公开(公告)号：US4511736A

公开(公告)日：1985-04-16

申请号：US456383

申请日：1983-01-07

申请人： Ferenc Mogyorodi ,  Eniko Koppany ,  Tibor Bodi ,  Karoly Balogh ,  Istvan Toth ,  Rezso Bognar ,  Sandor Makleit ,  Gyorgy Litkei ,  Miklos Rakosi ,  Zoltan Dinya

发明人： Ferenc Mogyorodi ,  Eniko Koppany ,  Tibor Bodi ,  Karoly Balogh ,  Istvan Toth ,  Rezso Bognar ,  Sandor Makleit ,  Gyorgy Litkei ,  Miklos Rakosi ,  Zoltan Dinya

IPC分类号： C07C233/07 ,  A01N20060101 ,  A01N37/28 ,  C07C20060101 ,  C07C102/00 ,  C07C102/06

CPC分类号： C07C231/02 ,  A01N37/22

摘要： The invention relates to a novel process for preparing chloroacetanilides of the formula ##STR1## wherein: R.sub.1 and R.sub.2 represent independently from each other a hydrogen atom or a C.sub.1-8 alkyl or C.sub.1-8 alkoxy group; andR.sub.3 stands for a straight chained or branched C.sub.1-8 alkoxy group.Said process is characterized by chloroacetylating a 2,6-dialkylaniline of the formula ##STR2## wherein R.sub.1 and R.sub.2 are as defined above, at a temperature of 10.degree. to 120.degree. C., optionally in a solvent medium in the presence of an acid binding agent, then reacting a thus-obtained intermediate with chloromethyl chloroformiate or, alternatively, reacting a compound of the formula (II) first with chloromethyl chloroformiate and subjecting then to chloroacetylation, thereafter reacting a thus-obtained intermediate with an alcohol of the formulaR.sub.3 --OH (III),wherein R.sub.3 is as defined above, optionally in a solvent medium in the presence of an acid binding agent, and recovering a product of the formula (I) in a known manner.The process of the invention enables the more simple and economic preparation of the compounds of formula (I) of improved purity.

摘要翻译： 本发明涉及一种制备式（I）的氯乙酰苯胺的新方法，其中：R1和R2彼此独立地表示氢原子或C1-8烷基或C1-8烷氧基; R3代表直链或支链C 1-8烷氧基。 所述方法的特征在于在10℃至120℃的温度下，任选在存在的溶剂介质中氯代乙酰化式（II）的2,6-二烷基苯胺，其中R 1和R 2如上定义 然后使由此获得的中间体与氯甲基氯甲酸酯反应，或者使式（II）的化合物首先与氯甲酸氯甲酯反应，然后进行氯乙酰化，然后使由此得到的中间体与醇的醇反应 任选地在酸性结合剂存在下在溶剂介质中，以已知方式回收式（I）的产物，其中R3如上所定义的式R3-OH（III）。 本发明的方法使得可以更简单和经济地制备具有改进纯度的式（I）化合物。

公开(公告)号：US4804405A

公开(公告)日：1989-02-14

申请号：US787912

申请日：1985-10-16

申请人： Ferenc Bajusz ,  Karoly Balogh ,  Tibor Bodi ,  Barna Bordas ,  Zsolt Dombay ,  Gyongyver Fodor nee Balogh ,  Erzsebet Grega nee Toth ,  Pal Gribovszki ,  Erno Lorik ,  Gyorgy Matolcsy ,  Judit Matyas nee David ,  Erzsebet Mile ,  Jozsef Nagy ,  Csaba Pavliscsak ,  Gyula Tarpai ,  Andras Toth ,  Istvan Toth ,  Maria Toth nee Takacs ,  Marton Tuske

发明人： Ferenc Bajusz ,  Karoly Balogh ,  Tibor Bodi ,  Barna Bordas ,  Zsolt Dombay ,  Gyongyver Fodor nee Balogh ,  Erzsebet Grega nee Toth ,  Pal Gribovszki ,  Erno Lorik ,  Gyorgy Matolcsy ,  Judit Matyas nee David ,  Erzsebet Mile ,  Jozsef Nagy ,  Csaba Pavliscsak ,  Gyula Tarpai ,  Andras Toth ,  Istvan Toth ,  Maria Toth nee Takacs ,  Marton Tuske

