公开(公告)号：US20130224493A1

公开(公告)日：2013-08-29

申请号：US13810847

申请日：2011-07-07

申请人： Falk Gabel ,  Otmar Becker ,  Michael Glasenapp ,  Jan-Peter Ortmann ,  Petra Grewer ,  Veit Luther ,  Harald Striegler ,  Dietmar Wennemann ,  Thomas Schuler ,  Thoralf Johansson ,  Helga Goetz ,  Michael Bug ,  Guenther Benhaar ,  Gerhard Hahn ,  Friedrich-Georg Schroeder

发明人： Falk Gabel ,  Otmar Becker ,  Michael Glasenapp ,  Jan-Peter Ortmann ,  Petra Grewer ,  Veit Luther ,  Harald Striegler ,  Dietmar Wennemann ,  Thomas Schuler ,  Thoralf Johansson ,  Helga Goetz ,  Michael Bug ,  Guenther Benhaar ,  Gerhard Hahn ,  Friedrich-Georg Schroeder

IPC分类号： C03B32/02 ,  C03C10/00

CPC分类号： C03B32/02 ,  C03C10/0027 ,  C03C10/0036 ,  Y02P40/57 ,  Y10T428/315

摘要： A lithium-containing, transparent glass-ceramic material is provided. The material has low thermal expansion and has an amorphous, lithium-depleted, vitreous surface zone. The zone is at least 50 nm thick on all sides and encloses a crystalline interior, which has high transmission. The material includes a transition region connecting the zone and the interior.

摘要翻译： 提供含锂透明玻璃陶瓷材料。 该材料具有低热膨胀性，并具有无定形，贫锂，玻璃质表面区域。 该区域在所有侧面上至少为50nm厚，并且包围结晶内部，其具有高透射率。 该材料包括连接该区域和内部的过渡区域。

公开(公告)号：US09249045B2

公开(公告)日：2016-02-02

申请号：US13810847

申请日：2011-07-07

申请人： Falk Gabel ,  Otmar Becker ,  Michael Glasenapp ,  Jan-Peter Ortmann ,  Petra Grewer ,  Veit Luther ,  Harald Striegler ,  Dietmar Wennemann ,  Thomas Schuler ,  Thoralf Johansson ,  Helga Goetz ,  Michael Bug ,  Guenther Siebenhaar ,  Gerhard Hahn ,  Friedrich-Georg Schroeder

发明人： Falk Gabel ,  Otmar Becker ,  Michael Glasenapp ,  Jan-Peter Ortmann ,  Petra Grewer ,  Veit Luther ,  Harald Striegler ,  Dietmar Wennemann ,  Thomas Schuler ,  Thoralf Johansson ,  Helga Goetz ,  Michael Bug ,  Guenther Siebenhaar ,  Gerhard Hahn ,  Friedrich-Georg Schroeder

IPC分类号： C03B32/02 ,  C03C10/00

CPC分类号： C03B32/02 ,  C03C10/0027 ,  C03C10/0036 ,  Y02P40/57 ,  Y10T428/315

摘要： A lithium-containing, transparent glass-ceramic material is provided. The material has low thermal expansion and has an amorphous, lithium-depleted, vitreous surface zone. The zone is at least 50 nm thick on all sides and encloses a crystalline interior, which has high transmission. The material includes a transition region connecting the zone and the interior.

摘要翻译： 提供含锂透明玻璃陶瓷材料。 该材料具有低热膨胀性，并具有无定形，贫锂，玻璃质表面区域。 该区域在所有侧面上至少为50nm厚，并且包围结晶内部，其具有高透射率。 该材料包括连接该区域和内部的过渡区域。

公开(公告)号：US20080199622A1

公开(公告)日：2008-08-21

申请号：US12026262

申请日：2008-02-05

申请人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

发明人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

IPC分类号： B05D3/02

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/475 ,  C03C2217/485 ,  C03C2218/113 ,  C03C2218/32 ,  F24C15/10

摘要： A transparent, colorless glass or glass-ceramic panel has a visually dense, high-temperature-stable coating having an organic/inorganic network structure containing filling material particles and a color-imparting pigment. The mechanically stable, visually dense coating has no melt-reaction zone at the surface of the panel, which is coated with the coating, so that it does not impair the panel strength. The inorganic network structure can be made from a SiO2-based sol. The coating is made by introducing the color-imparting pigment and the filling material particles into a reactive organic/inorganic network structure; applying the resulting organic/inorganic network structure containing the pigment and the filling material particles to the panel to coat the panel and then burning-in the organic/inorganic network structure with the pigment and the filling material particles under thermal conditions to form the coating with no melt-reaction zone.

