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公开(公告)号：US3972862A
公开(公告)日：1976-08-03
申请号：US490284
申请日：1974-07-22
IPC分类号： C08F4/00 , C08F4/60 , C08F36/00 , C08F236/00 , C08F236/06 , C08L7/00 , C08L21/00 , C08F4/64 , C08F4/66 , C08F236/20
CPC分类号： C08F236/06 , C08F10/00
摘要： Elastomeric copolymers of butadiene and piperylene containing at least 50 mole percent butadiene and having a random distribution of monomer units enchained in a stereo-regulated manner are characterized by, (1) vinyl unsaturation pendant to the main polymer chain which is equal to or less than 10 percent of the total unsaturation present in the polymer; (2) enchainment of at least 95 percent of the piperylene as the 1,2-trans and 1,4-trans-stereoisomers; and (3) selective enchainment of between 50 and 95 percent of the butadiene as the 1,4-trans-stereoisomer. The copolymers, which are prepared from a mixture of the monomers with the aid of an iodine-containing hydrocarbon-soluble catalyst system comprising TiX.sub.n -xMI.sub.n -yI.sub.2 -zAlR.sub.3 -QLB, can be compounded with other elastomers and with process oils, resins, plasticizers and reinforcing agents such as carbon black, silica, talc and the like. When vulcanized, the copolymers exhibit a high tensile strength, extension, modulus and abrasion resistance. They are particularly useful in automotive tire-tread compositions.
摘要翻译： 含有至少50摩尔百分数丁二烯和具有以立体调节方式链接的单体单元的无规分布的丁二烯和戊间二烯的弹性共聚物的特征在于：（1）垂饰于主聚合物链的乙烯基不饱和度等于或小于 聚合物中存在的总不饱和度的10％ （2）作为1,2-反式和1,4-反式立体异构体的至少95％的戊间二烯的连接; 和（3）作为1,4-反式立体异构体的丁二烯的选择性链接为50-95％。 由含有TiXn-xMIn-yI2-zAlR3-QLB的含碘烃可溶性催化剂体系由单体混合物制备的共聚物可以与其它弹性体和工艺油，树脂，增塑剂 和增强剂如炭黑，二氧化硅，滑石粉等。 当硫化时，共聚物显示出高抗拉强度，伸长率，模量和耐磨性。 它们在汽车轮胎胎面组合物中特别有用。
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公开(公告)号：US4201850A
公开(公告)日：1980-05-06
申请号：US931472
申请日：1978-08-07
IPC分类号： C08F236/06 , C08F4/64
CPC分类号： C08F236/06
摘要： Elastomeric copolymers of butadiene and piperylene containing at least 50 mole percent butadiene and having a random distribution of monomer units enchained in a stereo-regulated manner are characterized by, (1) vinyl unsaturation pendant to the main polymer chain which is equal to or less than 10 percent of the total unsaturation present in the polymer; (2) enchainment of at least 95 percent of the piperylene as the 1,2-trans and 1,4-trans-stereoisomers; and (3) selective enchainment of between 50 and 95 percent of the butadiene as the 1,4-trans-stereoisomer. The copolymers, which are prepared from a mixture of the monomers with the aid of an iodine-containing hydrocarbon-soluble catalyst system comprising TiX.sub.n --xMI.sub.n --yI.sub.2 --zAlR.sub.3 --QLB, can be compounded with other elastomers and with process oils, resins, plasticizers and reinforcing agents such as carbon black, silica, talc and the like. When vulcanized, the copolymers exhibit a high tensile strength, extension, modulus and abrasion resistance. They are particularly useful in automotive tire-tread compositions.