IPC分类号： A01N37/30 ,  A01N25/22 ,  A01N25/32

CPC分类号： A01N25/22 ,  A01N25/32

摘要： The invention relates to compositions useful for prolonging the action and increasing the selectivity of herbicide compositions containing .alpha.-chloroacetamide derivatives as active ingredient as well as to highly selective herbicide compositions containing .alpha.-chloroacetamide derivatives as active ingredients and optionally an antidote wherein an animal derivative of the general formula (III) is used for achieving the prolonged action and increased selectivity. In the formula (III) ##STR1## R.sub.5, R.sub.6, R.sub.7 and R.sub.8 stand independently for hydrogen, a C.sub.1-6 alkyl, C.sub.3-7 cycloalkyl or C.sub.2-5 alkenyl group optionally substituted by a C.sub.1-4 alkyl group; andR.sub.9 stands for hydrogen or a C.sub.1-4 alkyl group optionally substituted by halogen, or a phenyl group.

摘要翻译： 本发明涉及用于延长作用并增加含有α-氯乙酰胺衍生物作为活性成分的除草剂组合物的作用和增加选择性的组合物，以及含有α-氯乙酰胺衍生物作为活性成分和任选的解毒剂的高选择性除草剂组合物，其中， 通式（III）用于实现延长的作用和增加的选择性。 式（III）中，R5，R6，R7和R8分别独立地表示氢，C1-6烷基，C3-7环烷基或任意被C 1-4烷基取代的C 2-5烯基; 和R9代表氢或任选被卤素或苯基取代的C 1-4烷基。

公开(公告)号：US4787933A

公开(公告)日：1988-11-29

申请号：US65265

申请日：1987-06-22

申请人： Katalin Gorog nee Privitzer ,  Maria Kocsis nee Bagyi ,  Gyorgy Orosz ,  Tamas Torok ,  Istvan Laszlo ,  Laszlo Kondar ,  Istvan Toth ,  Karoly Balogh ,  Tibor Bodi ,  Erzsebet Grega nee Toth ,  Zsolt Dombay ,  Jozsef Nagy ,  Csaba Pavliscsak

发明人： Katalin Gorog nee Privitzer ,  Maria Kocsis nee Bagyi ,  Gyorgy Orosz ,  Tamas Torok ,  Istvan Laszlo ,  Laszlo Kondar ,  Istvan Toth ,  Karoly Balogh ,  Tibor Bodi ,  Erzsebet Grega nee Toth ,  Zsolt Dombay ,  Jozsef Nagy ,  Csaba Pavliscsak

IPC分类号： A01N25/32 ,  A01N37/34 ,  A01N47/30 ,  A01P13/00

CPC分类号： A01N25/32

摘要： The invention relates to a herbicide composition comprising as herbicidally active ingredient an urea derivative and/or a thiolcargamate derivative and/or a chloroacetanilide derivative together with a nitrile derivative of the general formula (I), ##STR1## wherein R.sub.1 and R.sub.2 which are the same or different, stand for hydroger, halogen or a methyl, ethyl, allyl, vinyl, phenyl or benzyl group; orR.sub.1 and R.sub.2 together may stand for a benzylidene group; andR.sub.3 means chlorine or a methyl, phenyl, chlorophenyl, alkoxyphenyl, chlorophenylamino, anilino, anilinomethylene, N-alkylanilinomethylene, N,N-dialkylanilinomethylene, alkoxyanilinomethylene, benzylaminomethylene, cyclohexylaminomethylene, N-alkyl-cyclohexylaminomethylene, hexamethyleniminomethylene, phthalimidomethylene, nitrophthalimidomethylene, morpholinomethylene, piperidinomethylene, C.sub.1-3 alkylaminomethylene, allylaminomethylene or di(C.sub.1-3 alkyl)aminorethylene groupand/or together with a cyanopyridine and/or with a benzonitrile derivative optionally mono- or polysubstituted by halogen(s) or C.sub.1-3 alkoxy group(s) as antidote(s) in a mass ratio from 40:1 to 1:1 of the herbicidally active ingredient to the antidote nitrile derivative.

