公开(公告)号：US11597889B2

公开(公告)日：2023-03-07

申请号：US17119096

申请日：2020-12-11

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Deyaa I. AbuSalim ,  Eugine Choi ,  Kun Wang ,  Himanshu Gupta ,  Dongil Kang ,  Jung Park ,  Jonathan E. Mitchell

IPC: C10L10/10 ,  C07C407/00 ,  C10L1/04 ,  C07C2/86 ,  C07C29/48 ,  C10G29/20 ,  C10G50/00

Abstract: A process for converting light paraffins and/or light hydrocarbons to a high octane gasoline composition is disclosed. The process involves: (1) oxidation of iso-paraffins to alkyl hydroperoxides and alcohol; (2) conversion of the alkyl hydroperoxides and alcohol to dialkyl peroxides; and (3) radical coupling of one or more iso-paraffins and/or iso-hydrocarbons using the dialkyl peroxides as radical initiators, thereby forming a gasoline composition comprising gasoline-range molecules including a C7 enriched gasoline composition having a road octane number (RON) greater than 100.