摘要翻译： 含有至少50摩尔百分数丁二烯和具有以立体调节方式链接的单体单元的无规分布的丁二烯和戊间二烯的弹性共聚物的特征在于：（1）垂饰于主聚合物链的乙烯基不饱和度等于或小于 聚合物中存在的总不饱和度的10％ （2）作为1,2-反式和1,4-反式立体异构体的至少95％的戊间二烯的连接; 和（3）作为1,4-反式立体异构体的丁二烯的选择性链接为50-95％。 由含有TiXn-xMIn-yI2-zAlR3-QLB的含碘烃可溶性催化剂体系由单体混合物制备的共聚物可以与其它弹性体和工艺油，树脂，增塑剂 和增强剂如炭黑，二氧化硅，滑石粉等。 当硫化时，共聚物显示出高抗拉强度，伸长率，模量和耐磨性。 它们在汽车轮胎胎面组合物中特别有用。
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3.发明授权Covulcanization of conjugated diene-containing butyl with halobutyl and butyl rubber 失效含有共轭二烯的丁基与卤代丁基和丁基橡胶的共硫化
公开(公告)号：US4014852A
公开(公告)日：1977-03-29
申请号：US562827
申请日：1975-03-28
CPC分类号： C08L23/22 , C08L23/283
摘要： Blends of 5 to 95 wt. % conjugated diene-containing butyl rubber with 95 to 5 wt. % halobutyl or butyl rubber are capable of higher carbon black loading and have faster cure times, unusually high tensile strength and improved green strength. The blends may be cured with dienophilic compounds or sulfur-based cure packages.
摘要翻译： 共混物为5至95wt。 ％共轭二烯的丁基橡胶与95〜5重量％ ％卤代丁基或丁基橡胶能够具有更高的炭黑负载量并且具有更快的固化时间，异常高的拉伸强度和改善的生坯强度。 共混物可以用二亲性化合物或硫基固化包装固化。
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4.发明授权Covulcanization of conjugated diene-containing butyl with halobutyl and butyl rubber 失效含有共轭二烯的丁基与卤代丁基和丁基橡胶的共硫化
公开(公告)号：US3968076A
公开(公告)日：1976-07-06
申请号：US582691
申请日：1975-06-02
CPC分类号： C08L23/22 , C08L23/283
摘要： Blends of 5 to 95 wt. % conjugated diene-containing butyl rubber with 95 to 5 wt. % halobutyl or butyl rubber are capable of higher carbon black loading and have faster cure times, unusually high tensile strength and improved green strength. The blends may be cured with dienophilic compounds or sulfur-based cure packages.
摘要翻译： 共混物为5至95wt。 ％共轭二烯的丁基橡胶与95〜5重量％ ％卤代丁基或丁基橡胶能够具有更高的炭黑负载量并且具有更快的固化时间，异常高的拉伸强度和改善的生坯强度。 共混物可以用二亲性化合物或硫基固化包装固化。
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公开(公告)号：US4132698A
公开(公告)日：1979-01-02
申请号：US770456
申请日：1977-02-22
CPC分类号： C08L23/02 , C08L23/16 , C08L53/02 , C08L91/00 , C08K5/01 , C08L2205/02 , C08L2207/04 , C08L23/10 , C08L23/12
摘要： Non-homogeneous, unvulcanized, paintable elastomeric thermoplastics suitable for use as injection molded automotive decorative and structural parts have been developed. These elastomeric thermoplastic compositions are comprised of a highly crystalline polyolefin, such as polypropylene, a noncrystalline or semicrystalline elastomer and a plasticizer such as a hydrocarbon oil.
摘要翻译： 已经开发了适合用作注塑汽车装饰和结构部件的非均匀的，未硫化的，可涂漆的弹性体热塑性塑料。 这些弹性体热塑性组合物由高结晶聚烯烃，如聚丙烯，非结晶或半结晶弹性体和增塑剂如烃油组成。
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6.发明授权Covulcanization of conjugated diene-containing butyl with halobutyl and butyl rubber 失效含有共轭二烯的丁基与卤代丁基和丁基橡胶的共硫化
公开(公告)号：US4039506A
公开(公告)日：1977-08-02
申请号：US562828
申请日：1975-03-28
CPC分类号： C08L23/22 , C08L23/283
摘要： Blends of 5 to 95 wt. % conjugated diene-containing butyl rubber with 95 to 25 wt. % halobutyl or butyl rubber are capable of higher carbon black loading and have faster cure times, unusually high tensile strength and improved green strength. The blends may be cured with dienophilic compounds or sulfur-based cure packages.
摘要翻译： 共混物为5至95wt。 ％共轭二烯的丁基橡胶，95〜25wt。 ％卤代丁基或丁基橡胶能够具有更高的炭黑负载量并且具有更快的固化时间，异常高的拉伸强度和改善的生坯强度。 共混物可以用二亲性化合物或硫基固化包装固化。
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