摘要翻译： 本发明涉及一种除草剂组合物，其包含作为除草活性成分的尿素衍生物和/或硫氰酸酯衍生物和/或氯代乙酰苯胺衍生物以及通式（I）的腈衍生物，其中R1和R2 氢原子，卤素或甲基，乙基，烯丙基，乙烯基，苯基或苄基;它们相同或不同。 或者R 1和R 2可以一起代表亚苄基; 并且R 3表示氯或甲基，苯基，氯苯基，烷氧基苯基，氯苯基氨基，苯胺基，苯胺基亚甲基，N-烷基苯胺基亚甲基，N，N-二烷基苯胺基亚甲基，烷氧基亚氨基亚甲基，苄基亚氨基亚甲基，环己基氨基亚甲基，N-烷基 - 环己基亚氨基亚甲基，六亚甲基亚氨基亚甲基，邻苯二甲酰亚胺亚甲基，硝基邻苯二甲酰亚甲基，吗啉代亚甲基， 哌啶亚甲基，C 1-3烷基氨基亚甲基，烯丙基氨基亚甲基或二（C 1-3烷基）氨基亚乙基和/或与氰基吡啶和/或与任选被卤素或C 1-3烷氧基单取代或多取代的苄腈衍生物一起作为 解毒剂与除草剂腈衍生物的除草活性成分的质量比为40:1-1:1。

公开(公告)号：US4620871A

公开(公告)日：1986-11-04

申请号：US301822

申请日：1981-09-11

申请人： Erzsebet Grega nee Toth ,  Eniko Koppany ,  Tibor Bodi ,  Jozsef Nagy ,  Zsolt Dombay ,  Tibor Szarvas ,  Laszlo Horvath ,  Ildiko Szabo nee Muranyi ,  Jozsef Marton ,  Bela Pozsar ,  Sandor Viranyi ,  Peter Simon ,  Jozsef Keseru ,  Jozsef Eifert

发明人： Erzsebet Grega nee Toth ,  Eniko Koppany ,  Tibor Bodi ,  Jozsef Nagy ,  Zsolt Dombay ,  Tibor Szarvas ,  Laszlo Horvath ,  Ildiko Szabo nee Muranyi ,  Jozsef Marton ,  Bela Pozsar ,  Sandor Viranyi ,  Peter Simon ,  Jozsef Keseru ,  Jozsef Eifert

IPC分类号： A01N43/50 ,  A01N43/52 ,  A01N43/58 ,  C07D235/06 ,  C07D237/32

CPC分类号： C07D235/06 ,  A01N43/50 ,  A01N43/52 ,  A01N43/58 ,  C07D237/32

摘要： The invention relates to new compositions which contain 0.5 to 90% by weight of a phthalazine derivative having the general formula (I), ##STR1## wherein R.sub.1 stands for hydrogen, halogen, a straight-chained or branched C.sub.1-4 alkyl group having optionally a chlorine or hydroxy substituent, a C.sub.2-4 alkenyl group, or an optionally alkyl-substituted amino, sulfhydryl or hydroxy group, andB.sub.1 and B.sub.2, which may be identical or different, have no meaning or stand for guanidine and/or hydrazine base,and/or an imidazole derivative of the general formula (II), ##STR2## wherein n is equal to zero or 4,R.sub.2 stands for hydrogen, a straight-chained or branched C.sub.1-5 alkyl group having optionally a chlorine or hydroxy substituent, or a C.sub.2-5 alkenyl group,X stands for an organic or inorganic anion, andin the compounds of the general formula (II) wherein n is equal to 4 R.sub.1 has the same meanings as defined above, together with 10 to 95% by weight of one or more solid and/or liquid carrier(s) and 1 to 10% by weight of one or more surfactant(s).The new compositions according to the invention increase the productivity, protein nitrogen level and anion uptake of plants, furthermore they also possess kinetin-supplementing, cytokinin-like and membrane activities. The new compositions can be applied to advantage for increasing crop yield and the nutrient value of the crop.

摘要翻译： 本发明涉及含有0.5〜90重量％通式（I）的酞嗪衍生物的新组合物，其中R1代表氢，卤素，直链 具有任选的氯或羟基取代基的链或支链C 1-4烷基，C 2-4链烯基或任选的烷基取代的氨基，巯基或羟基，以及可以相同或不同的B 1和B 2具有 胍基和/或肼基，和/或通式（II）的咪唑衍生物，其中n等于0或4，R2代表氢，直链， 或任选具有氯或羟基取代基的支链C 1-5烷基或C 2-5烯基，X表示有机或无机阴离子，并且在通式（II）的化合物中，n等于4 R 1 具有与上述相同的含义，以及10至95重量％的一种或多种固体和/或液体 1载体和1至10重量％的一种或多种表面活性剂。 根据本发明的新组合物增加了植物的生产力，蛋白质氮水平和阴离子吸收，此外它们还具有激动素补充，细胞分裂素样和膜活性。 新组合物可以有利地用于增加作物产量和作物的营养价值。