摘要翻译： 透明无色的玻璃或玻璃陶瓷面板具有视觉密实的高温稳定涂层，其具有含有填充材料颗粒和赋颜色颜料的有机/无机网状结构。 机械稳定的，目视密实的涂层在面板的表面没有熔融反应区，涂覆有涂层，从而不会损害面板强度。 无机网状结构可以由SiO 2基的溶胶制成。 通过将着色颜料和填充材料颗粒引入反应性有机/无机网络结构中来制备涂层; 将所得的含有颜料和填充材料颗粒的有机/无机网络结构施加到面板上以涂覆面板，然后在有机/无机网状结构中用颜料和填充材料颗粒在热条件下燃烧以形成具有 无熔融反应区。

公开(公告)号：US07361405B2

公开(公告)日：2008-04-22

申请号：US10993741

申请日：2004-11-19

申请人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

发明人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

IPC分类号： B32B17/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/475 ,  C03C2217/485 ,  C03C2218/113 ,  C03C2218/32

摘要： A transparent, colorless glass or glass-ceramic panel has a visually dense, high-temperature-stable coating having an organic/inorganic network structure containing filling material particles and a color-imparting pigment. The mechanically stable, visually dense coating has no melt-reaction zone at the surface of the panel, which is coated with the coating, so that it does not impair the panel strength. The inorganic network structure can be made from a SiO2-based sol. The coating is made by introducing the color-imparting pigment and the filling material particles into a reactive organic/inorganic network structure; applying the resulting organic/inorganic network structure containing the pigment and the filling material particles to the panel to coat the panel and then burning-in the organic/inorganic network structure with the pigment and the filling material particles under thermal conditions to form the coating with no melt-reaction zone.

摘要翻译： 透明无色的玻璃或玻璃陶瓷面板具有视觉密实的高温稳定涂层，其具有含有填充材料颗粒和赋颜色颜料的有机/无机网状结构。 机械稳定的，目视密实的涂层在面板的表面没有熔融反应区，涂覆有涂层，从而不会损害面板强度。 无机网状结构可以由SiO 2基的溶胶制成。 通过将着色颜料和填充材料颗粒引入反应性有机/无机网络结构中来制备涂层; 将所得的含有颜料和填充材料颗粒的有机/无机网络结构施加到面板上以涂覆面板，然后在有机/无机网络结构中用颜料和填充材料颗粒在热条件下燃烧以形成涂层 无熔融反应区。

公开(公告)号：US20050129959A1

公开(公告)日：2005-06-16

申请号：US10993741

申请日：2004-11-19

申请人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

发明人： Gabriele Roemer-Scheuermann ,  Andrea Anton ,  Harald Striegler ,  Thomas Kraus ,  Gerhard Weber ,  Lutz Klippe ,  Veit Luther ,  Petra Grewer

IPC分类号： F24C15/10 ,  C03C17/00 ,  C03C17/25 ,  B32B17/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/475 ,  C03C2217/485 ,  C03C2218/113 ,  C03C2218/32

摘要： A transparent, colorless glass or glass-ceramic panel has a visually dense, high-temperature-stable coating having an organic/inorganic network structure containing filling material particles and a color-imparting pigment. The mechanically stable, visually dense coating has no melt-reaction zone at the surface of the panel, which is coated with the coating, so that it does not impair the panel strength. The inorganic network structure can be made from a SiO2-based sol. The coating is made by introducing the color-imparting pigment and the filling material particles into a reactive organic/inorganic network structure; applying the resulting organic/inorganic network structure containing the pigment and the filling material particles to the panel to coat the panel and then burning-in the organic/inorganic network structure with the pigment and the filling material particles under thermal conditions to form the coating with no melt-reaction zone.

