公开(公告)号：US06403821B1

公开(公告)日：2002-06-11

申请号：US09677179

申请日：2000-10-02

申请人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev

发明人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev

IPC分类号： C07C6996

CPC分类号： B01J31/2239 ,  B01J31/0235 ,  B01J31/2234 ,  B01J31/26 ,  B01J2231/321 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and a promoter compound which is at least one C2-8 aliphatic or C7-10 aromatic mono- or dinitrile, preferably acetonitrile or adiponitrile. The catalyst system also preferably contains a compound of a non-Group VIIIB metal, preferably lead.

摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种C 2-8脂族或C 7-10芳族单或二腈，优选乙腈或己二腈的促进剂化合物。 催化剂体系还优选含有非ⅧB族金属化合物，优选含铅。

公开(公告)号：US06265340B1

公开(公告)日：2001-07-24

申请号：US09699005

申请日：2000-10-30

申请人： Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Eric James Pressman

发明人： Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Eric James Pressman

IPC分类号： B01J3100

CPC分类号： B01J31/0222 ,  B01J31/2234 ,  B01J31/2239 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/44 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one sulfone such as sulfolane. The catalyst system also preferably contains a compound of another metal, preferably lead.

公开(公告)号：US06346499B1

公开(公告)日：2002-02-12

申请号：US09686741

申请日：2000-10-11

申请人： Bruce Fletcher Johnson ,  Grigorii Lev Soloveichik ,  Eric James Pressman ,  Kirill Vladimirovich Shalyaev

发明人： Bruce Fletcher Johnson ,  Grigorii Lev Soloveichik ,  Eric James Pressman ,  Kirill Vladimirovich Shalyaev

IPC分类号： B01J3100

CPC分类号： B01J31/2234 ,  B01J31/0247 ,  B01J31/2239 ,  B01J31/26 ,  B01J2531/16 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a metal from Groups 8-10 of the Periodic Table having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; at least one carboxylic acid amide such as N-methylpyrrolidone or dimethylacetamide; and a cocatalyst which is a compound of one or more metals including copper, titanium, zinc, lead, cerium and manganese.

摘要翻译： 羟基芳族化合物如苯酚在含有原子序数至少为44，优选钯的周期表第8-10族的金属的催化剂体系存在下，用氧和一氧化碳羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 至少一种羧酸酰胺如N-甲基吡咯烷酮或二甲基乙酰胺; 和作为一种或多种金属的化合物的助催化剂，包括铜，钛，锌，铅，铈和锰。

公开(公告)号：US06180812B2

公开(公告)日：2001-01-30

申请号：US09383426

申请日：1999-08-27

申请人： Bruce Fletcher Johnson ,  Grigorii Lev Soloveichik ,  Eric James Pressman ,  Kirill Vladimirovich Shalyaev

发明人： Bruce Fletcher Johnson ,  Grigorii Lev Soloveichik ,  Eric James Pressman ,  Kirill Vladimirovich Shalyaev

IPC分类号： C07C6800

CPC分类号： B01J31/2234 ,  B01J31/0247 ,  B01J31/2239 ,  B01J31/26 ,  B01J2531/16 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIII metal having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; at least one carboxylic acid amide such as N-methylpyrrolidone or dimethylacetamide; and a cocatalyst which is a compound of one or more metals including copper, titanium, zinc, lead, cerium and manganese.

摘要翻译： 在包含原子序数至少为44，优选钯的Ⅷ族金属的催化剂体系存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 至少一种羧酸酰胺如N-甲基吡咯烷酮或二甲基乙酰胺; 和作为一种或多种金属的化合物的助催化剂，包括铜，钛，锌，铅，铈和锰。

公开(公告)号：US6114564A

公开(公告)日：2000-09-05

申请号：US383425

申请日：1999-08-27

申请人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson

发明人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson

IPC分类号： B01J31/28 ,  B01J31/02 ,  B01J31/06 ,  B01J31/22 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

CPC分类号： B01J31/2239 ,  B01J31/0202 ,  B01J31/0204 ,  B01J31/068 ,  B01J31/2234 ,  C07C68/005 ,  B01J2531/824 ,  B01J31/0201

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIII metal having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one aliphatic polyether such as a polyethylene glycol dimethyl ether or a crown ether. The catalyst system also preferably contains a compound of another metal, preferably lead.

摘要翻译： 在包含原子序数至少为44，优选钯的Ⅷ族金属的催化剂体系存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种脂族聚醚如聚乙二醇二甲醚或冠醚。 催化剂体系还优选含有另一种金属的化合物，优选含有铅。

公开(公告)号：US06215014B1

公开(公告)日：2001-04-10

申请号：US09383424

申请日：1999-08-27

申请人： Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Eric James Pressman

发明人： Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Eric James Pressman

IPC分类号： C07C6800

CPC分类号： B01J31/0222 ,  B01J31/2234 ,  B01J31/2239 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/44 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one sulfone such as sulfolane. The catalyst system also preferably contains a compound of another metal, preferably lead.

摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种砜如环丁砜。 催化剂体系还优选含有另一种金属的化合物，优选含有铅。

公开(公告)号：US06172254B2

公开(公告)日：2001-01-09

申请号：US09345538

申请日：1999-06-30

申请人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev

发明人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Kirill Vladimirovich Shalyaev

IPC分类号： C07C6996

CPC分类号： B01J31/2239 ,  B01J31/0235 ,  B01J31/2234 ,  B01J31/26 ,  B01J2231/321 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and a promoter compound which is at least one C2-8 aliphatic or C7-10 aromatic mono- or dinitrile, preferably acetonitrile or adiponitrile. The catalyst system also preferably contains a compound of a non-Group VIIIB metal, preferably lead.

摘要翻译： 在含有VIIIB族金属，优选钯的催化剂体系的存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种C 2-8脂族或C 7-10芳族单或二腈，优选乙腈或己二腈的促进剂化合物。 催化剂体系还优选含有非ⅧB族金属的化合物，优选为铅。

公开(公告)号：US06346500B1

公开(公告)日：2002-02-12

申请号：US09578400

申请日：2000-05-26

申请人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson

发明人： Eric James Pressman ,  Grigorii Lev Soloveichik ,  Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson

IPC分类号： B01J3100

CPC分类号： B01J31/2239 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/0204 ,  B01J31/068 ,  B01J31/2234 ,  B01J2531/824 ,  C07C68/005 ,  C07C69/96

摘要： Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIII metal having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one aliphatic polyether such as a polyethylene glycol dimethyl ether or a crown ether. The catalyst system also preferably contains a compound of another metal, preferably lead.

摘要翻译： 在包含原子序数至少为44，优选钯的Ⅷ族金属的催化剂体系存在下，用氧和一氧化碳将羟基芳族化合物如苯酚羰基化; 碱金属或碱土金属卤化物，优选溴化钠; 和至少一种脂族聚醚如聚乙二醇二甲醚或冠醚。 催化剂体系还优选含有另一种金属的化合物，优选含有铅。

公开(公告)号：US06700008B2

公开(公告)日：2004-03-02

申请号：US10135723

申请日：2002-04-30

申请人： Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr. ,  Grigorii Lev Soloveichik

发明人： Kirill Vladimirovich Shalyaev ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr. ,  Grigorii Lev Soloveichik

IPC分类号： C07C6996

CPC分类号： B01J31/0239 ,  B01J21/063 ,  B01J23/14 ,  B01J23/44 ,  B01J23/72 ,  B01J31/0251 ,  B01J31/128 ,  B01J31/2234 ,  B01J31/26 ,  B01J2219/0004 ,  B01J2231/321 ,  B01J2531/16 ,  B01J2531/38 ,  B01J2531/46 ,  B01J2531/72 ,  B01J2531/824 ,  C07C51/252 ,  C07C51/44 ,  C07C51/48 ,  C07C68/005 ,  C07C69/96 ,  C07C57/04

摘要： A method and catalyst composition for economically producing aromatic carbonates from aromatic hydroxy compounds is disclosed. The present invention provides a method for carbonylating aromatic hydroxy compounds, comprising the step of contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a halide-free carbonylation catalyst composition comprising an effective amount of at least one Group 8, 9, or 10 metal source, an effective amount of a first inorganic co-catalyst comprising at least one Group 14 metal source, an effective amount of a salt co-catalyst, and optionally an effective amount of a second inorganic co-catalyst selected from the group consisting of a Group 4 metal source, a Group 7 metal source, a Group 11 metal source, and a lanthanide element source, and optionally an effective amount of a base. A significant advantage of the present method and catalyst compositions is that no halide is present or required in the reaction mixture for catalytic activity.

摘要翻译： 公开了一种用于从芳族羟基化合物经济地生产芳族碳酸酯的方法和催化剂组合物。 本发明提供了一种芳族羟基化合物的羰基化方法，包括使至少一种芳香族羟基化合物与氧和一氧化碳在不含卤化物的羰基化催化剂组合物存在下接触的步骤，该组合物包含有效量的至少一种第8族， 9或10个金属源，有效量的第一无机助催化剂，其包含至少一种第14族金属源，有效量的盐助催化剂和任选的有效量的第二无机助催化剂，其选自 由4族金属源，7族金属源，11族金属源和镧系元素源组成的组，以及任选的有效量的碱。 本发明方法和催化剂组合物的显着优点是在反应混合物中不存在或需要用于催化活性的卤化物。

公开(公告)号：US06207849B1

公开(公告)日：2001-03-27

申请号：US09495539

申请日：2000-01-31

申请人： Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr.

发明人： Kirill Vladimirovich Shalyaev ,  Grigorii Lev Soloveichik ,  Bruce Fletcher Johnson ,  Donald Wayne Whisenhunt, Jr.

IPC分类号： C07C6800

CPC分类号： C07C68/005 ,  C07C69/96

摘要： A method and catalyst system for producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the method includes the step of contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system having catalytic amounts of the following components: a Group VIII B metal source; a combination of inorganic co-catalysts including a copper source and at least one of a titanium source or a zirconium source; an onium chloride composition; and a base. Alternative embodiments include inorganic co-catalyst combinations of a lead source and at least one of a titanium source or a manganese source.