 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/395 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/385 , B41M5/52 , B41M5/3854 , B41M5/388 , B41M5/39 , B41M5/5218 , B41M5/5245 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/259
摘要： A thermal dye transfer assemblage comprising: (I) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and(II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of a) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; and b) an acidic clay capable of reprotonating the deprotonated cationic dye.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有染料层的载体，所述染料层包含分散在聚合物粘合剂中的染料，所述染料是去质子化的阳离子染料，其能够被再赋色为阳离子染料， 作为共轭系统的一部分的NH基，和（II）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合染料影像接收层接触，聚合染料影像接收层包含a）Tg小于约19℃并且没有或仅有轻微酸度的聚合物的混合物; 和b）能够使去质子化的阳离子染料重现的酸性粘土。
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公开(公告)号：US6015772A
公开(公告)日：2000-01-18
申请号：US75082
申请日：1998-05-08
CPC分类号： B41M5/5254 , B41M5/5245 , Y10S428/913 , Y10S428/914
摘要： A dye-receiving element for thermal dye transfer comprising a support having on one side thereof a dye image-receiving layer comprising a vinyl latex polymer having the following general formula:A.sub.a -B.sub.b -C.sub.cwherein:A is derived from monomers which, when homopolymerized, yield a polymer having a Tg greater than 25;a is between 5 and 45 mole percent;B is derived from monomers which, when homopolymerized, yield a polymer having a Tg less than 10;b is between 35 and 90 mole percent;C is a repeat unit derived from the salt of an anionic water-soluble monomer; andc is between 0 and 20 mole percent.
摘要翻译： 一种用于热染料转移的染料接收元件，其包含一种载体，其一侧具有染料影像接受层，该染料影像接受层包含具有以下通式的乙烯基胶乳聚合物：Aa-Bb-Cc其中：A衍生自当均聚时 ，得到Tg大于25的聚合物; a为5至45摩尔％; B衍生自当均聚时得到Tg小于10的聚合物的单体; b为35至90摩尔％; C是衍生自阴离子水溶性单体的盐的重复单元; 且c为0至20摩尔％。
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8.发明授权
公开(公告)号：US5945376A
公开(公告)日：1999-08-31
申请号：US98996
申请日：1998-06-17
申请人： Elizabeth G. Burns , Kristine B. Lawrence , John DiCillo , Ricky G. Frazier , Daniel J. Harrison , Shandralynn Joiner
发明人： Elizabeth G. Burns , Kristine B. Lawrence , John DiCillo , Ricky G. Frazier , Daniel J. Harrison , Shandralynn Joiner
CPC分类号： B41M5/38235 , B41M5/385 , B41M5/52 , B41M5/3854 , B41M5/39 , B41M5/5227 , B41M5/5254 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31786 , Y10T428/31855
摘要： A thermal dye transfer assemblage comprising:(I) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N--H group which is part of a conjugated system, and(II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture ofa) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; andb) an acidic material containing at least 0.0007 meq/m.sup.2 of acid; the a) and/or b) having incorporated therein a plasticizer containing:(i) at least the following groups in the order given:E--Q--X--A wherein Q is a carbonyl or sulfonyl;X is N or O;E is an aromatic ring; andA is an alkyl or oxyalky group having up to 5 consecutive carbon atoms; or(ii) a phosphate group having at least one aromatic ring attached thereto;said plasticizer being present in an amount of up to about 25 weight percent of the polymer.
摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有染料层的载体，所述染料层包含分散在聚合物粘合剂中的染料，所述染料是去质子化的阳离子染料，其能够被再赋色为阳离子染料， 作为共轭系统的一部分的NH基，和（II）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合染料影像接收层接触，聚合染料影像接收层包含a）Tg小于约19℃并且没有或仅有轻微酸度的聚合物的混合物; 和b）含有至少0.0007meq / m 2酸的酸性物质; a）和/或b）其中掺入增塑剂，其含有：（i）至少以下给出的顺序：E-Q-X-A其中Q是羰基或磺酰基; X为N或O; E是芳香环; 并且A是具有至多5个连续碳原子的烷基或氧代基; 或（ii）具有至少一个连接到其上的芳环的磷酸酯基; 所述增塑剂以聚合物的至多约25重量％的量存在。
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9.发明授权
公开(公告)号：US5942465A
公开(公告)日：1999-08-24
申请号：US035709
申请日：1998-03-05
IPC分类号： B41M5/382 , B41M5/00 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/42 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/38235 , B41M5/385 , B41M5/52 , B41M5/3854 , B41M5/388 , B41M5/39 , B41M5/5218 , B41M5/5254 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, said dye being:I) an electrically neutral, deprotonated, delocalized cationic dye precursor;II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a linking group, E represents a moiety with basic properties and m is an integer of 1-3; orIII) a cationic dye precursor having the following structure: ##STR1## and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a mixture ofi) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; andii) a polyester which has been polymerized in the presence of an aluminum salt and which contains an aluminum ion.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示连接基团，E表示具有碱性的部分，m为1-3的整数; 或III）具有以下结构的阳离子染料前体：和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料供体元件重叠关系 使得染料层与染料影像接收层接触，染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; 和ii）在铝盐存在下聚合并含有铝离子的聚酯。
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10.发明授权
公开(公告)号：US5939355A
公开(公告)日：1999-08-17
申请号：US47158
申请日：1998-03-24
IPC分类号： B32B27/36 , B41M5/00 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/38235 , B41M5/385 , B41M5/52 , B41M5/3854 , B41M5/388 , B41M5/39 , B41M5/5218 , B41M5/5254 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31786
摘要： A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, said dye being:I) an electrically neutral, deprotonated, delocalized cationic dye precursor;II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a linking group, E represents a moiety with basic properties and m is an integer of 1-3; orIII) a cationic dye precursor having the following structure: ##STR1## and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a mixture ofi) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity;ii) a sulfonated polyester; andiii) a hydrated transition metal or metalloid salt of a strong acid.
摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示连接基团，E表示具有碱性的部分，m为1-3的整数; 或III）具有以下结构的阳离子染料前体：和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料供体元件重叠关系 使得染料层与染料影像接收层接触，染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; ii）磺化聚酯; 和iii）强酸的水合过渡金属或准金属盐。
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