摘要翻译： 透明无色的玻璃或玻璃陶瓷面板具有视觉密实的高温稳定涂层，其具有含有填充材料颗粒和赋颜色颜料的有机/无机网状结构。 机械稳定的，目视密实的涂层在面板的表面没有熔融反应区，涂覆有涂层，从而不会损害面板强度。 无机网状结构可以由SiO 2基的溶胶制成。 通过将着色颜料和填充材料颗粒引入反应性有机/无机网络结构中来制备涂层; 将所得的含有颜料和填充材料颗粒的有机/无机网络结构施加到面板上以涂覆面板，然后在有机/无机网状结构中用颜料和填充材料颗粒在热条件下燃烧以形成具有 无熔融反应区。

公开(公告)号：US20100130342A1

公开(公告)日：2010-05-27

申请号：US12540881

申请日：2009-08-13

申请人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schönberger ,  Petra Grewer ,  Erich Rodek

发明人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schönberger ,  Petra Grewer ,  Erich Rodek

IPC分类号： C03C10/12

CPC分类号： C03C3/095 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054

摘要： A transparent, colorless lithium-aluminosilicate glass ceramic plate with high-quartz mixed crystals as the prevailing crystal phase, which is provided on one side with an opaque, colored, temperature-stable coating over the entire surface or over the entire surface to a large extent, is described, which has a content of Nd2O3 of 40 to 4000 ppm, a Yellowness Index of less than 10% with a 4 mm glass (ceramic) layer thickness, and a variegation of colors of the glass or the glass ceramic in the CIELAB color system of C* of less than 5. The glass ceramic plate preferably has a composition (in % by weight based on oxide) of: Li2O 3.0-4.5, Na2O 0-1.5, K2O 0-1.5, ΣNa2O+K2O 0.2-2.0, MgO 0-2.0, CaO 0-1.5, SrO 0-1.5, BaO 0-2.5, ZnO 0-2.5, B2O3 0-1.0, Al2O3 19-25, SiO2 55-69, TiO2 1-3, ZrO2 1-2.5, SnO2 0-0.4, ΣSnO2+TiO2

摘要翻译： 一种透明，无色的铝硅铝酸盐玻璃陶瓷板，其具有高石英混晶作为主要晶相，其一面在整个表面或整个表面上设置为不透明，着色，温度稳定的涂层至大面积 描述了其具有40至4000ppm的Nd2O3含量，具有4mm玻璃（陶瓷）层厚度的小于10％的黄度指数，以及玻璃或玻璃陶瓷的颜色的变化 C *的CIELAB色系小于5.玻璃陶瓷板的组成（以氧化物重量计）为：Li2O 3.0-4.5，Na2O 0-1.5，K2O 0-1.5，Na2O + K2O 0.2-2.0，MgO 0-2.0，CaO 0-1.5，SrO 0-1.5，BaO 0-2.5，ZnO 0-2.5，B 2 O 3 0-1.0，Al 2 O 3 19-25，SiO 2 55-69，TiO 2 1-3，ZrO 2 1-2.5，SnO2 0-0.4，＆lt; SnO2 + TiO2 <3，P2O5 0-3.0，Nd2O3 0.01-0.4，CoO 0.0-0.004

公开(公告)号：US07981823B2

公开(公告)日：2011-07-19

申请号：US12540881

申请日：2009-08-13

申请人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schönberger ,  Petra Grewer ,  Erich Rodek

发明人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schönberger ,  Petra Grewer ,  Erich Rodek

IPC分类号： C03C10/12 ,  C03C10/14 ,  C03C3/095 ,  C03C3/083 ,  B32B17/06 ,  B32B15/00

CPC分类号： C03C3/095 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054

摘要： A transparent, colorless lithium-aluminosilicate glass ceramic plate with high-quartz mixed crystals as the prevailing crystal phase, which is provided on one side with an opaque, colored, temperature-stable coating over the entire surface or over the entire surface to a large extent, is described, which has a content of Nd2O3 of 40 to 4000 ppm, a Yellowness Index of less than 10% with a 4 mm glass (ceramic) layer thickness, and a variegation of colors of the glass or the glass ceramic in the CIELAB color system of C* of less than 5. The glass ceramic plate preferably has a composition (in % by weight based on oxide) of: Li2O 3.0-4.5, Na2O 0-1.5, K2O 0-1.5, ΣNa2O+K2O 0.2-2.0, MgO 0-2.0, CaO 0-1.5, SrO 0-1.5, BaO 0-2.5, ZnO 0-2.5, B2O3 0-1.0, Al2O3 19-25, SiO2 55-69, TiO2 1-3, ZrO2 1-2.5, SnO2 0-0.4, ΣSnO2+TiO2

