公开(公告)号：US20130184361A1

公开(公告)日：2013-07-18

申请号：US13812701

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

发明人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

IPC分类号： C07C1/04

CPC分类号： C07C1/0445 ,  B01J21/005 ,  B01J21/04 ,  B01J21/12 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J31/065 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0226 ,  B01J37/12 ,  B01J2231/641 ,  B01J2231/648 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/74 ,  C07C2523/75 ,  C07C2531/02 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C07C9/14

摘要： C5+ hydrocarbon synthesis by contracting a synthesis gas with a catalyst naming at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process of at least: i) contracting at least the support with at least one solution containing at least one precursor of metal from group VIII; ii) contracting at least the support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) at least one calcining to obtain at least the metal from group VIII in the oxide form; i) and ii) being carried out separately, in any order, or simultaneously.

摘要翻译： C5 +烃合成通过用催化剂收缩合成气，催化剂命名至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，所述催化剂使用以下方法制备，所述方法至少包括：i）至少在载体上收缩载体 含有至少一种来自VIII族金属的前体的至少一种溶液; ii）至少由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖形成的有机化合物至少包含载体; iii）至少一种煅烧以至少获得氧化物形式的VIII族金属; i）和ii）以任何顺序或同时单独进行。

公开(公告)号：US08618182B2

公开(公告)日：2013-12-31

申请号：US13812701

申请日：2011-06-24

申请人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

发明人： Fabrice Diehl ,  Anne Griboval-Constant ,  Andrei Khodakov ,  Alan Jean-Marie ,  Eric Monflier

IPC分类号： C07C27/00

CPC分类号： C07C1/0445 ,  B01J21/005 ,  B01J21/04 ,  B01J21/12 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J31/065 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0226 ,  B01J37/12 ,  B01J2231/641 ,  B01J2231/648 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/10 ,  C07C2523/74 ,  C07C2523/75 ,  C07C2531/02 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333 ,  C07C9/14

摘要： C5+ hydrocarbon synthesis by contracting a synthesis gas with a catalyst naming at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process of at least: i) contracting at least the support with at least one solution containing at least one precursor of metal from group VIII; ii) contracting at least the support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) at least one calcining to obtain at least the metal from group VIII in the oxide form; i) and ii) being carried out separately, in any order, or simultaneously.

摘要翻译： C5 +烃合成通过用催化剂收缩合成气，催化剂命名至少一种沉积在由至少一种氧化物形成的载体上的VIII族金属，所述催化剂使用以下方法制备，所述方法至少包括：i）至少在载体上收缩载体 含有至少一种来自VIII族金属的前体的至少一种溶液; ii）至少由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖形成的有机化合物至少包含载体; iii）至少一种煅烧以至少获得氧化物形式的VIII族金属; i）和ii）以任何顺序或同时单独进行。

公开(公告)号：US06710011B2

公开(公告)日：2004-03-23

申请号：US10036866

申请日：2001-12-21

申请人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni ,  Andrei Khodakov

发明人： Edouard A. Mamedov ,  Kathleen A. Bethke ,  Shahid N. Shaikh ,  Armando Araujo ,  Neeta K. Kulkarni ,  Andrei Khodakov

IPC分类号： B01J2320

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/31 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/32 ,  B01J2523/33 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/69 ,  B01J2523/35 ,  B01J2523/305 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/36 ,  B01J2523/47 ,  B01J2523/13 ,  B01J2523/67 ,  B01J2523/57 ,  B01J2523/68 ,  B01J2523/54 ,  B01J2523/56 ,  B01J2523/43 ,  B01J2523/49 ,  B01J2523/17 ,  B01J2523/3712 ,  B01J2523/27 ,  B01J2523/845 ,  B01J2523/842 ,  B01J2523/24 ,  B01J2523/74 ,  B01J2523/28 ,  B01J2523/12 ,  B01J2523/25 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/72

摘要： A catalyst composition for the vapor phase ammoxidation of alkanes and olefins of the general empirical formulae: VSbaMbOx VSbaMbM′b′Ox VSbaMbQcOx VSbaMbQcQ′c′Ox wherein M and M′ are at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, M and M′ being different, Q and Q′ are at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, Q and Q′ being different, a is 0.5 to 20, b is 2 to 50, b′ is 0 to 50, c is 0 to 10, c′ is 0 to 10 and x is determined by the valence requirements of the elements present. The catalyst composition containing isolated vanadium and antimony species in an inert matrix is prepared by incorporating respective compounds of vanadium and antimony into the oxide of at least one or more M and adding by co-precipitation or impregnation one or more optional Q in the relative atomic proportions indicated by the subscripts.

摘要翻译： 用于烷烃和烯烃的气相氨氧化的催化剂组合物的一般经验式：其中M和M'是选自镁，铝，锆，硅，铪，钛和铌中的至少一种元素，M和M'是不同的 Q，Q'为选自铼，钨，钼，钽，锰，磷，铈，锡，硼，钪，铋，镓，铟，铁，铬，镧，钇， 镍，镉，铜，锶，钡，钙，银，钾，钠和铯，Q和Q'不同，a为0.5至20，b为2至50，b'为0至50，c为0至 10，c'为0至10，x由所存在的元素的化合价要求确定。 在惰性基质中含有分离的钒和锑物质的催化剂组合物是通过将各种化合物的钒和锑引入到至少一个或多个M的氧化物中并通过共沉淀或浸渍加入相对原子中的一个或多个任选Q来制备的 比例由下标表示。