摘要翻译： 一种透明，无色的铝硅铝酸盐玻璃陶瓷板，其具有高石英混晶作为主要晶相，其一面在整个表面或整个表面上设置为不透明，着色，温度稳定的涂层至大面积 描述了其具有40至4000ppm的Nd2O3含量，具有4mm玻璃（陶瓷）层厚度的小于10％的黄度指数，以及玻璃或玻璃陶瓷的颜色的变化 C *的CIELAB色系小于5.玻璃陶瓷板的组成（以氧化物重量计）为：Li2O 3.0-4.5，Na2O 0-1.5，K2O 0-1.5，Na2O + K2O 0.2-2.0，MgO 0-2.0，CaO 0-1.5，SrO 0-1.5，BaO 0-2.5，ZnO 0-2.5，B 2 O 3 0-1.0，Al 2 O 3 19-25，SiO 2 55-69，TiO 2 1-3，ZrO 2 1-2.5，SnO2 0-0.4，＆lt; SnO2 + TiO2 <3，P2O5 0-3.0，Nd2O3 0.01-0.4，CoO 0.0-0.004。

公开(公告)号：US20070232476A1

公开(公告)日：2007-10-04

申请号：US11688099

申请日：2007-03-19

申请人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schonberger ,  Petra Grewer ,  Erich Rodek

发明人： Friedrich Siebers ,  Ulrich Schiffner ,  Wolfgang Schmidbauer ,  Klaus Schonberger ,  Petra Grewer ,  Erich Rodek

IPC分类号： C03C10/14 ,  C03C10/12

CPC分类号： C03C3/095 ,  C03C10/0027 ,  C03C10/0045 ,  C03C10/0054

摘要： A transparent, colorless lithium-aluminosilicate glass ceramic plate with high-quartz mixed crystals as the prevailing crystal phase, which is provided on one side with an opaque, colored, temperature-stable coating over the entire surface or over the entire surface to a large extent, is described, which has a content of Nd2O3 of 40 to 4000 ppm, a Yellowness Index of less than 10% with a 4 mm glass (ceramic) layer thickness, and a variegation of colors of the glass or the glass ceramic in the CIELAB color system of C* of less than 5. The glass ceramic plate preferably has a composition (in % by weight based on oxide) of: Li2O 3.0-4.5, Na2O 0-1.5, K2O 0-1.5, ΣNa2O+K2O 0.2-2.0, MgO 0-2.0, CaO 0-1.5, SrO 0-1.5, BaO 0-2.5, ZnO 0-2.5, B2O3 0-1.0, Al2O3 19-25, SiO2 55-69, TiO2 1-3, ZrO2 1-2.5, SnO2 0-0.4, ΣSnO2+TiO2

摘要翻译： 一种透明，无色的铝硅铝酸盐玻璃陶瓷板，其具有高石英混晶作为主要晶相，其一面在整个表面或整个表面上设置为不透明，着色，温度稳定的涂层至大面积 描述了其具有40至4000ppm的Nd 2 O 3 3含量，使用4mm玻璃（陶瓷）的黄度指数小于10％的范围， 层厚度以及C *小于5的CIELAB色系中的玻璃或玻璃陶瓷的颜色的变化。玻璃陶瓷板优选具有以下成分（以氧化物计的重量％）：Li _{2 O 3.0-4.5，Na 2 O 0-1.5，K 2 O 0-1.5，SigmaNa 2 O + K 2 O 0.2-2.0，MgO 0-2.0，CaO 0-1.5，SrO 0-1.5，BaO 0-2.5，ZnO 0-2.5，B 2 O， 0> 3 0-1.0，Al 2 O 3 19-25，SiO 2 55-69，TiO 2， 2 1-3，ZrO 2 1-2.5，SnO 2 0-0.4，SigmaSnO 2， + TiO 2 <3，P O 0-3.0，Nd 2 O 3， /SUB>0.01-0.4，CoO 0.0-0.004}